Photoluminescence properties of cerium oxide nanoparticles as a function of lanthanum content

Journal Article · Thu Oct 15 00:00:00 EDT 2015 · Materials Research Bulletin

DOI:https://doi.org/10.1016/J.MATERRESBULL.2015.05.006· OSTI ID:22475927

Deus, R. C. ^[1]; Ramirez, M. A. ^[1]; Ponce, M. A. ^[2]; Andres, J. ^[3]; Rocha, L. S.R. ^[1]; others, and

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1. Universidade Estadual Paulista, Unesp —Faculdade de Engenharia de Guaratinguetá, Av. Dr Ariberto Pereira da Cunha 333, Bairro Pedregulho, P.O. Box 355, 12.516-410 Guaratinguetá, São Paulo, Brazil, (Brazil)
2. Instituto de Investigaciones en Ciencia y Tecnología de Materiales (INTEMA) (CONICET-Universidad Nacional de Mar del Plata), Juan B. Justo 4302, 7600 Mar del Plata (Argentina)
3. Laboratório Interdisciplinar em Cerâmica, Instituto de Química, Universidade Estadual Paulista, P.O. Box 355, 14801-907 Araraquara, São Paulo (Brazil)

Highlights: • CeO{sub 2} nanoparticles were obtained by microwave-hydrothermal method. • Rietveld refinement reveals a cubic structure. • KOH mineralizer agent exhibit weak agglomeration at low temperature and shorter time. - Abstract: The structural and photoluminescent properties at room temperature of CeO{sub 2} and La-doped CeO{sub 2} particles were undertaken. The obtained particles were synthesized by a microwave-assisted hydrothermal method (MAH) under different lanthanum contents. X-ray diffraction (XRD), Fourier transform infrared (FT-IR), Fourier transform Raman (FT-Raman), Ultra-violet spectroscopy (UV–vis) and photoluminescence (PL) measurements were carried out. XRD revealed that the powders are free of secondary phases and crystallize in the cubic structure. Raman data show that increasing La doping content increase oxygen vacancies due to lattice expansion. The UV/vis absorption spectroscopy suggested the presence of intermediate energy levels in the band gap of structurally ordered powders. Lanthanum addition creates oxygen vacancies and shifts the photoluminescence in the low energy range leading to intense PL emission.

• OSTI ID: 22475927
• Journal Information: Materials Research Bulletin, Journal Name: Materials Research Bulletin Vol. 70; ISSN MRBUAC; ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
ABSORPTION SPECTROSCOPY
AGGLOMERATION
CERAMICS
CERIUM OXIDES
CRYSTAL GROWTH
DOPED MATERIALS
ENERGY LEVELS
EXPANSION
FOURIER TRANSFORMATION
HYDROTHERMAL SYNTHESIS
INFRARED SPECTRA
LANTHANUM ADDITIONS
MICROWAVE RADIATION
NANOPARTICLES
NANOSTRUCTURES
PHOTOLUMINESCENCE
POWDERS
X-RAY DIFFRACTION