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Title: Superhydrophobic durable coating based on UV-photoreactive silica nanoparticles

Abstract

Superhydrophobic surfaces with contact angle (CA) >150 and sliding angle (SA) <10 have been aroused curiosity over the years due to their various applications. Superhydrophobicity can be obtained tailoring the chemistry and the roughness of the surface, mimicking the Lotus flower. Most superhydrophobic surfaces based on secondary bonding lose their roughness in harsh conditions and are unsuitable for practical applications. Photoreactive SiO{sub 2} nanoparticles (NPs) based on benzophenone (BP) can be a very effective tool for formation of reactive species that function as a molecular bridge by covalent bonding between the NP and any polymer matrix with C-C and C-H bonds. The present work focused on thermoset radiation curing urethane acrylate. Upon UV irradiation reactive excited nπ* triplet benzophenone species are formed and react through hydrogen abstraction to form ketyl radicals which interact with a radicals from the UV irradiated polymer matrix to yield covalent bonding. Roughness was achieved by dipping the substrate in SiO{sub 2}@BPs NPs dispersion followed by irradiation. Fluoroalkylsilane was used to obtain hydrophobic top layer. AFM nano manipulation was used to verify the immobilization of NPs. Evaluation of durability was made using air flow at 300 km/hr. Preliminary results indicate the formation of super hydrophobic surfaces (CA>150more » and SA<10) with improved stability.« less

Authors:
; ; ;  [1];  [2]
  1. Department of Plastics Engineering, Shenkar College of Engineering and Design, 12 Anna Frank Street, Ramat Gan 52526 (Israel)
  2. Department of Chemistry, Nanomaterials Research Center, Institute of Nanotechnology and Advanced Materials, Bar-Ilan University, Ramar-Gan, 52900 (Israel)
Publication Date:
OSTI Identifier:
22391856
Resource Type:
Journal Article
Journal Name:
AIP Conference Proceedings
Additional Journal Information:
Journal Volume: 1664; Journal Issue: 1; Conference: PPS-30: 30. International Conference of the Polymer Processing Society, Cleveland, OH (United States), 6-12 Jun 2014; Other Information: (c) 2015 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0094-243X
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ACRYLATES; ATOMIC FORCE MICROSCOPY; BONDING; BORON PHOSPHIDES; COVALENCE; HARDNESS; IRRADIATION; MATRIX MATERIALS; NANOPARTICLES; ORGANIC POLYMERS; RADIATION CURING; ROUGHNESS; SERVICE LIFE; SILICA; SILICON OXIDES; SUBSTRATES; SURFACES; ULTRAVIOLET RADIATION; URETHANE; WEAR RESISTANCE

Citation Formats

Nahum, T., Dodiuk, H., Dotan, A., Kenig, S., and Lellouche, J. P. Superhydrophobic durable coating based on UV-photoreactive silica nanoparticles. United States: N. p., 2015. Web. doi:10.1063/1.4918436.
Nahum, T., Dodiuk, H., Dotan, A., Kenig, S., & Lellouche, J. P. Superhydrophobic durable coating based on UV-photoreactive silica nanoparticles. United States. doi:10.1063/1.4918436.
Nahum, T., Dodiuk, H., Dotan, A., Kenig, S., and Lellouche, J. P. Fri . "Superhydrophobic durable coating based on UV-photoreactive silica nanoparticles". United States. doi:10.1063/1.4918436.
@article{osti_22391856,
title = {Superhydrophobic durable coating based on UV-photoreactive silica nanoparticles},
author = {Nahum, T. and Dodiuk, H. and Dotan, A. and Kenig, S. and Lellouche, J. P.},
abstractNote = {Superhydrophobic surfaces with contact angle (CA) >150 and sliding angle (SA) <10 have been aroused curiosity over the years due to their various applications. Superhydrophobicity can be obtained tailoring the chemistry and the roughness of the surface, mimicking the Lotus flower. Most superhydrophobic surfaces based on secondary bonding lose their roughness in harsh conditions and are unsuitable for practical applications. Photoreactive SiO{sub 2} nanoparticles (NPs) based on benzophenone (BP) can be a very effective tool for formation of reactive species that function as a molecular bridge by covalent bonding between the NP and any polymer matrix with C-C and C-H bonds. The present work focused on thermoset radiation curing urethane acrylate. Upon UV irradiation reactive excited nπ* triplet benzophenone species are formed and react through hydrogen abstraction to form ketyl radicals which interact with a radicals from the UV irradiated polymer matrix to yield covalent bonding. Roughness was achieved by dipping the substrate in SiO{sub 2}@BPs NPs dispersion followed by irradiation. Fluoroalkylsilane was used to obtain hydrophobic top layer. AFM nano manipulation was used to verify the immobilization of NPs. Evaluation of durability was made using air flow at 300 km/hr. Preliminary results indicate the formation of super hydrophobic surfaces (CA>150 and SA<10) with improved stability.},
doi = {10.1063/1.4918436},
journal = {AIP Conference Proceedings},
issn = {0094-243X},
number = 1,
volume = 1664,
place = {United States},
year = {2015},
month = {5}
}