Low temperature hydrogen superpermeation in vanadium composite metal foil pumps

Li, Chao; Douglas Way, J.; Fuerst, Thomas F.; Wolden, Colin A.

doi:10.1016/j.nme.2023.101529

Title: Low temperature hydrogen superpermeation in vanadium composite metal foil pumps

Journal Article · Thu Sep 28 00:00:00 EDT 2023 · Nuclear Materials and Energy

DOI:https://doi.org/10.1016/j.nme.2023.101529· OSTI ID:2246899

Li, Chao ^[1]; Douglas Way, J. ^[1]; Fuerst, Thomas F. ^[2];

^[1]

Colorado School of Mines, Golden, CO (United States)
Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Palladium-based foil membranes are an effective option for hydrogen isotope recovery from the plasma exhaust of future fusion plants, but cost and availability are concerns. Vanadium (V) is a relatively low cost, neutron tolerant material with high hydrogen permeability. It has been well-studied as a superpermeable membrane at high temperature (>500 °C), but V displays negligible superpermeation at low temperature (75–200 °C) due to catalytic limitations. Composite membranes were fabricated by depositing thin layers (~100 nm) of either Pd or BCC PdCu on sputter-cleaned vanadium foils (100 μm). Symmetric membranes elevated superpermeation to levels approaching bulk Pd or PdCu foils, with ~5X higher flux in the latter reflecting the superior properties of PdCu. Asymmetric membranes revealed that the Pd-based catalyst layer was critical for both efficient absorption of superthermal hydrogen upstream as well as catalyzing re-combinative desorption downstream. At T ≥ 150 °C composite membrane superpermeation was equivalent to the Pd-based foils, but the flux was attenuated by a factor of 2-3X as the temperature was reduced. This deviation from pure foil performance coincided with the formation of vanadium hydride (β-V₂H), which also impacted the transient response. Nevertheless, no embrittlement was observed under the conditions examined and elevating the temperature >150 °C removed the hydride and restored full performance. The achievement of palladium-level performance with a >99% reduction in Pd inventory makes these V composite metal foils pumps an attractive option for low temperature hydrogen isotope recovery in future fusion plants.

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Research Organization:: Idaho National Laboratory (INL), Idaho Falls, ID (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AC07-05ID14517; AR0001368

OSTI ID:: 2246899

Report Number(s):: INL/JOU-23-74074-Rev000

Journal Information:: Nuclear Materials and Energy, Vol. 37; ISSN 2352-1791

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (49)

