Series of coordination polymers based on 4-(5-sulfo-quinolin-8-yloxy) phthalate and bipyridinyl coligands: Structure diversity and properties

Journal Article · Thu Oct 15 00:00:00 EDT 2015 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/J.JSSC.2015.06.018· OSTI ID:22486791

Feng, Xun ^[1]; Liu, Jing ^[2]; Li, Jin; Ma, Lu-Fang ^[1]; Wang, Li-Ya ^[1]; Ng, Seik-Weng ^[3]; Qin, Guo-Zhan ^[1]

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1. College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022 (China)
2. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001 (China)
3. Department of Chemistry, University of Malaya, Kuala Lumpur 50603 (Malaysia)

Reactions between later metal salts and conjugational N-hetrocyclic sulfonate/ carboxylic acid under the presence of bipyridyl auxiliary ligands afforded a series of manganese, nickel, zinc, silver, cadmium coordination polymers bearing with phenyl pendant arm attached to quinoline skeletons, and they have been characterized by elements analysis, thermogravimetry, infrared spectroscopy and single-crystal X-ray diffraction studying. The series of polymers show interesting structural diversity in coordination environment, dimensions and topologies. They are all built from 2-D networks constructed from metal cluster through sulfonate or carboxylate groups, as the secondary building unit (SBU). The thermalgravimetric analyses show that they display framework stabilities in solid state. Variable-temperature magnetic susceptibility studies reveal the existence of antiferromagnetic interactions between adjacent Mn (II) ions in 1, and ferromagnetic interactions between Ni(II) ions for 2, respectively. The photo-luminescence properties of 3-5 have also been investigated systemically. - Highlights: • A series of coordination polymers based on later transition metal ions have been obtained. • They contain conjugational N-hetrocyclic sulfonate-carboxylic acid and bipyridyl auxiliary ligands. • They have been characterized systemically. • They exhibit structure diversity and interesting properties.

• OSTI ID: 22486791
• Journal Information: Journal of Solid State Chemistry, Vol. 230; Other Information: Copyright (c) 2015 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ABSORPTION SPECTROSCOPY
ANTIFERROMAGNETISM
CADMIUM
INFRARED SPECTRA
LIGANDS
LUMINESCENCE
MAGNETIC SUSCEPTIBILITY
MANGANESE
MONOCRYSTALS
NICKEL
PHTHALIC ACID
POLYMERS
SALTS
SILVER
SOLIDS
SULFATES
THERMAL GRAVIMETRIC ANALYSIS
X-RAY DIFFRACTION
ZINC