Effect of chromium substitution on the dielectric properties of mixed Ni-Zn ferrite prepared by WOWS sol–gel technique
- Nano Scale Physics Laboratory, Department of Physics, Air University, PAF Complex E-9, Islamabad (Pakistan)
- Applied Thermal Physics Laboratory, Department of Physics, COMSATS Institute of Information Technology, Islamabad 44000 (Pakistan)
Graphical abstract: Variation of AC conductivity (σ{sub AC}) as a function of natural log of angular frequency (lnω) for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2-x}Cr{sub x}O{sub 4} nanoferrites at room temperature. - Highlights: • Cr doped mixed Ni-Zn ferrites were successfully synthesized by a newly developed WOWS sol gel technique. • The specific surface area and specific surface area to volume ratio increased with decrease in particle size. • The resonance peaks appeared in dielectric loss graphs, shifting towards low frequency with the increase in Cr concentration. • The prepared samples have the lowest values of the dielectric constant. • The dielectric constant were observed to be inversely proportional to square root of the AC resistivity. - Abstract: Cr{sup +3} doped Ni-Zn nanoferrite samples with composition Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2-x}Cr{sub x}O{sub 4}(x = 0.1, 0.2, 0.3, 0.4) were synthesized With Out Water and Surfactant (WOWS) sol-gel technique. The structural, morphological and dielectric properties of the samples were investigated. The lattice constant, crystallite size, theoretical density and porosity of each sample were obtained from X-ray diffraction (XRD) data. The specific surface area and specific surface area to volume ratio increased with the decrease in the size of Cr{sup +3} doped Ni-Zn ferrite nanoparticles, as the concentration of Cr{sup +3} increased. The SEM analysis revealed that the particles were of nano size and of spherical shape. The dielectric parameters such as dielectric constant (ε′) and dielectric loss (tanδ) of all the samples as a function of frequency at room temperature were measured. The AC conductivity (σ{sub AC}) was determined from the dielectric parameters, which showed increasing trend with the rise in frequency.
- OSTI ID:
- 22581568
- Journal Information:
- Materials Research Bulletin, Vol. 79; Other Information: Copyright (c) 2016 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
Similar Records
Structural and Electrical Dependence in Zn-Doped Li-Ferrite Nanostructures
AC Electrical Properties of MgFe{sub 2−x}Nd{sub x}O{sub 4} (x = 0 to 0.04) for High Frequency Applications
Related Subjects
CHROMIUM COMPOUNDS
CHROMIUM IONS
CONCENTRATION RATIO
DIELECTRIC MATERIALS
DOPED MATERIALS
ELECTRIC CONDUCTIVITY
FERRATES
FREQUENCY DEPENDENCE
LATTICE PARAMETERS
NANOPARTICLES
NANOSTRUCTURES
NICKEL COMPOUNDS
PERMITTIVITY
RELAXATION LOSSES
SCANNING ELECTRON MICROSCOPY
SOL-GEL PROCESS
SPECIFIC SURFACE AREA
TEMPERATURE RANGE 0273-0400 K
X-RAY DIFFRACTION
ZINC COMPOUNDS