Hydrogen Release Through Metallic Surface: The Role of Sputtering and of the Impurity Dynamics Livshits, A. I.; Notkin, M. E.; Ohyabu, N. Physica Scripta https://doi.org/10.1238/Physica.Topical.108a00023	journal	January 2004
Interactions of low energy hydrogen ions with niobium: effects of non-metallic overlayers on reemission, retention and permeation Livshits, A. I.; Notkin, M. E.; Samartsev, A. A. Journal of Nuclear Materials, Vol. 233-237 https://doi.org/10.1016/S0022-3115(96)00084-0	journal	October 1996
Nuclear-fusion lab achieves ‘ignition’: what does it mean? Tollefson, Jeff; Gibney, Elizabeth Nature, Vol. 612, Issue 7941 https://doi.org/10.1038/d41586-022-04440-7	journal	December 2022
Hydrogen pumping and compression by superpermeation through iron Hackfort, H.; Bösche, K.; Waelbroeck, F. Journal of Nuclear Materials, Vol. 144, Issue 1-2 https://doi.org/10.1016/0022-3115(87)90273-X	journal	January 1987
Hydrogen Diffusion in a One Domain β-V₂H Single Crystal* Richter, D.; Mahling-Ennaoui, S.; Hempelmann, R. Zeitschrift für Physikalische Chemie, Vol. 164, Issue 1 https://doi.org/10.1524/zpch.1989.164.Part_1.0907	journal	January 1989
Fuel recycling and edge plasma control with membrane techniques: plasma–membrane simulation experiments Livshits, A.; Ohyabu, N.; Bacal, M. Journal of Nuclear Materials, Vol. 266-269 https://doi.org/10.1016/S0022-3115(98)00693-X	journal	March 1999
Synthesis of Stable Shape-Controlled Catalytically Active β-Palladium Hydride Zhao, Zipeng; Huang, Xiaoqing; Li, Mufan Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b11543	journal	December 2015
Permeation of deuterium implanted into copper Nagasaki, T.; Yamada, R.; Ohno, H. Journal of Nuclear Materials, Vol. 179-181 https://doi.org/10.1016/0022-3115(91)90094-N	journal	March 1991
Superpermeability: Critical points for applications in fusion Livshits, A. I.; Notkin, M. E.; Pistunovich, V. I. Journal of Nuclear Materials, Vol. 220-222 https://doi.org/10.1016/0022-3115(94)00424-2	journal	April 1995
Asymmetric surface recombination of hydrogen on palladium exposed to plasma Takagi, Ikuji; Moritani, Kimikazu; Moriyama, Hirotake Journal of Nuclear Materials, Vol. 313-316 https://doi.org/10.1016/S0022-3115(02)01370-3	journal	March 2003
Plasma driven superpermeation of hydrogen through group Va metals Livshits, A. I.; Sube, F.; Solovyev, M. N. Journal of Applied Physics, Vol. 84, Issue 5 https://doi.org/10.1063/1.368418	journal	September 1998
Atomic, ionic and molecular hydrogen permeation facility with in situ Auger surface analysis Antoniazzi, A. B.; Haasz, A. A.; Auciello, O. Journal of Nuclear Materials, Vol. 128-129 https://doi.org/10.1016/0022-3115(84)90432-X	journal	December 1984
Long-term radioactive waste from fusion reactors: Part II Fetter, Steve; Cheng, E. T.; Mann, F. M. Fusion Engineering and Design, Vol. 13, Issue 2 https://doi.org/10.1016/0920-3796(90)90104-E	journal	November 1990
Nb interaction with hydrogen plasma Nakamura, Y.; Busnyuk, A.; Suzuki, H. Journal of Applied Physics, Vol. 89, Issue 1 https://doi.org/10.1063/1.1331075	journal	January 2001
Hydrogen permeation through copper-coated palladium Andrew, P. L.; Haasz, A. A. Journal of Applied Physics, Vol. 70, Issue 7 https://doi.org/10.1063/1.349256	journal	October 1991
Effect of thin copper and palladium films on hydrogen permeation through iron Andrew, P. L.; Haasz, A. A. Journal of the Less Common Metals, Vol. 172-174 https://doi.org/10.1016/0022-5088(91)90197-C	journal	August 1991
How Many Years Away is Fusion Energy? A Review Takeda, Shutaro; Keeley, Alexander Ryota; Managi, Shunsuke Journal of Fusion Energy, Vol. 42, Issue 1 https://doi.org/10.1007/s10894-023-00361-z	journal	May 2023
