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Title: Ferromagnetic behavior and exchange bias effect in akaganeite nanorods

Abstract

We report ferromagnetic-like properties and exchange bias effect in akaganeite (β-FeOOH) nanorods. They exhibit a Néel temperature T{sub N} = 259 K and ferromagnetic-like hysteresis behavior both below and above T{sub N}. An exchange bias effect is observed below T{sub N} and represents an interesting behavior for akaganeite nanorods. These results are explained on the basis of a core-shell structure in which the core has bulk akaganeite magnetic properties (i.e., antiferromagnetic ordering) while the shell exhibits a disordered spin state. Thus, the nanorods show ferromagnetic properties and an exchange bias effect at the same time, increasing their potential for use in practical applications.

Authors:
 [1]; ;  [2];  [3];  [4];  [5]
  1. Condensed Matter Physics Laboratory, Vinca Institute of Nuclear Science, University of Belgrade, P.O. Box 522, 11001 Belgrade (Serbia)
  2. Laboratoire CSPBAT, UMR 7244 CNRS Université Paris 13, 93017 Bobigny Cedex (France)
  3. Department for Materials Synthesis, Jožef Stefan Institute, Jamova 39, 1000 Ljubljana (Slovenia)
  4. CNRS, University of Orleans, F-45071 Orleans 2 (France)
  5. (France)
Publication Date:
OSTI Identifier:
22399025
Resource Type:
Journal Article
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 106; Journal Issue: 18; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0003-6951
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; ANTIFERROMAGNETISM; FERROMAGNETIC MATERIALS; FERROMAGNETISM; HYSTERESIS; IRON HYDROXIDES; IRON OXIDES; MAGNETIC PROPERTIES; NANOSTRUCTURES; NEEL TEMPERATURE; SPIN

Citation Formats

Tadic, Marin, E-mail: marint@vinca.rs, Milosevic, Irena, Motte, Laurence, Kralj, Slavko, Saboungi, Marie-Louise, and IMPMC, Sorbonne Univ-UPMC Univ Paris 06, UMR CNRS 7590, Museum National d'Histoire Naturelle, IRD UMR 206, 4 Place Jussieu, F-75005 Paris. Ferromagnetic behavior and exchange bias effect in akaganeite nanorods. United States: N. p., 2015. Web. doi:10.1063/1.4918930.
Tadic, Marin, E-mail: marint@vinca.rs, Milosevic, Irena, Motte, Laurence, Kralj, Slavko, Saboungi, Marie-Louise, & IMPMC, Sorbonne Univ-UPMC Univ Paris 06, UMR CNRS 7590, Museum National d'Histoire Naturelle, IRD UMR 206, 4 Place Jussieu, F-75005 Paris. Ferromagnetic behavior and exchange bias effect in akaganeite nanorods. United States. doi:10.1063/1.4918930.
Tadic, Marin, E-mail: marint@vinca.rs, Milosevic, Irena, Motte, Laurence, Kralj, Slavko, Saboungi, Marie-Louise, and IMPMC, Sorbonne Univ-UPMC Univ Paris 06, UMR CNRS 7590, Museum National d'Histoire Naturelle, IRD UMR 206, 4 Place Jussieu, F-75005 Paris. Mon . "Ferromagnetic behavior and exchange bias effect in akaganeite nanorods". United States. doi:10.1063/1.4918930.
@article{osti_22399025,
title = {Ferromagnetic behavior and exchange bias effect in akaganeite nanorods},
author = {Tadic, Marin, E-mail: marint@vinca.rs and Milosevic, Irena and Motte, Laurence and Kralj, Slavko and Saboungi, Marie-Louise and IMPMC, Sorbonne Univ-UPMC Univ Paris 06, UMR CNRS 7590, Museum National d'Histoire Naturelle, IRD UMR 206, 4 Place Jussieu, F-75005 Paris},
abstractNote = {We report ferromagnetic-like properties and exchange bias effect in akaganeite (β-FeOOH) nanorods. They exhibit a Néel temperature T{sub N} = 259 K and ferromagnetic-like hysteresis behavior both below and above T{sub N}. An exchange bias effect is observed below T{sub N} and represents an interesting behavior for akaganeite nanorods. These results are explained on the basis of a core-shell structure in which the core has bulk akaganeite magnetic properties (i.e., antiferromagnetic ordering) while the shell exhibits a disordered spin state. Thus, the nanorods show ferromagnetic properties and an exchange bias effect at the same time, increasing their potential for use in practical applications.},
doi = {10.1063/1.4918930},
journal = {Applied Physics Letters},
issn = {0003-6951},
number = 18,
volume = 106,
place = {United States},
year = {2015},
month = {5}
}