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Title: Photosensitive response of azobenzene containing films towards pure intensity or polarization interference patterns

Abstract

In this paper, we report on differences in the response of photosensitive azobenzene containing films upon irradiation with the intensity or polarization interference patterns. Two materials are studied differing in the molecular weight: an azobenzene-containing polymer and a molecular glass formed from a much smaller molecule consisting of three connected azobenzene units. Topography changes occurring along with the changes in irradiation conditions are recorded using a homemade set-up combining an optical part for generation and shaping of interference patterns and an atomic force microscope for acquiring the kinetics of film deformation. In this way, we could reveal the unique behavior of photosensitive materials during the first few minutes of irradiation: the change in topography is initially driven by an increase in the azobenzene free volume along with the trans-cis isomerization, followed by the mass transport finally resulting in the surface relief grating. This study demonstrates the great potential of our setup to experimentally highlight puzzling processes governing the formation of surface relief gratings.

Authors:
;  [1];  [2]
  1. Department of Experimental Physics, Institute of Physics and Astronomy, University of Potsdam, 14476 Potsdam (Germany)
  2. Leibniz Institute of Polymer Research Dresden, 01069 Dresden (Germany)
Publication Date:
OSTI Identifier:
22314474
Resource Type:
Journal Article
Resource Relation:
Journal Name: Applied Physics Letters; Journal Volume: 105; Journal Issue: 5; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ATOMIC FORCE MICROSCOPY; BENZENE; GRATINGS; INTERFERENCE; ISOMERIZATION; POLARIZATION; POLYMERS; SURFACES; THIN FILMS

Citation Formats

Yadavalli, Nataraja Sekhar, Santer, Svetlana, E-mail: santer@uni-potsdam.de, and Saphiannikova, Marina. Photosensitive response of azobenzene containing films towards pure intensity or polarization interference patterns. United States: N. p., 2014. Web. doi:10.1063/1.4891615.
Yadavalli, Nataraja Sekhar, Santer, Svetlana, E-mail: santer@uni-potsdam.de, & Saphiannikova, Marina. Photosensitive response of azobenzene containing films towards pure intensity or polarization interference patterns. United States. doi:10.1063/1.4891615.
Yadavalli, Nataraja Sekhar, Santer, Svetlana, E-mail: santer@uni-potsdam.de, and Saphiannikova, Marina. Mon . "Photosensitive response of azobenzene containing films towards pure intensity or polarization interference patterns". United States. doi:10.1063/1.4891615.
@article{osti_22314474,
title = {Photosensitive response of azobenzene containing films towards pure intensity or polarization interference patterns},
author = {Yadavalli, Nataraja Sekhar and Santer, Svetlana, E-mail: santer@uni-potsdam.de and Saphiannikova, Marina},
abstractNote = {In this paper, we report on differences in the response of photosensitive azobenzene containing films upon irradiation with the intensity or polarization interference patterns. Two materials are studied differing in the molecular weight: an azobenzene-containing polymer and a molecular glass formed from a much smaller molecule consisting of three connected azobenzene units. Topography changes occurring along with the changes in irradiation conditions are recorded using a homemade set-up combining an optical part for generation and shaping of interference patterns and an atomic force microscope for acquiring the kinetics of film deformation. In this way, we could reveal the unique behavior of photosensitive materials during the first few minutes of irradiation: the change in topography is initially driven by an increase in the azobenzene free volume along with the trans-cis isomerization, followed by the mass transport finally resulting in the surface relief grating. This study demonstrates the great potential of our setup to experimentally highlight puzzling processes governing the formation of surface relief gratings.},
doi = {10.1063/1.4891615},
journal = {Applied Physics Letters},
number = 5,
volume = 105,
place = {United States},
year = {Mon Aug 04 00:00:00 EDT 2014},
month = {Mon Aug 04 00:00:00 EDT 2014}
}
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