Selective oxidation of rhodinol to citral using H{sub 2}O{sub 2}-platinum black system under microwave irradiation
Journal Article
·
· AIP Conference Proceedings
- School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)
- Department of Chemistry, Gadjah Mada University, Yogyakarta (Indonesia)
The oxidation method utilising H{sub 2}O{sub 2}-Pt black system was successfully adapted in the oxidation of rhodinol which is a mixture form of geraniol and citronellol. This green oxidation found to be selectively converted geraniol to citral using conventional method. The implementation of microwave irradiation (175 Watt, 90°C, 30 mins) and a higher molar of H{sub 2}O{sub 2} further improved the conversion rate (72.6%) and selectivity (81%) as compared to the conventional method.
- OSTI ID:
- 22308335
- Journal Information:
- AIP Conference Proceedings, Vol. 1614, Issue 1; Conference: 2014 UKM FST postgraduate colloquium, Selangor (Malaysia), 9-11 Apr 2014; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
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