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Title: Surfactant-assisted synthesis of mono-dispersed cubic BaTiO{sub 3} nanoparticles

Abstract

Mono-dispersed BaTiO{sub 3} nanoparticles have been prepared via the assistance of capping agent poly(vinylpyrrolidone) (PVP). - Highlights: • BaTiO{sub 3} nanoparticles with single cubic crystal structure. • Poor dispersibility of nanoparticles has been overcome by in situ modification way. • Growth competition between BaTiO3 core and polymer shell. - Abstract: In this study, poly(vinylpyrrolidone)-assisted synthesis of mono-dispersed BaTiO{sub 3} nanoparticles have been reported. The various processing parameters, namely, refluxing temperature, KOH concentration, and poly(vinylpyrrolidone) concentration, have been varied, and the effects on the growth of BaTiO{sub 3} particles have been analyzed systematically. X-ray diffraction studies indicated that poly(vinylpyrrolidone) did not affect the crystal structure, but rather influenced the crystal lattice structure. In addition, the use of surfactant poly(vinylpyrrolidone) hindered the agglomeration of the nanoparticles, and facilitated the formation of mono-dispersed core–shell organic/inorganic hybrid nanocomposite. Furthermore, the mineralizer KOH promoted the dissolution of reactants and promoted the crystallization of BaTiO{sub 3} particles. Accordingly, the dissolution-precipitation scheme was believed to be the mechanism underlying the formation of BaTiO{sub 3} particles. This was further substantiated by the experimental observations, which indicated that the nucleation and crystallization of the particles was affected by the KOH concentration in the reaction system. Finally, the formation ofmore » mono-dispersed core–shell nanocomposites proceeded via reaction limited cluster aggregation. We believe that the method proposed in this study could be extended for the synthesis of mono-dispersed nanoparticles for industrial applications.« less

Authors:
 [1]; ;  [2]; ; ;  [1];  [1]
  1. National Institute of Advanced Industrial Science and Technology (AIST), Shimo-Shidami, Moriyama-ku, Nagoya 463-8560 (Japan)
  2. Noritake Co., Limited, RD Center, Miyoshi 470-0293 (Japan)
Publication Date:
OSTI Identifier:
22420550
Resource Type:
Journal Article
Journal Name:
Materials Research Bulletin
Additional Journal Information:
Journal Volume: 57; Other Information: Copyright (c) 2014 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0025-5408
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; AGGLOMERATION; BARIUM COMPOUNDS; CONCENTRATION RATIO; CRYSTAL GROWTH; CRYSTAL LATTICES; CRYSTALLIZATION; NANOCOMPOSITES; NANOPARTICLES; NANOSTRUCTURES; NUCLEATION; POTASSIUM HYDROXIDES; PRECIPITATION; PVP; SYNTHESIS; TITANATES; X-RAY DIFFRACTION

Citation Formats

Hai, Chunxi, Inukai, Koji, Takahashi, Yosuke, Izu, Noriya, Akamatsu, Takafumi, Itoh, Toshio, and Shin, Woosuck, E-mail: w.shin@aist.go.jp. Surfactant-assisted synthesis of mono-dispersed cubic BaTiO{sub 3} nanoparticles. United States: N. p., 2014. Web. doi:10.1016/J.MATERRESBULL.2014.05.036.
Hai, Chunxi, Inukai, Koji, Takahashi, Yosuke, Izu, Noriya, Akamatsu, Takafumi, Itoh, Toshio, & Shin, Woosuck, E-mail: w.shin@aist.go.jp. Surfactant-assisted synthesis of mono-dispersed cubic BaTiO{sub 3} nanoparticles. United States. doi:10.1016/J.MATERRESBULL.2014.05.036.
Hai, Chunxi, Inukai, Koji, Takahashi, Yosuke, Izu, Noriya, Akamatsu, Takafumi, Itoh, Toshio, and Shin, Woosuck, E-mail: w.shin@aist.go.jp. Mon . "Surfactant-assisted synthesis of mono-dispersed cubic BaTiO{sub 3} nanoparticles". United States. doi:10.1016/J.MATERRESBULL.2014.05.036.
@article{osti_22420550,
title = {Surfactant-assisted synthesis of mono-dispersed cubic BaTiO{sub 3} nanoparticles},
author = {Hai, Chunxi and Inukai, Koji and Takahashi, Yosuke and Izu, Noriya and Akamatsu, Takafumi and Itoh, Toshio and Shin, Woosuck, E-mail: w.shin@aist.go.jp},
abstractNote = {Mono-dispersed BaTiO{sub 3} nanoparticles have been prepared via the assistance of capping agent poly(vinylpyrrolidone) (PVP). - Highlights: • BaTiO{sub 3} nanoparticles with single cubic crystal structure. • Poor dispersibility of nanoparticles has been overcome by in situ modification way. • Growth competition between BaTiO3 core and polymer shell. - Abstract: In this study, poly(vinylpyrrolidone)-assisted synthesis of mono-dispersed BaTiO{sub 3} nanoparticles have been reported. The various processing parameters, namely, refluxing temperature, KOH concentration, and poly(vinylpyrrolidone) concentration, have been varied, and the effects on the growth of BaTiO{sub 3} particles have been analyzed systematically. X-ray diffraction studies indicated that poly(vinylpyrrolidone) did not affect the crystal structure, but rather influenced the crystal lattice structure. In addition, the use of surfactant poly(vinylpyrrolidone) hindered the agglomeration of the nanoparticles, and facilitated the formation of mono-dispersed core–shell organic/inorganic hybrid nanocomposite. Furthermore, the mineralizer KOH promoted the dissolution of reactants and promoted the crystallization of BaTiO{sub 3} particles. Accordingly, the dissolution-precipitation scheme was believed to be the mechanism underlying the formation of BaTiO{sub 3} particles. This was further substantiated by the experimental observations, which indicated that the nucleation and crystallization of the particles was affected by the KOH concentration in the reaction system. Finally, the formation of mono-dispersed core–shell nanocomposites proceeded via reaction limited cluster aggregation. We believe that the method proposed in this study could be extended for the synthesis of mono-dispersed nanoparticles for industrial applications.},
doi = {10.1016/J.MATERRESBULL.2014.05.036},
journal = {Materials Research Bulletin},
issn = {0025-5408},
number = ,
volume = 57,
place = {United States},
year = {2014},
month = {9}
}