Distributive Nd-to-Yb Energy Transfer within Pure [YbNdYb] Heterometallic Molecules

Maniaki, Diamantoula; Sickinger, Annika; Barrios Moreno, Leoní A.; Aguilà, David; Roubeau, Olivier; Settineri, Nicholas S.; Guyot, Yannick; Riobé, François; Maury, Olivier; Galán, Laura Abad; Aromí, Guillem

doi:10.1021/acs.inorgchem.2c03940

Distributive Nd-to-Yb Energy Transfer within Pure [YbNdYb] Heterometallic Molecules

Journal Article · Wed Feb 08 00:00:00 EST 2023 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.2c03940· OSTI ID:2229874

Maniaki, Diamantoula ^[1]; ^[2]; ^[1]; ^[1]; ^[3]; ^[4]; Guyot, Yannick ^[5]; ^[2]; ^[2]; Galán, Laura Abad ^[6]; ^[1]

Universitat de Barcelona (Spain); Institute of Nanoscience and Nanotechnology of the University of Barcelona (IN2UB) (Spain)
Laboratoire de Chimie, UMR 5182, CNRS, ENS Lyon, Université de Lyon (France)
Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC and Universidad de Zaragoza (Spain)
University of California, Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
Institut Lumière Matière, UMR 5306 CNRS-Université Claude Bernard, Université de Lyon (France)
Universidad Complutense de Madrid (Spain)

Facile access to site-selective hetero-lanthanide molecules will open new avenues in the search of novel photophysical phenomena based on Ln-to-Ln' energy transfer (ET). This challenge demands strategies to segregate efficiently different Ln metal ions among different positions in a molecule. We report here the one-step synthesis and structure of a pure [YbNdYb] (1) coordination complex featuring short Yb···Nd distances, ideal to investigate a potential distributive (i.e., from one donor to two acceptors) intramolecular ET from one Nd³⁺ ion to two Yb³⁺ centers within a well-characterized molecule. The difference in ionic radius is the mechanism allowing to allocate selectively both types of metal ion within the molecular structure, exploited with the simultaneous use of two β-diketone-type ligands. To assist the photophysical investigation of this heterometallic species, the analogues [YbLaYb] (2) and [LuNdLu] (3) have also been prepared. Sensitization of Yb³⁺ and Nd³⁺ in the last two complexes, respectively, was observed, with remarkably long decay times, facilitating the determination of the Nd-to-Yb ET within the [YbNdYb] composite. This ET was demonstrated by comparing the emission of iso-absorbant solutions of 1, 2, and 3 and through lifetime determinations in solution and solid state. The comparatively high efficiency of this process corroborates the facilitating effect of having two acceptors for the nonradiative decay of Nd³⁺ created within the [YbNdYb] molecule.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: Generalitat de Catalunya; State Research Agency (AEI); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities (SUF)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 2229874

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 7 Vol. 62; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (83)

Unequivocal Synthetic Pathway to Heterodinuclear (4f,4f′) Complexes: Magnetic Study of Relevant (LnIII, GdIII) and (GdIII, LnIII) Complexes Costes, Jean-Pierre; Nicodème, Franck Chemistry - A European Journal, Vol. 8, Issue 15 https://doi.org/10.1002/1521-3765(20020802)8:15<3442::AID-CHEM3442>3.0.CO;2-Z	journal	August 2002
