Synthesis and structural characterization of a new rubidium borosulfate, Rb{sub 5}BS{sub 4}O{sub 16}
Journal Article
·
· Materials Research Bulletin
- Key Laboratory of Functional Materials and Devices for Special Environments of CAS, Xinjiang Technical Institute of Physics and Chemistry of CAS, Xinjiang Key Laboratory of Electronic Information Materials and Devices, 40-1 South Beijing Road, Urumqi 830011 (China)
Highlights: • Rb{sub 5}BS{sub 4}O{sub 16} has been synthesized using (NH{sub 4}){sub 2}SO{sub 4} as a source of sulfate ions for the first time. • Zero-dimensional anion groups, [B(SO{sub 4}){sub 4}]{sup 5−}, exist in the title compound. • Spectral properties and thermal analysis of Rb{sub 5}BS{sub 4}O{sub 16} were reported. - Abstract: A new rubidium borosulfate, Rb{sub 5}BS{sub 4}O{sub 16}, has been synthesized using (NH{sub 4}){sub 2}SO{sub 4} as a source of sulfate ions for the first time. The compound crystallizes in the space group P4{sub 3}2{sub 1}2 (No. 96) of the tetragonal system with a = 10.148(4) Å, c = 16.689(14) Å, V = 1718.8(17) Å{sup 3}, and Z = 4. Zero-dimensional anion groups, [B(SO{sub 4}){sub 4}]{sup 5−}, a central BO{sub 4} tetrahedron sharing all its four vertices with neighboring sulfate tetrahedra, exist in the title compound, and then the rubidium atoms are situated in the voids of the resulting structure. The IR spectrum confirms the presence of BO{sub 4} and SO{sub 4} units. The UV–vis-NIR diffuse reflectance spectrum exhibits a band gap of about 3.99 eV. The TG-DSC analysis suggests that Rb{sub 5}BS{sub 4}O{sub 16} is an incongruent melting compound.
- OSTI ID:
- 22420830
- Journal Information:
- Materials Research Bulletin, Journal Name: Materials Research Bulletin Vol. 63; ISSN MRBUAC; ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
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