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Title: XPS study of thermal and electron-induced decomposition of Ni and Co acetylacetonate thin films for metal deposition

Abstract

Optimizing thin metal film deposition techniques from metal-organic precursors such as atomic layer deposition, chemical vapor deposition (CVD), or electron beam-induced deposition (EBID) with the help of surface science analysis tools in ultrahigh vacuum requires a contamination-free precursor delivery technique, especially in the case of the less volatile precursors. For this purpose, the preparation of layers of undecomposed Ni(acac){sub 2} and Co(acac){sub 2} was tried via pulsed spray evaporation of a liquid solution of the precursors in ethanol into a flow of nitrogen on a CVD reactor. Solvent-free layers of intact precursor molecules were obtained when the substrate was held at a temperature of 115 °C. A qualitative comparison of thermally initiated and electron-induced precursor decomposition and metal center reduction was carried out. All deposited films were analyzed with respect to chemical composition quasi in situ by x-ray photoelectron spectroscopy. Thermally initiated decomposition yielded higher metal-to-metal oxide ratios in the deposit than the electron-induced process for which ratios of 60:40 and 20:80 were achieved for Ni and Co, resp. Compared to continuous EBID processes, all deposits showed low levels of carbon impurities of ∼10 at. %. Therefore, postdeposition irradiation of metal acetylacetonate layers by a focused electron beam and subsequent removalmore » of intact precursor by dissolution in ethanol or by heating is proposed as electron beam lithography technique on the laboratory scale for the production of the metal nanostructures.« less

Authors:
; ; ; ;  [1]
  1. Institut für Angewandte und Physikalische Chemie, Universität Bremen, Postfach 330440, D-28334 Bremen (Germany)
Publication Date:
OSTI Identifier:
22592881
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Vacuum Science and Technology. A, Vacuum, Surfaces and Films; Journal Volume: 34; Journal Issue: 4; Other Information: (c) 2016 American Vacuum Society; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 42 ENGINEERING; CARBON; CHEMICAL COMPOSITION; CHEMICAL VAPOR DEPOSITION; COMPARATIVE EVALUATIONS; DECOMPOSITION; DEPOSITS; ELECTRON BEAMS; ELECTRONS; ETHANOL; EVAPORATION; LAYERS; LIQUIDS; METALS; NITROGEN; ORGANOMETALLIC COMPOUNDS; OXIDES; PRECURSOR; THIN FILMS; X-RAY PHOTOELECTRON SPECTROSCOPY

Citation Formats

Weiss, Theodor, Warneke, Jonas, Zielasek, Volkmar, E-mail: zielasek@uni-bremen.de, Swiderek, Petra, and Bäumer, Marcus. XPS study of thermal and electron-induced decomposition of Ni and Co acetylacetonate thin films for metal deposition. United States: N. p., 2016. Web. doi:10.1116/1.4953469.
Weiss, Theodor, Warneke, Jonas, Zielasek, Volkmar, E-mail: zielasek@uni-bremen.de, Swiderek, Petra, & Bäumer, Marcus. XPS study of thermal and electron-induced decomposition of Ni and Co acetylacetonate thin films for metal deposition. United States. doi:10.1116/1.4953469.
Weiss, Theodor, Warneke, Jonas, Zielasek, Volkmar, E-mail: zielasek@uni-bremen.de, Swiderek, Petra, and Bäumer, Marcus. Fri . "XPS study of thermal and electron-induced decomposition of Ni and Co acetylacetonate thin films for metal deposition". United States. doi:10.1116/1.4953469.
@article{osti_22592881,
title = {XPS study of thermal and electron-induced decomposition of Ni and Co acetylacetonate thin films for metal deposition},
author = {Weiss, Theodor and Warneke, Jonas and Zielasek, Volkmar, E-mail: zielasek@uni-bremen.de and Swiderek, Petra and Bäumer, Marcus},
abstractNote = {Optimizing thin metal film deposition techniques from metal-organic precursors such as atomic layer deposition, chemical vapor deposition (CVD), or electron beam-induced deposition (EBID) with the help of surface science analysis tools in ultrahigh vacuum requires a contamination-free precursor delivery technique, especially in the case of the less volatile precursors. For this purpose, the preparation of layers of undecomposed Ni(acac){sub 2} and Co(acac){sub 2} was tried via pulsed spray evaporation of a liquid solution of the precursors in ethanol into a flow of nitrogen on a CVD reactor. Solvent-free layers of intact precursor molecules were obtained when the substrate was held at a temperature of 115 °C. A qualitative comparison of thermally initiated and electron-induced precursor decomposition and metal center reduction was carried out. All deposited films were analyzed with respect to chemical composition quasi in situ by x-ray photoelectron spectroscopy. Thermally initiated decomposition yielded higher metal-to-metal oxide ratios in the deposit than the electron-induced process for which ratios of 60:40 and 20:80 were achieved for Ni and Co, resp. Compared to continuous EBID processes, all deposits showed low levels of carbon impurities of ∼10 at. %. Therefore, postdeposition irradiation of metal acetylacetonate layers by a focused electron beam and subsequent removal of intact precursor by dissolution in ethanol or by heating is proposed as electron beam lithography technique on the laboratory scale for the production of the metal nanostructures.},
doi = {10.1116/1.4953469},
journal = {Journal of Vacuum Science and Technology. A, Vacuum, Surfaces and Films},
number = 4,
volume = 34,
place = {United States},
year = {Fri Jul 15 00:00:00 EDT 2016},
month = {Fri Jul 15 00:00:00 EDT 2016}
}