Luminescence of Lanthanide Ions in Coordination Compounds and Nanomaterials de Bettencourt‐Dias, Ana John Wiley and Sons, Ltd https://doi.org/10.1002/9781118682760	book	October 2014
Near-Infrared→Visible Light Upconversion in a Molecular Trinuclear d-f-d Complex Aboshyan-Sorgho, Lilit; Besnard, Céline; Pattison, Phil Angewandte Chemie International Edition, Vol. 50, Issue 18 https://doi.org/10.1002/anie.201100095	journal	April 2011
Cooperative Luminescence and Cooperative Sensitisation Upconversion of Lanthanide Complexes in Solution Knighton, Richard C.; Soro, Lohona K.; Francés‐Soriano, Laura Angewandte Chemie International Edition, Vol. 61, Issue 4 https://doi.org/10.1002/anie.202113114	journal	December 2021
Programming Heteropolymetallic Lanthanide Helicates: Thermodynamic Recognition of Different Metal Ions Along the Strands Floquet, Sébastien; Borkovec, Michal; Bernardinelli, Gérald Chemistry - A European Journal, Vol. 10, Issue 5 https://doi.org/10.1002/chem.200305498	journal	March 2004
The Rich Stereochemistry of Eight-Vertex Polyhedra: A Continuous Shape Measures Study Casanova, David; Llunell, Miquel; Alemany, Pere Chemistry - A European Journal, Vol. 11, Issue 5 https://doi.org/10.1002/chem.200400799	journal	February 2005
Lanthanide Contraction within a Series of Asymmetric Dinuclear [Ln ₂ ] Complexes Aguilà, David; Barrios, Leoní A.; Velasco, Verónica Chemistry - A European Journal, Vol. 19, Issue 19 https://doi.org/10.1002/chem.201204451	journal	March 2013
Heterodinuclear Lanthanoid-Containing Polyoxometalates: Stepwise Synthesis and Single-Molecule Magnet Behavior Sato, Rinta; Suzuki, Kosuke; Sugawa, Midori Chemistry - A European Journal, Vol. 19, Issue 39 https://doi.org/10.1002/chem.201302596	journal	September 2013
Ytterbium(III) Porpholactones: β-Lactonization of Porphyrin Ligands Enhances Sensitization Efficiency of Lanthanide Near-Infrared Luminescence Ke, Xian-Sheng; Yang, Bo-Yan; Cheng, Xin Chemistry - A European Journal, Vol. 20, Issue 15 https://doi.org/10.1002/chem.201303972	journal	March 2014
Lanthanide Complexes of Azidophenacyl‐DO3A as New Synthons for Click Chemistry and the Synthesis of Heterometallic Lanthanide Arrays Tropiano, Manuel; Kenwright, Alan M.; Faulkner, Stephen Chemistry – A European Journal, Vol. 21, Issue 15 https://doi.org/10.1002/chem.201500188	journal	March 2015
Thermodynamic Stability of Heterodimetallic [LnLn′] Complexes: Synthesis and DFT Studies Gónzalez-Fabra, Joan; Bandeira, Nuno A. G.; Velasco, Verónica Chemistry - A European Journal, Vol. 23, Issue 21 https://doi.org/10.1002/chem.201700095	journal	March 2017
Controlled Heterometallic Composition in Linear Trinuclear [LnCeLn] Lanthanide Molecular Assemblies Velasco, Verónica; Barrios, Leoní A.; Schütze, Mike Chemistry – A European Journal, Vol. 25, Issue 67 https://doi.org/10.1002/chem.201903829	journal	October 2019
Luminescence‐Driven Electronic Structure Determination in a Textbook Dimeric Dy^III‐Based Single‐Molecule Magnet Guettas, Djamila; Gendron, Frédéric; Fernandez Garcia, Guglielmo Chemistry – A European Journal, Vol. 26, Issue 19 https://doi.org/10.1002/chem.201905493	journal	March 2020
