Study of Cs-promoted, {alpha}-alumina-supported silver ethylene-epoxidation catalysts. I. Characterization of the support and As-prepared catalyst
- Union Carbide Corp., South Charleston, WV (United States)
- Univ. of Florida, Gainesville, FL (United States)
An {alpha}-alumina support and a Cs-promoted Ag/{alpha}-Al{sub 2}O{sub 3} ethylene-epoxidation catalyst prepared on this same support have been characterized using secondary electron microscopy (SEM), electron dispersive X-ray spectroscopy (EDS), ion scattering spectroscopy (ISS), Auger electron spectroscopy (AES), and X-ray photoelectron spectroscopy (XPS). The SEM micrographs indicate that the {alpha}-alumina is crystalline with a well-defined plane exposed and that the Ag covers the support surface uniformly as a thin film. The EDS data also support the assertion that both surfaces are fairly uniform with regard to composition. ISS data exhibit features due to many contaminants such as C, N, Ca, and Ni on the {alpha}-alumina, as well as Na and Si binder materials which are also observed with AES and XPS. The XPS chemical-state data for the O, Al, Na, C, and Ag are complex, indicating that multiple chemical states of each element are present. Apparently, Ag is present predominantly as AgO, but Ag{sub 2}O and Ag metal are also present. 20 refs., 8 figs., 1 tab.
- OSTI ID:
- 223974
- Journal Information:
- Journal of Catalysis, Journal Name: Journal of Catalysis Journal Issue: 1 Vol. 158; ISSN 0021-9517; ISSN JCTLA5
- Country of Publication:
- United States
- Language:
- English
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