Spectral studies of copper(II) complexes of 6-(3-thienyl) pyridine-2-thiosemicarbazone
Journal Article
·
· AIP Conference Proceedings
- School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor (Malaysia)
Two novel copper(II) complexes [Cu(HL)Cl]Cl.H{sub 2}O (1) and [Cu(L)NO{sub 3}]Ðœ‡H{sub 2}O (2) of the three NNS donor thiosemicarbazone ligand 6-(3-thienyl) pyridine-2-thiosemicarbazone have been synthesized. The ligand and its copper(II) complexes were characterized by elemental analysis (C, H, N, and S), FT-IR, UV-visible, magnetic susceptibility and molar conductance. The thiosemicarbazone is present either as the thione form in complex 1 or as thiol form in complex 2 and is coordinated to copper(II) atom via the pyridine nitrogen atom, the azomethine nitrogen atom and the sulfur atom. The physicochemical and spectral data suggest square planar geometry for copper(II) atoms.
- OSTI ID:
- 22308316
- Journal Information:
- AIP Conference Proceedings, Vol. 1614, Issue 1; Conference: 2014 UKM FST postgraduate colloquium, Selangor (Malaysia), 9-11 Apr 2014; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
Similar Records
Crystal structures of copper(II) chloride, copper(II) bromide, and copper(II) nitrate complexes with pyridine-2-carbaldehyde thiosemicarbazone
Synthesis, Characterization, and Biological Activity of Hybrid Thiosemicarbazone–Alkylthiocarbamate Metal Complexes
Syntheses and structures of three heterometallic coordination polymers derived from 4-pyridin-3-yl-benzoic acid
Journal Article
·
Mon Sep 15 00:00:00 EDT 2008
· Crystallography Reports
·
OSTI ID:22308316
+4 more
Synthesis, Characterization, and Biological Activity of Hybrid Thiosemicarbazone–Alkylthiocarbamate Metal Complexes
Journal Article
·
Wed Mar 11 00:00:00 EDT 2020
· Inorganic Chemistry
·
OSTI ID:22308316
+5 more
Syntheses and structures of three heterometallic coordination polymers derived from 4-pyridin-3-yl-benzoic acid
Journal Article
·
Tue Apr 01 00:00:00 EDT 2014
· Journal of Solid State Chemistry
·
OSTI ID:22308316