Accessing Lanthanide‐to‐Lanthanide Energy Transfer in a Family of Site‐Resolved [Ln^IIILn^III′] Heterodimetallic Complexes Abad Galán, Laura; Aguilà, David; Guyot, Yannick Chemistry – A European Journal, Vol. 27, Issue 25 https://doi.org/10.1002/chem.202005327	journal	March 2021
Excited State Properties of Lanthanide(III) Complexes with a Nonadentate Bispidine Ligand Abad‐Galán, Laura; Cieslik, Patrick; Comba, Peter Chemistry – A European Journal, Vol. 27, Issue 40 https://doi.org/10.1002/chem.202005459	journal	May 2021
Cover Picture: Ln₃Q₉ as a Molecular Framework for Ion‐Size‐Driven Assembly of Heterolanthanide (Nd, Er, Yb) Multiple Near‐Infrared Emitters (Chem. Eur. J. 10/2015) Artizzu, Flavia; Quochi, Francesco; Marchiò, Luciano Chemistry – A European Journal, Vol. 21, Issue 10 https://doi.org/10.1002/chem.404435	journal	February 2015
The Role of Functionalisation, Asymmetry and Shape of a New Macrocyclic Compartmental Ligand in the Formation of Mononuclear, Homo‐ and Heterodinuclear Lanthanide(III) Complexes Tamburini, Sergio; Sitran, Sergio; Peruzzo, Valentina European Journal of Inorganic Chemistry, Vol. 2009, Issue 1 https://doi.org/10.1002/ejic.200800394	journal	December 2008
Engineering of Lanthanide-Doped Upconversion Nanoparticles for Optical Encoding Huang, Kai; Idris, Niagara Muhammad; Zhang, Yong Small, Vol. 12, Issue 7 https://doi.org/10.1002/smll.201502722	journal	December 2015
A mini-review on recent progress of new sensitizers for luminescence of lanthanide doped nanomaterials Zhang, Hongxin; Chen, Zi-Han; Liu, Xuan Nano Research, Vol. 13, Issue 7 https://doi.org/10.1007/s12274-020-2661-8	journal	February 2020
Energy transfer in solution of lanthanide complexes Lis, S.; Elbanowski, M.; Mąkowska, B. Journal of Photochemistry and Photobiology A: Chemistry, Vol. 150, Issue 1-3 https://doi.org/10.1016/S1010-6030(01)00637-2	journal	July 2002
Synthesis, structure, reactivity and photoluminescence of lanthanide(III) monoporphyrinate complexes Wong, W.; Zhu, X.; Wong, W. Coordination Chemistry Reviews, Vol. 251, Issue 17-20 https://doi.org/10.1016/j.ccr.2006.11.014	journal	September 2007
Design of luminescent lanthanide complexes: From molecules to highly efficient photo-emitting materials Armelao, L.; Quici, S.; Barigelletti, F. Coordination Chemistry Reviews, Vol. 254, Issue 5-6 https://doi.org/10.1016/j.ccr.2009.07.025	journal	March 2010
Mechanisms of sensitization of lanthanide(III)-based luminescence in transition metal/lanthanide and anthracene/lanthanide dyads Ward, Michael D. Coordination Chemistry Reviews, Vol. 254, Issue 21-22 https://doi.org/10.1016/j.ccr.2009.12.001	journal	November 2010
Recent advances in the sensitized luminescence of organic europium complexes Ma, Yan; Wang, Yuan Coordination Chemistry Reviews, Vol. 254, Issue 9-10 https://doi.org/10.1016/j.ccr.2010.02.013	journal	May 2010
Charge transfer excited states sensitization of lanthanide emitting from the visible to the near-infra-red D’Aléo, Anthony; Pointillart, Fabrice; Ouahab, Lahcène Coordination Chemistry Reviews, Vol. 256, Issue 15-16 https://doi.org/10.1016/j.ccr.2012.03.023	journal	August 2012
Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications Cui, Yuanjing; Chen, Banglin; Qian, Guodong Coordination Chemistry Reviews, Vol. 273-274 https://doi.org/10.1016/j.ccr.2013.10.023	journal	August 2014
Luminescent 4f and d-4f polynuclear complexes and coordination polymers with flexible salen-type ligands Yang, Xiaoping; Jones, Richard A.; Huang, Shaoming Coordination Chemistry Reviews, Vol. 273-274 https://doi.org/10.1016/j.ccr.2013.11.012	journal	August 2014
Recent advances in lanthanide luminescence with metal-organic chromophores as sensitizers Xu, Liang-Jin; Xu, Guang-Tao; Chen, Zhong-Ning Coordination Chemistry Reviews, Vol. 273-274 https://doi.org/10.1016/j.ccr.2013.11.021	journal	August 2014
Upconversion of light with molecular and supramolecular lanthanide complexes Nonat, Aline M.; Charbonnière, Loïc J. Coordination Chemistry Reviews, Vol. 409 https://doi.org/10.1016/j.ccr.2020.213192	journal	May 2020
A new Eu(III)/Tb(III) binuclear coordination compound with crown ethers and bridging 4,4′-dipyridyl Belian, Mônica F.; Freire, Ricardo O.; Galembeck, André Journal of Luminescence, Vol. 130, Issue 10 https://doi.org/10.1016/j.jlumin.2010.05.010	journal	October 2010
Efficient near-infrared down conversion in Nd 3+ -Yb 3+ co-doped transparent nanostructured glass ceramics for photovoltaic application Tai, Yuping; Li, Xinzhong; Pan, Bingli Journal of Luminescence, Vol. 195 https://doi.org/10.1016/j.jlumin.2017.10.051	journal	March 2018
Broadband down-conversion based near infrared quantum cutting in Eu2+–Yb3+ co-doped SrAl2O4 for crystalline silicon solar cells Tai, Yuping; Zheng, Guojun; Wang, Hui Journal of Solid State Chemistry, Vol. 226 https://doi.org/10.1016/j.jssc.2015.02.020	journal	March 2015
Structure, optical absorption and NIR-Photoluminescence of ternary Neodymium (III) complexes with fluorinated β-diketone and heterocyclic Lewis bases Ganaie, Aabid B.; Iftikhar, K. Journal of Molecular Structure, Vol. 1273 https://doi.org/10.1016/j.molstruc.2022.134352	journal	February 2023
Improving spectral modification for applications in solar cells: A review Day, Joseph; Senthilarasu, S.; Mallick, Tapas K. Renewable Energy, Vol. 132 https://doi.org/10.1016/j.renene.2018.07.101	journal	March 2019
Sorting Phenomena and Chirality Transfer in Fluoride-Bridged Macrocyclic Rare Earth Complexes Ślepokura, Katarzyna; Cabreros, Trevor A.; Muller, Gilles Inorganic Chemistry, Vol. 60, Issue 23 https://doi.org/10.1021/acs.inorgchem.1c03034	journal	November 2021
Luminescence and Single-Molecule Magnet Behavior in Lanthanide Complexes Involving a Tetrathiafulvalene-Fused Dipyridophenazine Ligand Pointillart, Fabrice; Jung, Julie; Berraud-Pache, Romain Inorganic Chemistry, Vol. 54, Issue 11 https://doi.org/10.1021/acs.inorgchem.5b00441	journal	May 2015
Synthesis of Inert Homo- and Heterodinuclear Rare-Earth Cryptates Wahsner, Jessica; Seitz, Michael Inorganic Chemistry, Vol. 54, Issue 20 https://doi.org/10.1021/acs.inorgchem.5b01922	journal	October 2015
Selective Lanthanide Distribution within a Comprehensive Series of Heterometallic [LnPr] Complexes Aguilà, David; Velasco, Verónica; Barrios, Leoní A. Inorganic Chemistry, Vol. 57, Issue 14 https://doi.org/10.1021/acs.inorgchem.8b01112	journal	June 2018
