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Title: Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands

Abstract

3-(4-(1H-Benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one (L{sup 1}, 1) and its Mn(II) complex, [Mn(L{sup 1}){sub 2}(SCN){sub 2}]{sub ∞} (2), were synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The Mn(II) ion in 2 is six-coordinated to four nitrogen atoms of two L{sup 1} ligands, two SCN-ligands, and two oxygen atoms of other two L{sup 1} ligands to form a distorted octahedral geometry. Therefore, each L{sup 1} links Mn ions through the O and N atoms to generate 2D sheet structure.

Authors:
; ; ; ; ;  [1]
  1. Yuncheng University, Department of Applied Chemistry (China)
Publication Date:
OSTI Identifier:
22472053
Resource Type:
Journal Article
Journal Name:
Crystallography Reports
Additional Journal Information:
Journal Volume: 60; Journal Issue: 7; Other Information: Copyright (c) 2015 Pleiades Publishing, Inc.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 1063-7745
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ABSORPTION SPECTROSCOPY; CRYSTAL STRUCTURE; IMIDAZOLES; INFRARED SPECTRA; LIGANDS; MANGANESE COMPLEXES; MANGANESE IONS; MONOCRYSTALS; MULTI-ELEMENT ANALYSIS; NITROGEN; ORGANIC POLYMERS; OXYGEN; SYNTHESIS; X-RAY DIFFRACTION

Citation Formats

Wang, G.-F., E-mail: wgf1979@126.com, Zhang, X., E-mail: zhangx@hit.edu.cn, Sun, S.-W., E-mail: s-shuwen@163.com, Han, Q. -P., Yang, X., Li, H., Ma, H. -X., Yao, C. -Z., Sun, H., and Dong, H.-B., E-mail: Donghb0622@126.com. Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands. United States: N. p., 2015. Web. doi:10.1134/S1063774515070305.
Wang, G.-F., E-mail: wgf1979@126.com, Zhang, X., E-mail: zhangx@hit.edu.cn, Sun, S.-W., E-mail: s-shuwen@163.com, Han, Q. -P., Yang, X., Li, H., Ma, H. -X., Yao, C. -Z., Sun, H., & Dong, H.-B., E-mail: Donghb0622@126.com. Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands. United States. doi:10.1134/S1063774515070305.
Wang, G.-F., E-mail: wgf1979@126.com, Zhang, X., E-mail: zhangx@hit.edu.cn, Sun, S.-W., E-mail: s-shuwen@163.com, Han, Q. -P., Yang, X., Li, H., Ma, H. -X., Yao, C. -Z., Sun, H., and Dong, H.-B., E-mail: Donghb0622@126.com. Tue . "Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands". United States. doi:10.1134/S1063774515070305.
@article{osti_22472053,
title = {Synthesis and crystal structure of a novel Mn(II) coordination polymer with 3-(4-(1H-benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one ligands},
author = {Wang, G.-F., E-mail: wgf1979@126.com and Zhang, X., E-mail: zhangx@hit.edu.cn and Sun, S.-W., E-mail: s-shuwen@163.com and Han, Q. -P. and Yang, X. and Li, H. and Ma, H. -X. and Yao, C. -Z. and Sun, H. and Dong, H.-B., E-mail: Donghb0622@126.com},
abstractNote = {3-(4-(1H-Benzo[d]imidazol-1-yl)-4-methoxyphenyl)-1-phenylprop-2-en-1-one (L{sup 1}, 1) and its Mn(II) complex, [Mn(L{sup 1}){sub 2}(SCN){sub 2}]{sub ∞} (2), were synthesized and characterized by elemental analyses, IR spectroscopy and single-crystal X-ray diffraction. The Mn(II) ion in 2 is six-coordinated to four nitrogen atoms of two L{sup 1} ligands, two SCN-ligands, and two oxygen atoms of other two L{sup 1} ligands to form a distorted octahedral geometry. Therefore, each L{sup 1} links Mn ions through the O and N atoms to generate 2D sheet structure.},
doi = {10.1134/S1063774515070305},
journal = {Crystallography Reports},
issn = {1063-7745},
number = 7,
volume = 60,
place = {United States},
year = {2015},
month = {12}
}