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Title: Adenine adlayers on Cu(111): XPS and NEXAFS study

Abstract

The adsorption of adenine on Cu(111) was studied by photoelectron and near edge x-ray absorption fine structure spectroscopy. Disordered molecular films were deposited by means of physical vapor deposition on the substrate at room temperature. Adenine chemisorbs on the Cu(111) surface with strong rehybridization of the molecular orbitals and the Cu 3d states. Annealing at 150 °C caused the desorption of weakly bonded molecules accompanied by formation of a short-range ordered molecular adlayer. The interface is characterized by the formation of new states in the valence band at 1.5, 7, and 9 eV. The present work complements and refines existing knowledge of adenine interaction with this surface. The coverage is not the main parameter that defines the adenine geometry and adsorption properties on Cu(111). Excess thermal energy can further rearrange the molecular adlayer and, independent of the initial coverage, the flat lying stable molecular adlayer is formed.

Authors:
; ; ;  [1];  [2];  [2];  [3]
  1. Department of Surface and Plasma Science, Faculty of Mathematics and Physics, Charles University in Prague, V Holešovičkách 2, 18000 Prague 8 (Czech Republic)
  2. Elettra-Sincrotrone Trieste S.C.p.A., Area Science Park, Strada Statale 14, km 163.5, 34149 Basovizza, Trieste (Italy)
  3. (Italy)
Publication Date:
OSTI Identifier:
22493201
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Chemical Physics; Journal Volume: 143; Journal Issue: 17; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; ADENINES; ADSORPTION; ANNEALING; CHEMISORPTION; DEPOSITS; DESORPTION; FILMS; FINE STRUCTURE; INTERACTIONS; INTERFACES; MOLECULES; PHYSICAL VAPOR DEPOSITION; SUBSTRATES; SURFACES; TEMPERATURE RANGE 0273-0400 K; X-RAY PHOTOELECTRON SPECTROSCOPY; X-RAY SPECTROSCOPY

Citation Formats

Tsud, Nataliya, Bercha, Sofiia, Ševčíková, Klára, Matolín, Vladimír, Acres, Robert G., Prince, Kevin C., and Istituto Officina dei Materiali, Consiglio Nazionale delle Ricerche, 34149 Basovizza, Trieste. Adenine adlayers on Cu(111): XPS and NEXAFS study. United States: N. p., 2015. Web. doi:10.1063/1.4935055.
Tsud, Nataliya, Bercha, Sofiia, Ševčíková, Klára, Matolín, Vladimír, Acres, Robert G., Prince, Kevin C., & Istituto Officina dei Materiali, Consiglio Nazionale delle Ricerche, 34149 Basovizza, Trieste. Adenine adlayers on Cu(111): XPS and NEXAFS study. United States. doi:10.1063/1.4935055.
Tsud, Nataliya, Bercha, Sofiia, Ševčíková, Klára, Matolín, Vladimír, Acres, Robert G., Prince, Kevin C., and Istituto Officina dei Materiali, Consiglio Nazionale delle Ricerche, 34149 Basovizza, Trieste. Sat . "Adenine adlayers on Cu(111): XPS and NEXAFS study". United States. doi:10.1063/1.4935055.
@article{osti_22493201,
title = {Adenine adlayers on Cu(111): XPS and NEXAFS study},
author = {Tsud, Nataliya and Bercha, Sofiia and Ševčíková, Klára and Matolín, Vladimír and Acres, Robert G. and Prince, Kevin C. and Istituto Officina dei Materiali, Consiglio Nazionale delle Ricerche, 34149 Basovizza, Trieste},
abstractNote = {The adsorption of adenine on Cu(111) was studied by photoelectron and near edge x-ray absorption fine structure spectroscopy. Disordered molecular films were deposited by means of physical vapor deposition on the substrate at room temperature. Adenine chemisorbs on the Cu(111) surface with strong rehybridization of the molecular orbitals and the Cu 3d states. Annealing at 150 °C caused the desorption of weakly bonded molecules accompanied by formation of a short-range ordered molecular adlayer. The interface is characterized by the formation of new states in the valence band at 1.5, 7, and 9 eV. The present work complements and refines existing knowledge of adenine interaction with this surface. The coverage is not the main parameter that defines the adenine geometry and adsorption properties on Cu(111). Excess thermal energy can further rearrange the molecular adlayer and, independent of the initial coverage, the flat lying stable molecular adlayer is formed.},
doi = {10.1063/1.4935055},
journal = {Journal of Chemical Physics},
number = 17,
volume = 143,
place = {United States},
year = {Sat Nov 07 00:00:00 EST 2015},
month = {Sat Nov 07 00:00:00 EST 2015}
}
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