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Synthesis and crystal structure of α,β-unsaturated ketone: 3,3′-[1,2-ethanediylbis(oxy-2,1-phenylene)]bis[1-(2-pyridyl)-2-propen-1-one]

Journal Article · · Crystallography Reports
;  [1]
  1. Yuncheng University, Department of Applied Chemistry (China)

The title compound, C{sub 30}H{sub 24}N{sub 2}O{sub 4}, 3,3′-[1,2-ethanediyl-bis(oxy-2,1-phenylene)]bis[1-(2-pyridyl)-2-propen-1-one] was synthesized and characterized by elemental analysis, FT-IR spectra, {sup 1}H NMR, and X-ray single-crystal diffraction. In the molecule, the pyridine plane and the adjacent phenyl plane are almost coplanar with the dihedral angle of 3.07°, while the dihedral angle between the mean planes of the two asymmetric units is 67.56°. The crystal packing is stabilized by weak intermolecular C-H...N and C-H...O hydrogen bonds, C-H...π and π...π stacking interactions.

OSTI ID:
22311401
Journal Information:
Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 7 Vol. 58; ISSN 1063-7745; ISSN CYSTE3
Country of Publication:
United States
Language:
English