Simultaneous ion and gas driven permeation of deuterium through nickel Nagasaki, Takanori; Yamada, Reiji; Saidoh, Masahiro Journal of Nuclear Materials, Vol. 151, Issue 2 https://doi.org/10.1016/0022-3115(88)90071-2	journal	January 1988
Physics and technology considerations for the deuterium–tritium fuel cycle and conditions for tritium fuel self sufficiency Abdou, Mohamed; Riva, Marco; Ying, Alice Nuclear Fusion, Vol. 61, Issue 1 https://doi.org/10.1088/1741-4326/abbf35	journal	November 2020
Effect of surface impurities on the permeation of hydrogen through iron Andrew, P. L.; Haasz, A. A. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 8, Issue 3 https://doi.org/10.1116/1.576807	journal	May 1990
Metal Foil Pump performance aspects in view of the implementation of Direct Internal Recycling for future fusion fuel cycles Peters, B. J.; Hanke, S.; Day, C. Fusion Engineering and Design, Vol. 136 https://doi.org/10.1016/j.fusengdes.2018.05.036	journal	November 2018
Characteristic of a pdCu membrane as atomic hydrogen probe for QUEST Onaka, Masayuki; Takagi, Ikuji; Kobayashi, Taishi Nuclear Materials and Energy, Vol. 9 https://doi.org/10.1016/j.nme.2016.09.001	journal	December 2016
Superpermeability of solid membranes and gas evacuation Part II Permeation of hydrogen through a palladium membrane under different gas and membrane boundary conditions Livshitz, A. I.; Notkin, M. E.; Pustovoit, YuM Vacuum, Vol. 29, Issue 3 https://doi.org/10.1016/S0042-207X(79)80451-0	journal	January 1979
Key design integration issues addressed in the EU DEMO pre-concept design phase Bachmann, C.; Ciattaglia, S.; Cismondi, F. Fusion Engineering and Design, Vol. 156 https://doi.org/10.1016/j.fusengdes.2020.111595	journal	July 2020
Deuterium pumping experiment with superpermeable Nb membrane in JFT-2M tokamak Nakamura, Y.; Sengoku, S.; Nakahara, Y. Journal of Nuclear Materials, Vol. 278, Issue 2-3 https://doi.org/10.1016/S0022-3115(99)00243-3	journal	April 2000
Tubular vanadium membranes for hydrogen purification Dolan, Michael D.; Viano, David M.; Langley, Matthew J. Journal of Membrane Science, Vol. 549 https://doi.org/10.1016/j.memsci.2017.12.031	journal	March 2018
Physico-chemical origin of superpermeability — Large-scale effects of surface chemistry on “hot” hydrogen permeation and absorption in metals Livshits, A. I.; Notkin, M. E.; Samartsev, A. A. Journal of Nuclear Materials, Vol. 170, Issue 1 https://doi.org/10.1016/0022-3115(90)90329-L	journal	January 1990
Preliminary configuration of the torus vacuum pumping system installed in the DEMO lower port Giegerich, T.; Day, C.; Gliss, C. Fusion Engineering and Design, Vol. 146 https://doi.org/10.1016/j.fusengdes.2019.03.147	journal	September 2019
The effect of adsorbed carbon and sulphur on hydrogen permeation through palladium Antoniazzi, A. B.; Haasz, A. A.; Stangeby, P. C. Journal of Nuclear Materials, Vol. 162-164 https://doi.org/10.1016/0022-3115(89)90410-8	journal	April 1989
The Direct Internal Recycling concept to simplify the fuel cycle of a fusion power plant Day, Christian; Giegerich, Thomas Fusion Engineering and Design, Vol. 88, Issue 6-8 https://doi.org/10.1016/j.fusengdes.2013.05.026	journal	October 2013
Development of Advanced Exhaust Pumping Technology for a DT Fusion Power Plant Day, Christian; Giegerich, Thomas IEEE Transactions on Plasma Science, Vol. 42, Issue 4 https://doi.org/10.1109/TPS.2014.2307435	journal	April 2014
Tritium tests with a technical PERMCAT for final clean-up of ITER exhaust gases Bornschein, B.; Glugla, M.; Günther, K. Fusion Engineering and Design, Vol. 69, Issue 1-4 https://doi.org/10.1016/S0920-3796(03)00234-5	journal	September 2003
Kinetics of Dissociative Absorption of Hydrogen through Nb Surface Covered by Oxygen Hatano, Yuji; Livshits, Alexander; Busnyuk, Andrei Physica Scripta https://doi.org/10.1238/Physica.Topical.108a00014	journal	January 2004
