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Title: Local charge transport properties of hydrazine reduced monolayer graphene oxide sheets prepared under pressure condition

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4895072· OSTI ID:22311037
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  1. Nano-Science Center and Department of Chemistry, University of Copenhagen, Universitetparken 5, 2100 Københaven Ø (Denmark)

Charge transport properties of chemically reduced graphene oxide (RGO) sheets prepared by treatment with hydrazine were examined using conductive atomic force microscopy. The current-voltage (I-V) characteristics of monolayer RGO sheets prepared under atmospheric pressure followed an exponentially increase due to 2D variable-range hopping conduction through small graphene domains in an RGO sheet containing defect regions of residual sp{sup 3} carbon clusters bonded to oxygen groups, whereas RGO sheets prepared in a closed container under moderate pressure showed linear I-V characteristics with a conductivity of 267.2−537.5 S/m. It was found that the chemical reduction under pressure results in larger graphene domains (sp{sup 2} networks) in the RGO sheets when compared to that prepared under atmospheric pressure, indicating that the present reduction of GO sheets under the pressure is one of the effective methods to make well-reduced GO sheets.

OSTI ID:
22311037
Journal Information:
Applied Physics Letters, Vol. 105, Issue 9; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English