Dye-Sensitized Downconversion Wang, Zijun; Meijerink, Andries The Journal of Physical Chemistry Letters, Vol. 9, Issue 7 https://doi.org/10.1021/acs.jpclett.8b00516	journal	March 2018
Structural and Photophysical Studies on Geometric (Er₂Yb₂/Yb₂Er₂) and Configurational (EuTb₃/Eu₃Tb) Isomers of Heterotetranuclear Lanthanide(III) Complexes Xu, Hai-Bing; Deng, Jian-Guo; Zhang, Li-Yi Crystal Growth & Design, Vol. 13, Issue 2 https://doi.org/10.1021/cg3015546	journal	December 2012
Upconversion Nanoparticles: Design, Nanochemistry, and Applications in Theranostics Chen, Guanying; Qiu, Hailong; Prasad, Paras N. Chemical Reviews, Vol. 114, Issue 10 https://doi.org/10.1021/cr400425h	journal	March 2014
Lanthanide-Based Luminescent Hybrid Materials Binnemans, Koen Chemical Reviews, Vol. 109, Issue 9 https://doi.org/10.1021/cr8003983	journal	September 2009
Lanthanide Luminescence for Biomedical Analyses and Imaging Bünzli, Jean-Claude G. Chemical Reviews, Vol. 110, Issue 5 https://doi.org/10.1021/cr900362e	journal	May 2010
High-Resolution Optical Spectroscopy of Na₃[Ln(dpa)₃]·13H₂O with Ln = Er³⁺, Tm³⁺, Yb³⁺ Reinhard, Christine; Güdel, Hans U. Inorganic Chemistry, Vol. 41, Issue 5 https://doi.org/10.1021/ic0108484	journal	February 2002
Structure-Based Description of a Step-by-Step Synthesis of Homo- and Heterodinuclear (4f, 4f ‘) Lanthanide Complexes Costes, Jean-Pierre; Dahan, Françoise; Nicodème, Franck Inorganic Chemistry, Vol. 42, Issue 20 https://doi.org/10.1021/ic034564q	journal	October 2003
Supramolecular Recognition of Heteropairs of Lanthanide Ions: A Step toward Self-Assembled Bifunctional Probes André, Nicolas; Jensen, Thomas B.; Scopelliti, Rosario Inorganic Chemistry, Vol. 43, Issue 2 https://doi.org/10.1021/ic0351996	journal	January 2004
Enantiomeric Self-Recognition in Homo- and Heterodinuclear Macrocyclic Lanthanide(III) Complexes Lisowski, Jerzy Inorganic Chemistry, Vol. 50, Issue 12 https://doi.org/10.1021/ic2001909	journal	May 2011
A Series of Tetrathiafulvalene-Based Lanthanide Complexes Displaying Either Single Molecule Magnet or Luminescence—Direct Magnetic and Photo-Physical Correlations in the Ytterbium Analogue Pointillart, Fabrice; Le Guennic, Boris; Cauchy, Thomas Inorganic Chemistry, Vol. 52, Issue 10 https://doi.org/10.1021/ic400253m	journal	April 2013
Near-Infrared Luminescence of Nine-Coordinate Neodymium Complexes with Benzimidazole-Substituted 8-Hydroxyquinolines Shavaleev, Nail M.; Scopelliti, Rosario; Gumy, Frédéric Inorganic Chemistry, Vol. 47, Issue 19 https://doi.org/10.1021/ic8010585	journal	August 2008
Lanthanide-Sensitized Lanthanide Luminescence: Terbium-Sensitized Ytterbium Luminescence in a Trinuclear Complex Faulkner, Stephen; Pope, Simon J. A. Journal of the American Chemical Society, Vol. 125, Issue 35 https://doi.org/10.1021/ja035634v	journal	September 2003
Purely Heterometallic Lanthanide(III) Macrocycles through Controlled Assembly of Disulfide Bonds for Dual Color Emission Lewis, David J.; Glover, Peter B.; Solomons, Melissa C. Journal of the American Chemical Society, Vol. 133, Issue 4 https://doi.org/10.1021/ja109157g	journal	February 2011
d−f Heterobimetallic Association between Ytterbium and Ruthenium Carbon-Rich Complexes: Redox Commutation of Near-IR Luminescence Di Piazza, Emmanuel; Norel, Lucie; Costuas, Karine Journal of the American Chemical Society, Vol. 133, Issue 16 https://doi.org/10.1021/ja2023515	journal	April 2011
