Highly tritiated water processing by isotopic exchange
- ITER Organization, Saint-Paul-lez-Durance (France)
- Karlsruhe Institute of Technology, Tritium Laboratory Karlsruhe, Karlsruhe (Germany)
Highly tritiated water (HTW) is produced in fusion machines and one of the promising technologies to process it is isotopic exchange. 3 kinds of Pt-catalyzed zeolite (13X-APG, CBV-100-CY and HiSiv-1000) were tested as candidates for isotopic exchange of highly tritiated water (HTW), and CBV-100-CY (Na-Y type with a SiO{sub 2}/Al{sub 2}O{sub 3} ratio of ∼ 5.0) shows the best performance. Small-scale tritium testing indicates that this method is efficient for reaching an exchange factor (EF) of 100. Full-scale non-tritium testing implies that an EF of 300 can be achieved in 24 hours of operation if a temperature gradient is applied along the column. For the isotopic exchange, deuterium recycled from the Isotope Separation System (deuterium with 1% T and/or 200 ppm T) should be employed, and the tritiated water regenerated from the Pt-catalyzed zeolite bed after isotopic exchange should be transferred to Water Detritiation System (WDS) for further processing.
- OSTI ID:
- 22429767
- Journal Information:
- Fusion Science and Technology, Vol. 67, Issue 3; Conference: TRITIUM 2013: 10. International Conference on Tritium Science and Technology, Nice Acropolis (France), 21-25 Oct 2013; Other Information: Country of input: France; 5 refs.; ISSN 1536-1055
- Country of Publication:
- United States
- Language:
- English
Similar Records
Capture and isotopic exchange method for water and hydrogen isotopes on zeolite catalysts up to technical scale for pre-study of processing highly tritiated water
Tritium effluent control project progress report, July--September 1975. [Tritiated liquid waste decontamination by molecular excitation, electrolysis of high-level tritiated water, and catalytic exchange detritiation studies]