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Structure and thermal behavior of a nickel complex based on a V-shaped bis(4-(1H-imidazol-1-yl)phenyl)amine ligand

Journal Article · · Crystallography Reports
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  1. Nanjing University of Information Science & Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Innovative Research Laboratory of Energy & Environmental Catalysis, School of Environmental Science and Engineering (China)

A new coordination polymer ([Ni(BIPA)(bpdc)(H{sub 2}O){sub 2}]){sub n} has been prepared based on a new V-shaped bis(4-(1H-imidazol-1-yl)phenyl)amine (BIPA) ligand. Complex was characterized by elemental analysis, IR spectra, X-ray powder diffraction, thermal analysis and single crystal X-ray analysis. Complex exhibits a 1D → 3D structure. Hydrogen bonds play an important role in the formation of supramolecular network structure. Thermal analysis indicates that complex exhibits a high thermal stability.

OSTI ID:
22472057
Journal Information:
Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 7 Vol. 60; ISSN CYSTE3; ISSN 1063-7745
Country of Publication:
United States
Language:
English