Synthesis and novel luminescence properties of one-dimension BaMoO{sub 4}:Ln{sup 3+} nanostructures

Journal Article · Tue Dec 15 00:00:00 EST 2015 · Materials Research Bulletin

DOI:https://doi.org/10.1016/J.MATERRESBULL.2015.08.005· OSTI ID:22584239

Wang, Yuping; Li, Mingxia; Pan, Kai; Wang, Guofeng

Highlights: • String BaMoO{sub 4}:Ln{sup 3+} nanobeans were prepared by a hydrothermal method. • The Decay dynamics were performed to study the photoluminescence of the BaMoO{sub 4}:Eu{sup 3+} nanobeans. • For BaMoO{sub 4}:Er{sup 3+}/Eu{sup 3+}, the {sup 2}P{sub 3/2} → {sup 4}I{sub 11/2} and {sup 2}H{sub 11/2}/{sup 4}S{sub 3/2} → {sup 4}I{sub 15/2} transitions were observed. - Abstract: String BaMoO{sub 4}:Ln{sup 3+} (Ln = Eu, Tb, Er, and Gd) nanobeans were prepared by a hydrothermal method. The samples were characterized by transmission electron microscope, scanning electron microscope, X-ray diffraction, X-ray photoelectron spectroscope, and Raman spectrometer. Under direct excitation in the charge transfer absorption band, concentration quenching phenomenon occurs and decay dynamics were performed to study the photoluminescence of the string BaMoO{sub 4}:Eu{sup 3+} nanobeans. In the emission spectra of BaMoO{sub 4}:Er{sup 3+}/Eu{sup 3+} under 274 nm excitation, the {sup 2}P{sub 3/2} → {sup 4}I{sub 11/2}, {sup 2}H{sub 11/2} → {sup 4}I{sub 15/2}, and {sup 4}S{sub 3/2} → {sup 4}I{sub 15/2} transitions from Er{sup 3+} ions were observed for the first time. In addition, the photoluminescence properties of BaMoO{sub 4}:Tb{sup 3+}/Eu{sup 3+} and BaMoO{sub 4}:Gd{sup 3+}/Eu{sup 3+} were also investigated.

• OSTI ID: 22584239
• Journal Information: Materials Research Bulletin, Vol. 72; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
BARIUM COMPOUNDS
CONCENTRATION RATIO
EMISSION SPECTRA
EMISSION SPECTROSCOPY
ERBIUM IONS
EUROPIUM IONS
EXCITATION
GADOLINIUM IONS
HYDROTHERMAL SYNTHESIS
MOLYBDATES
NANOSTRUCTURES
PHOTOLUMINESCENCE
RAMAN SPECTROSCOPY
SCANNING ELECTRON MICROSCOPY
TERBIUM IONS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
X-RAY PHOTOELECTRON SPECTROSCOPY