Heterodimetallic [LnLn′] Lanthanide Complexes: Toward a Chemical Design of Two-Qubit Molecular Spin Quantum Gates Aguilà, David; Barrios, Leoní A.; Velasco, Verónica Journal of the American Chemical Society, Vol. 136, Issue 40 https://doi.org/10.1021/ja507809w	journal	August 2014
Synthesis and Spectroscopic Studies on Azo-Dye Derivatives of Polymetallic Lanthanide Complexes: Using Diazotization to Link Metal Complexes Together Placidi, Matteo P.; Villaraza, Aaron Joseph L.; Natrajan, Louise S. Journal of the American Chemical Society, Vol. 131, Issue 29 https://doi.org/10.1021/ja904362f	journal	July 2009
Upconversion in a d–f [RuYb₃] Supramolecular Assembly Knighton, Richard C.; Soro, Lohona K.; Thor, Waygen Journal of the American Chemical Society, Vol. 144, Issue 29 https://doi.org/10.1021/jacs.2c05037	journal	June 2022
Molecular Upconversion in Water in Heteropolynuclear Supramolecular Tb/Yb Assemblies Nonat, Aline; Bahamyirou, Sylvana; Lecointre, Alexandre Journal of the American Chemical Society, Vol. 141, Issue 4 https://doi.org/10.1021/jacs.8b10932	journal	December 2018
Upconversion Modulation through Pulsed Laser Excitation for Anti-counterfeiting Han, Yingdong; Li, Hongyu; Wang, Yangbo Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-01611-9	journal	May 2017
Lanthanide luminescence for functional materials and bio-sciences Eliseeva, Svetlana V.; Bünzli, Jean-Claude G. Chem. Soc. Rev., Vol. 39, Issue 1 https://doi.org/10.1039/B905604C	journal	January 2010
Preparation and study of an f,f,f′,f′′ covalently linked tetranuclear hetero-trimetallic complex – a europium, terbium, dysprosium triad Sørensen, Thomas Just; Tropiano, Manuel; Blackburn, Octavia A. Chem. Commun., Vol. 49, Issue 8 https://doi.org/10.1039/C2CC35931F	journal	January 2013
Hybrid materials based on lanthanide organic complexes: a review Feng, Jing; Zhang, Hongjie Chem. Soc. Rev., Vol. 42, Issue 1 https://doi.org/10.1039/C2CS35069F	journal	January 2013
Enhancing solar cell efficiency: the search for luminescent materials as spectral converters Huang, Xiaoyong; Han, Sanyang; Huang, Wei Chem. Soc. Rev., Vol. 42, Issue 1 https://doi.org/10.1039/C2CS35288E	journal	January 2013
Photon upconversion in core–shell nanoparticles Chen, Xian; Peng, Denfeng; Ju, Qiang Chemical Society Reviews, Vol. 44, Issue 6 https://doi.org/10.1039/C4CS00151F	journal	January 2015
Energy transfer in lanthanide upconversion studies for extended optical applications Dong, Hao; Sun, Ling-Dong; Yan, Chun-Hua Chemical Society Reviews, Vol. 44, Issue 6 https://doi.org/10.1039/C4CS00188E	journal	January 2015
Tailoring functionality through synthetic strategy in heterolanthanide assemblies Artizzu, Flavia; Quochi, Francesco; Serpe, Angela Inorganic Chemistry Frontiers, Vol. 2, Issue 3 https://doi.org/10.1039/C4QI00188E	journal	January 2015
Magnetic interplay between two different lanthanides in a tris-phthalocyaninato complex: a viable synthetic route and detailed investigation in the bulk and on the surface Lan, Yanhua; Klyatskaya, Svetlana; Ruben, Mario Journal of Materials Chemistry C, Vol. 3, Issue 38 https://doi.org/10.1039/C5TC02011E	journal	January 2015