Design and feasibility of a pumping concept based on tritium direct recycling Haertl, T.; Day, C.; Giegerich, T. Fusion Engineering and Design, Vol. 174 https://doi.org/10.1016/j.fusengdes.2021.112969	journal	January 2022
Models for hydrogen permeation in metals Andrew, P. L.; Haasz, A. A. Journal of Applied Physics, Vol. 72, Issue 7 https://doi.org/10.1063/1.351526	journal	October 1992
Superpermeability to fast and thermal hydrogen particles: applications to the pumping and recycling of hydrogen isotopes Livishits, A. I.; Notkin, M. E.; Samartsev, A. A. Journal of Nuclear Materials, Vol. 196-198 https://doi.org/10.1016/S0022-3115(06)80023-1	journal	December 1992
Effects of impurities on hydrogen permeability through palladium alloy membranes at comparatively high pressures and temperatures Yoshida, H.; Konishi, S.; Naruse, Y. Journal of the Less Common Metals, Vol. 89, Issue 2 https://doi.org/10.1016/0022-5088(83)90353-3	journal	February 1983
Hydrogen solubilisation into and permeation through wall materials Waelbroeck, F.; Ali-Khan, I.; Dietz, K. J. Journal of Nuclear Materials, Vol. 85-86 https://doi.org/10.1016/0022-3115(79)90514-2	journal	December 1979
Introduction to Climate Change Mitigation and Adaptation Lackner, Maximilian; Sajjadi, Bahar; Chen, Wei-Yin Handbook of Climate Change Mitigation and Adaptation https://doi.org/10.1007/978-1-4614-6431-0_169-1	book	January 2021
Tritium Pumping Based on Asymmetric Permeation Shmayda, W. T.; Waelbroeck, F.; Winter, J. Fusion Technology, Vol. 8, Issue 2P2 https://doi.org/10.13182/FST85-A24621	journal	September 1985
Study of Carbon Deposition Effect on Hydrogen Permeation Through Palladium Membrane Tominaga, S.; Busnyuk, A.; Matsushima, T. Fusion Science and Technology, Vol. 41, Issue 3P2 https://doi.org/10.13182/FST02-A22719	journal	May 2002
Influence of oxygen and carbon on performance of superpermeable membranes Hatano, Y.; Livshits, A.; Nakamura, Y. Fusion Engineering and Design, Vol. 81, Issue 1-7 https://doi.org/10.1016/j.fusengdes.2005.06.368	journal	February 2006
Applications of superpermeable membranes in fusion: The flux density problem and experimental progress Livshits, A. Journal of Nuclear Materials, Vol. 241-243, Issue 1 https://doi.org/10.1016/S0022-3115(96)00700-3	journal	February 1997
Progress of the R&D programme to develop a metal foil pump for DEMO Hanke, Stefan; Day, Christian; Giegerich, Thomas Fusion Engineering and Design, Vol. 161 https://doi.org/10.1016/j.fusengdes.2020.111890	journal	December 2020
Sticking coefficient of molecular and atomic hydrogen on palladium Dean, B.; Haasz, A. A.; Stangeby, P. C. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 5, Issue 4 https://doi.org/10.1116/1.574446	journal	July 1987
The effect of the surface state on the permeation of hydrogen through palladium Antoniazzi, A. B.; Haasz, A. A.; Stangeby, P. C. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 5, Issue 4 https://doi.org/10.1116/1.574445	journal	July 1987
A model for atomic hydrogen-metal interactions — application to recycling, recombination and permeation Pick, M. A.; Sonnenberg, K. Journal of Nuclear Materials, Vol. 131, Issue 2-3 https://doi.org/10.1016/0022-3115(85)90459-3	journal	April 1985
A comparison of the performance and stability of Pd/BCC metal composite membranes for hydrogen purification Cooney, Daniel A.; Way, J. Douglas; Wolden, Colin A. International Journal of Hydrogen Energy, Vol. 39, Issue 33 https://doi.org/10.1016/j.ijhydene.2014.09.094	journal	November 2014
Low temperature hydrogen plasma permeation in palladium and its alloys for fuel recycling in fusion systems Li, Chao; Job, Adam J.; Fuerst, Thomas F. Journal of Nuclear Materials, Vol. 582 https://doi.org/10.1016/j.jnucmat.2023.154484	journal	August 2023

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