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Title: Polymer electrolyte based on crosslinked poly(glycidyl methacrylate) and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Abstract

Polymer electrolytes based on crosslinked poly(glycidyl methacrylate) as polymer host and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BmimTFSI) as incorporated salt were prepared by in-situ photopolymerization technique. The complexes with different mass ratio of glycidyl methacrylate (GMA) monomer to BmimTFSI were investigated. The ionic conductivity of the polymer electrolyte was increased and reach the highest value of 7.50 × 10{sup −4} S cm{sup −1} at the ratio of 3:7 (GMA: BmimTFSI). The interaction between the polymer host and ionic liquid was proved by Attenuated Total Reflectance-Fourier Transformation Infra-Red Spectroscopy (ATR-FTIR). Meanwhile, the X-ray diffraction analysis shows the amorphousity of the polymer electrolyte film increase with the ionic liquid ratio.

Authors:
; ; ;  [1]
  1. School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43000 Bangi, Selangor Darul Ehsan (Malaysia)
Publication Date:
OSTI Identifier:
22488990
Resource Type:
Journal Article
Journal Name:
AIP Conference Proceedings
Additional Journal Information:
Journal Volume: 1678; Journal Issue: 1; Conference: Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2015 Postgraduate Colloquium, Selangor (Malaysia), 15-16 Apr 2015; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0094-243X
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AMORPHOUS STATE; CROSS-LINKING; ELECTROLYTES; FILMS; FOURIER TRANSFORMATION; IMIDAZOLES; IMIDES; INFRARED SPECTRA; IONIC CONDUCTIVITY; METHACRYLATES; MONOMERS; ORGANIC POLYMERS; SALTS; X-RAY DIFFRACTION

Citation Formats

Fei, Beatrice Wong Chui, Hanifah, Sharina Abu, Ahmad, Azizan, and Hassan, Nur Hasyareeda. Polymer electrolyte based on crosslinked poly(glycidyl methacrylate) and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. United States: N. p., 2015. Web. doi:10.1063/1.4931288.
Fei, Beatrice Wong Chui, Hanifah, Sharina Abu, Ahmad, Azizan, & Hassan, Nur Hasyareeda. Polymer electrolyte based on crosslinked poly(glycidyl methacrylate) and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. United States. https://doi.org/10.1063/1.4931288
Fei, Beatrice Wong Chui, Hanifah, Sharina Abu, Ahmad, Azizan, and Hassan, Nur Hasyareeda. 2015. "Polymer electrolyte based on crosslinked poly(glycidyl methacrylate) and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide". United States. https://doi.org/10.1063/1.4931288.
@article{osti_22488990,
title = {Polymer electrolyte based on crosslinked poly(glycidyl methacrylate) and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide},
author = {Fei, Beatrice Wong Chui and Hanifah, Sharina Abu and Ahmad, Azizan and Hassan, Nur Hasyareeda},
abstractNote = {Polymer electrolytes based on crosslinked poly(glycidyl methacrylate) as polymer host and 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (BmimTFSI) as incorporated salt were prepared by in-situ photopolymerization technique. The complexes with different mass ratio of glycidyl methacrylate (GMA) monomer to BmimTFSI were investigated. The ionic conductivity of the polymer electrolyte was increased and reach the highest value of 7.50 × 10{sup −4} S cm{sup −1} at the ratio of 3:7 (GMA: BmimTFSI). The interaction between the polymer host and ionic liquid was proved by Attenuated Total Reflectance-Fourier Transformation Infra-Red Spectroscopy (ATR-FTIR). Meanwhile, the X-ray diffraction analysis shows the amorphousity of the polymer electrolyte film increase with the ionic liquid ratio.},
doi = {10.1063/1.4931288},
url = {https://www.osti.gov/biblio/22488990}, journal = {AIP Conference Proceedings},
issn = {0094-243X},
number = 1,
volume = 1678,
place = {United States},
year = {Fri Sep 25 00:00:00 EDT 2015},
month = {Fri Sep 25 00:00:00 EDT 2015}
}