Hydroformylation of 1-octene in the presence of cobalt alkylidynecarbonyl clusters
- Scientific Research and Design Inst. of Monomers, Tula (Russian Federation); and others
The hydroformylation of 1-octene in the presence of Co{sub 3}(CO){sub 9}({mu}-CR) (R = H, Me, Ph, CO{sub 2}Me, CO{sub 2}Et, CO{sub 2}Pr{sup i}, CO{sub 2}Bu{sup t}, Cl, Br, OMe) alkylidynecarbonyl clusters, as well as triphenylphosphine derivatives of these complexes and heteronuclear Co{sub 2}Ni compounds have been studied. The nature of the catalytically active species in hydroformylation, as well as the processes of their formation and transformation during the reaction, have been established by means of IR spectroscopy, The effects of the reaction conditions, the nature of the substituent at the apical carbon atom, the electron donating phosphine substituent, and the substituent in the metal cluster framework have been discussed.
- OSTI ID:
- 223931
- Journal Information:
- Russian Chemical Bulletin, Journal Name: Russian Chemical Bulletin Journal Issue: 8 Vol. 42; ISSN 1066-5285; ISSN RCBUEY
- Country of Publication:
- United States
- Language:
- English
Similar Records
Features of hydroformylation in the presence of a rhodium complex with a macromolecular phosphine ligand
Force-Modulated Selectivity of the Rhodium-Catalyzed Hydroformylation of 1-Alkenes