Electronic structure evolution of fullerene on CH{sub 3}NH{sub 3}PbI{sub 3}

Wang, Chenggong; Wang, Congcong; Kauppi, John; Gao, Yongli; Liu, Xiaoliang; Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng; Huang, Jinsong

doi:10.1063/1.4916079

Electronic structure evolution of fullerene on CH{sub 3}NH{sub 3}PbI{sub 3}

Journal Article · Mon Mar 16 04:00:00 EDT 2015 · Applied Physics Letters

DOI:https://doi.org/10.1063/1.4916079· OSTI ID:22395748

Wang, Chenggong; Wang, Congcong; Kauppi, John; Gao, Yongli ^[1]; Liu, Xiaoliang ^[2]; Shao, Yuchuan; Xiao, Zhengguo; Bi, Cheng; Huang, Jinsong ^[3]

Department of Physics and Astronomy, University of Rochester, Rochester, New York, 14627 (United States)
Hunan Key Laboratory for Super-microstructure and Ultrafast Process, College of Physics and Electronics, Central South University, Changsha 410083 (China)
Department of Mechanical and Materials Engineering, Nebraska Center for Materials and Nanoscience, University of Nebraska-Lincoln, Lincoln, Nebraska, 68588 (United States)

The thickness dependence of fullerene on CH{sub 3}NH{sub 3}PbI{sub 3} perovskite film surface has been investigated by using ultraviolet photoemission spectroscopy (UPS), X-ray photoemission spectroscopy (XPS), and inverse photoemission spectroscopy (IPES). The lowest unoccupied molecular orbital and highest occupied molecular orbital (HOMO) can be observed directly with IPES and UPS. It is observed that the HOMO level in fullerene shifts to lower binding energy. The XPS results show a strong initial shift of core levels to lower binding energy in the perovskite, which indicates that electrons transfer from the perovskite film to fullerene molecules. Further deposition of fullerene forms C{sub 60} solid, accompanied by the reduction of the electron transfer. The strongest electron transfer happened at 1/4 monolayer of fullerene.

OSTI ID:: 22395748

Journal Information:: Applied Physics Letters, Journal Name: Applied Physics Letters Journal Issue: 11 Vol. 106; ISSN APPLAB; ISSN 0003-6951

Country of Publication:: United States

Language:: English

Cited By (10)

Rapid Fabrication of Ni/NiO@CoFe Layered Double Hydroxide Hierarchical Nanostructures by Femtosecond Laser Ablation and Electrodeposition for Efficient Overall Water Splitting Wu, Haofei; Yin, Kai; Qi, Weihong ChemSusChem, Vol. 12, Issue 12 https://doi.org/10.1002/cssc.201900479	journal	May 2019
Picosecond Capture of Photoexcited Electrons Improves Photovoltaic Conversion in MAPbI ₃ :C ₇₀ -Doped Planar and Mesoporous Solar Cells Gharibzadeh, Saba; Valduga de Almeida Camargo, Franco; Roldán-Carmona, Cristina Advanced Materials, Vol. 30, Issue 40 https://doi.org/10.1002/adma.201801496	journal	August 2018
Controllable Synthesis of 2D Perovskite on Different Substrates and Its Application as Photodetector Xue, Yunzhou; Yuan, Jian; Liu, Jingying Nanomaterials, Vol. 8, Issue 8 https://doi.org/10.3390/nano8080591	journal	August 2018
Perovskite-perovskite tandem photovoltaics with optimized band gaps Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A. Science, Vol. 354, Issue 6314 https://doi.org/10.1126/science.aaf9717	journal	October 2016
Defects in metal triiodide perovskite materials towards high-performance solar cells: origin, impact, characterization, and engineering Ran, Chenxin; Xu, Jiantie; Gao, Weiyin Chemical Society Reviews, Vol. 47, Issue 12 https://doi.org/10.1039/c7cs00868f	journal	January 2018
Recent Advances in Energetics and Stability of Metal Halide Perovskites for Optoelectronic Applications Yang, Jian-Ming; Luo, Yuxin; Bao, Qinye Advanced Materials Interfaces, Vol. 6, Issue 3 https://doi.org/10.1002/admi.201801351	journal	December 2018
Research Update: The electronic structure of hybrid perovskite layers and their energetic alignment in devices Olthof, Selina APL Materials, Vol. 4, Issue 9 https://doi.org/10.1063/1.4960112	journal	August 2016
Perovskite-perovskite tandem photovoltaics with optimized bandgaps Eperon, Giles E.; Leijtens, Tomas; Bush, Kevin A. arXiv https://doi.org/10.48550/arxiv.1608.03920	text	January 2016
Investigation on thermal evaporated CH ₃ NH ₃ PbI ₃ thin films Li, Youzhen; Xu, Xuemei; Wang, Chenggong AIP Advances, Vol. 5, Issue 9 https://doi.org/10.1063/1.4930545	journal	September 2015
Progress of Surface Science Studies on ABX ₃ ‐Based Metal Halide Perovskite Solar Cells Qiu, Longbin; He, Sisi; Ono, Luis K. Advanced Energy Materials, Vol. 10, Issue 13 https://doi.org/10.1002/aenm.201902726	journal	April 2020

Similar Records

Electronic structure evolution of fullerene on CH₃NH₃PbI₃

Journal Article · Wed Mar 18 20:00:00 EDT 2015 · Applied Physics Letters · OSTI ID:1238030

Electronic structure evolution in doping of fullerene (C{sub 60}) by molybdenum trioxide

Journal Article · Mon Sep 15 00:00:00 EDT 2014 · Applied Physics Letters · OSTI ID:22303496

Surface analytical investigation on organometal triiodide perovskite

Journal Article · Thu Mar 19 20:00:00 EDT 2015 · Journal of Vacuum Science and Technology B · OSTI ID:1238031

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
AMMONIUM COMPOUNDS
BINDING ENERGY
DEPOSITION
ELECTRON TRANSFER
ELECTRONIC STRUCTURE
EMISSION SPECTROSCOPY
FILMS
LEAD IODIDES
MOLECULAR ORBITAL METHOD
MOLECULES
PEROVSKITE
PHOTOEMISSION
SOLIDS
SURFACES
ULTRAVIOLET RADIATION
X-RAY PHOTOELECTRON SPECTROSCOPY

Electronic structure evolution of fullerene on CH{sub 3}NH{sub 3}PbI{sub 3}

Citation Formats

Cited By (10)

Similar Records

Related Subjects