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Zero lattice mismatch and twin-free single crystalline ScN buffer layers for GaN growth on silicon

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4935856· OSTI ID:22486088
; ; ;  [1]; ;  [2]; ; ;  [3];  [1]
  1. IHP, Im Technologiepark 25, 15236 Frankfurt, Oder (Germany)
  2. Technische Universität Berlin, Institut für Optik und Atomare Physik, Straße des 17. Juni 135, 10623 Berlin (Germany)
  3. SILTRONIC AG, Hanns-Seidel-Platz 4, 81737 München (Germany)
We report the growth of thin ScN layers deposited by plasma-assisted molecular beam epitaxy on Sc{sub 2}O{sub 3}/Y{sub 2}O{sub 3}/Si(111) substrates. Using x-ray diffraction, Raman spectroscopy, and transmission electron microscopy, we find that ScN films grown at 600 °C are single crystalline, twin-free with rock-salt crystal structure, and exhibit a direct optical band gap of 2.2 eV. A high degree of crystalline perfection and a very good lattice matching between ScN and GaN (misfit < 0.1%) makes the ScN/Sc{sub 2}O{sub 3}/Y{sub 2}O{sub 3} buffer system a very promising template for the growth of high quality GaN layers on silicon.
OSTI ID:
22486088
Journal Information:
Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 20 Vol. 107; ISSN APPLAB; ISSN 0003-6951
Country of Publication:
United States
Language:
English