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Isotopic dependence of the predissociations of the E{sup 1}Π state of CO

Journal Article · · Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.4918910· OSTI ID:22415710

The predissociations of the E{sup 1}Π state of CO are again studied. They include both the background predissociation attributed to the continuum of the A{sup 1}Π state and the accidental predissociation due to the k{sup 3}Π state. They are calculated using a coupled equations method. The three components of the k state are introduced. These predissociations are studied for different isotopologues and are shown to decrease with increasing reduced mass, in agreement with the experimental results of Ubachs et al. [J. Chem. Phys. 113, 547 (2000)].

OSTI ID:
22415710
Journal Information:
Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 16 Vol. 142; ISSN JCPSA6; ISSN 0021-9606
Country of Publication:
United States
Language:
English

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