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Title: Local rhombohedral symmetry in Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2} near the morphotropic phase boundary

Abstract

The recently reported morphotropic phase boundary (MPB) in a number of giant magnetostrictive materials (GMMs) has drawn considerable interest to the local symmetry/structure near MPB region of these materials. In this letter, by in-situ X-ray diffraction and AC magnetic susceptibility measurements, we show that Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2}, the typical composition of Terfenol-D GMMs, has coexistence of rhombohedral and tetragonal phases over a wide temperature range in the vicinity of MPB. High resolution transmission electron microscopy provides direct evidence for local rhombohedral symmetry of the ferromagnetic phase and reveals regular-shaped nanoscale domains below 10 nm. The nano-sized structural/magnetic domains are hierarchically inside a single micron-sized stripe-like domain with the same average magnetization direction. Such domain structures are consistent with the low magnetocrystalline anisotropy and easy magnetic/structural domain switching under magnetic field, thus generating large magnetostriction at low field.

Authors:
 [1]; ; ; ; ;  [1]; ;  [2];  [3]
  1. State Key Laboratory of Silicon Materials, Department of Materials Science and Engineering, Key Laboratory of Novel Materials for Information Technology of Zhejiang Province, Cyrus Tang Center for Sensor Materials and Applications, Zhejiang University, Hangzhou 310027 (China)
  2. Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049 (China)
  3. Ferroic Physics Group, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047, Ibaraki (Japan)
Publication Date:
OSTI Identifier:
22391957
Resource Type:
Journal Article
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 105; Journal Issue: 19; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0003-6951
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ANISOTROPY; DOMAIN STRUCTURE; DYSPROSIUM COMPOUNDS; IRON COMPOUNDS; MAGNETIC FIELDS; MAGNETIC SUSCEPTIBILITY; MAGNETIZATION; MAGNETOSTRICTION; NANOSTRUCTURES; SYMMETRY; TEMPERATURE RANGE; TERBIUM COMPOUNDS; TRANSMISSION ELECTRON MICROSCOPY; TRIGONAL LATTICES; X-RAY DIFFRACTION

Citation Formats

Ma, Tianyu, Ferroic Physics Group, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047, Ibaraki, Liu, Xiaolian, Pan, Xingwen, Li, Xiang, Jiang, Yinzhu, Yan, Mi, Li, Huiying, Fang, Minxia, Ren, Xiaobing, and Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049. Local rhombohedral symmetry in Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2} near the morphotropic phase boundary. United States: N. p., 2014. Web. doi:10.1063/1.4901646.
Ma, Tianyu, Ferroic Physics Group, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047, Ibaraki, Liu, Xiaolian, Pan, Xingwen, Li, Xiang, Jiang, Yinzhu, Yan, Mi, Li, Huiying, Fang, Minxia, Ren, Xiaobing, & Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049. Local rhombohedral symmetry in Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2} near the morphotropic phase boundary. United States. https://doi.org/10.1063/1.4901646
Ma, Tianyu, Ferroic Physics Group, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047, Ibaraki, Liu, Xiaolian, Pan, Xingwen, Li, Xiang, Jiang, Yinzhu, Yan, Mi, Li, Huiying, Fang, Minxia, Ren, Xiaobing, and Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049. Mon . "Local rhombohedral symmetry in Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2} near the morphotropic phase boundary". United States. https://doi.org/10.1063/1.4901646.
@article{osti_22391957,
title = {Local rhombohedral symmetry in Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2} near the morphotropic phase boundary},
author = {Ma, Tianyu and Ferroic Physics Group, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba 305-0047, Ibaraki and Liu, Xiaolian and Pan, Xingwen and Li, Xiang and Jiang, Yinzhu and Yan, Mi and Li, Huiying and Fang, Minxia and Ren, Xiaobing and Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710049},
abstractNote = {The recently reported morphotropic phase boundary (MPB) in a number of giant magnetostrictive materials (GMMs) has drawn considerable interest to the local symmetry/structure near MPB region of these materials. In this letter, by in-situ X-ray diffraction and AC magnetic susceptibility measurements, we show that Tb{sub 0.3}Dy{sub 0.7}Fe{sub 2}, the typical composition of Terfenol-D GMMs, has coexistence of rhombohedral and tetragonal phases over a wide temperature range in the vicinity of MPB. High resolution transmission electron microscopy provides direct evidence for local rhombohedral symmetry of the ferromagnetic phase and reveals regular-shaped nanoscale domains below 10 nm. The nano-sized structural/magnetic domains are hierarchically inside a single micron-sized stripe-like domain with the same average magnetization direction. Such domain structures are consistent with the low magnetocrystalline anisotropy and easy magnetic/structural domain switching under magnetic field, thus generating large magnetostriction at low field.},
doi = {10.1063/1.4901646},
url = {https://www.osti.gov/biblio/22391957}, journal = {Applied Physics Letters},
issn = {0003-6951},
number = 19,
volume = 105,
place = {United States},
year = {2014},
month = {11}
}