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Title: BODIPY star-shaped molecules as solid state colour converters for visible light communications

Abstract

In this paper, we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22% to 56%. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than that of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ∼15 cm.

Authors:
; ; ; ;  [1];  [2];  [3]; ; ;  [4]; ; ; ;  [5];  [5];  [6]
  1. Organic Semiconductor Centre, SUPA, School of Physics and Astronomy, University of St Andrews, St. Andrews KY16 9SS (United Kingdom)
  2. School of Computing, Electronics and Mathematics, Coventry University, Coventry, West Midlands CV1 2JH (United Kingdom)
  3. (United Kingdom)
  4. Department of Engineering Science, University of Oxford, Oxford OX1 3PJ (United Kingdom)
  5. WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL (United Kingdom)
  6. (Ukraine)
Publication Date:
OSTI Identifier:
22590636
Resource Type:
Journal Article
Resource Relation:
Journal Name: Applied Physics Letters; Journal Volume: 109; Journal Issue: 1; Other Information: (c) 2016 Author(s); Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; BORON; COLOR; COMMUNICATIONS; CONTROL; CONVERSION; DISTANCE; LENGTH; LIGHTING SYSTEMS; MHZ RANGE 01-100; MODULATION; MOLECULES; ORGANIC SEMICONDUCTORS; PHOSPHORS; PHOTOLUMINESCENCE; THIN FILMS; VISIBLE RADIATION

Citation Formats

Vithanage, D. A., Manousiadis, P. P., Sajjad, M. T., Samuel, I. D. W., E-mail: idws@st-andrews.ac.uk, E-mail: gat@st-andrews.ac.uk, Turnbull, G. A., E-mail: idws@st-andrews.ac.uk, E-mail: gat@st-andrews.ac.uk, Rajbhandari, S., Department of Engineering Science, University of Oxford, Oxford OX1 3PJ, Chun, H., Faulkner, G., O'Brien, D. C., Orofino, C., Cortizo-Lacalle, D., Findlay, N. J., Skabara, P. J., Kanibolotsky, A. L., and Institute of Physical-Organic Chemistry and Coal Chemistry, 02160 Kyiv. BODIPY star-shaped molecules as solid state colour converters for visible light communications. United States: N. p., 2016. Web. doi:10.1063/1.4953789.
Vithanage, D. A., Manousiadis, P. P., Sajjad, M. T., Samuel, I. D. W., E-mail: idws@st-andrews.ac.uk, E-mail: gat@st-andrews.ac.uk, Turnbull, G. A., E-mail: idws@st-andrews.ac.uk, E-mail: gat@st-andrews.ac.uk, Rajbhandari, S., Department of Engineering Science, University of Oxford, Oxford OX1 3PJ, Chun, H., Faulkner, G., O'Brien, D. C., Orofino, C., Cortizo-Lacalle, D., Findlay, N. J., Skabara, P. J., Kanibolotsky, A. L., & Institute of Physical-Organic Chemistry and Coal Chemistry, 02160 Kyiv. BODIPY star-shaped molecules as solid state colour converters for visible light communications. United States. doi:10.1063/1.4953789.
Vithanage, D. A., Manousiadis, P. P., Sajjad, M. T., Samuel, I. D. W., E-mail: idws@st-andrews.ac.uk, E-mail: gat@st-andrews.ac.uk, Turnbull, G. A., E-mail: idws@st-andrews.ac.uk, E-mail: gat@st-andrews.ac.uk, Rajbhandari, S., Department of Engineering Science, University of Oxford, Oxford OX1 3PJ, Chun, H., Faulkner, G., O'Brien, D. C., Orofino, C., Cortizo-Lacalle, D., Findlay, N. J., Skabara, P. J., Kanibolotsky, A. L., and Institute of Physical-Organic Chemistry and Coal Chemistry, 02160 Kyiv. Mon . "BODIPY star-shaped molecules as solid state colour converters for visible light communications". United States. doi:10.1063/1.4953789.
@article{osti_22590636,
title = {BODIPY star-shaped molecules as solid state colour converters for visible light communications},
author = {Vithanage, D. A. and Manousiadis, P. P. and Sajjad, M. T. and Samuel, I. D. W., E-mail: idws@st-andrews.ac.uk, E-mail: gat@st-andrews.ac.uk and Turnbull, G. A., E-mail: idws@st-andrews.ac.uk, E-mail: gat@st-andrews.ac.uk and Rajbhandari, S. and Department of Engineering Science, University of Oxford, Oxford OX1 3PJ and Chun, H. and Faulkner, G. and O'Brien, D. C. and Orofino, C. and Cortizo-Lacalle, D. and Findlay, N. J. and Skabara, P. J. and Kanibolotsky, A. L. and Institute of Physical-Organic Chemistry and Coal Chemistry, 02160 Kyiv},
abstractNote = {In this paper, we study a family of solid-state, organic semiconductors for visible light communications. The star-shaped molecules have a boron-dipyrromethene (BODIPY) core with a range of side arm lengths which control the photophysical properties. The molecules emit red light with photoluminescence quantum yields ranging from 22% to 56%. Thin films of the most promising BODIPY molecules were used as a red colour converter for visible light communications. The film enabled colour conversion with a modulation bandwidth of 73 MHz, which is 16 times higher than that of a typical phosphor used in LED lighting systems. A data rate of 370 Mbit/s was demonstrated using On-Off keying modulation in a free space link with a distance of ∼15 cm.},
doi = {10.1063/1.4953789},
journal = {Applied Physics Letters},
number = 1,
volume = 109,
place = {United States},
year = {Mon Jul 04 00:00:00 EDT 2016},
month = {Mon Jul 04 00:00:00 EDT 2016}
}