Controlling Nd-to-Yb energy transfer through a molecular approach Artizzu, Flavia; Serpe, Angela; Marchiò, Luciano Journal of Materials Chemistry C, Vol. 3, Issue 43 https://doi.org/10.1039/C5TC02985F	journal	January 2015
Dye-sensitized lanthanide-doped upconversion nanoparticles Wang, Xindong; Valiev, Rashid R.; Ohulchanskyy, Tymish Y. Chemical Society Reviews, Vol. 46, Issue 14 https://doi.org/10.1039/C7CS00053G	journal	January 2017
Tailored homo- and hetero- lanthanide porphyrin dimers: a synthetic strategy for integrating multiple spintronic functionalities into a single molecule Le Roy, Jennifer J.; Cremers, Jonathan; Thomlinson, Isabel A. Chemical Science, Vol. 9, Issue 45 https://doi.org/10.1039/C8SC03762K	journal	January 2018
Luminescence, chiroptical, magnetic andab initiocrystal-field characterizations of an enantiopure helicoidal Yb(iii) complex Gendron, Frédéric; Di Pietro, Sebastiano; Abad Galán, Laura Inorganic Chemistry Frontiers, Vol. 8, Issue 4 https://doi.org/10.1039/D0QI01194K	journal	January 2021
Modulated self-assembly of metal–organic frameworks Forgan, Ross S. Chemical Science, Vol. 11, Issue 18 https://doi.org/10.1039/D0SC01356K	journal	January 2020
A heterometallic [LnLn′Ln] lanthanide complex as a qubit with embedded quantum error correction Macaluso, Emilio; Rubín, Marcos; Aguilà, David Chemical Science, Vol. 11, Issue 38 https://doi.org/10.1039/D0SC03107K	journal	January 2020
Design of pure heterodinuclear lanthanoid cryptate complexes Buch, Christian D.; Hansen, Steen H.; Mitcov, Dmitri Chemical Science, Vol. 12, Issue 20 https://doi.org/10.1039/D1SC00987G	journal	January 2021
Unparalleled selectivity and electronic structure of heterometallic [LnLn′Ln] molecules as 3-qubit quantum gates Maniaki, Diamantoula; Garay-Ruiz, Diego; Barrios, Leoní A. Chemical Science, Vol. 13, Issue 19 https://doi.org/10.1039/D2SC00436D	journal	January 2022
Sensitised luminescence in lanthanide containing arrays and d–f hybrids Faulkner, Stephen; Natrajan, Louise S.; Perry, William S. Dalton Transactions, Issue 20 https://doi.org/10.1039/b902006c	journal	January 2009
Application of the Ugi four-component reaction to the synthesis of ditopic bifunctional chelating agents Tei, Lorenzo; Gugliotta, Giuseppe; Avedano, Stefano Organic & Biomolecular Chemistry, Vol. 7, Issue 21 https://doi.org/10.1039/b907932g	journal	January 2009
Controlled preparation of a heterometallic lanthanide complex containing different lanthanides in symmetrical binding pockets Natrajan, Louise S.; Villaraza, Aaron Joseph L.; Kenwright, Alan M. Chemical Communications, Issue 40 https://doi.org/10.1039/b913702e	journal	January 2009
Lanthanide ions as spectral converters for solar cells van der Ende, Bryan M.; Aarts, Linda; Meijerink, Andries Physical Chemistry Chemical Physics, Vol. 11, Issue 47 https://doi.org/10.1039/b913877c	journal	January 2009
Designing strategies for supramolecular luminescent complex of lanthanide–heterometal assembly Iki, Nobuhiko Supramolecular Chemistry, Vol. 23, Issue 1-2 https://doi.org/10.1080/10610278.2010.514915	journal	January 2011
Recent progress in lanthanide-doped luminescent glasses for solid-state lighting applications—a review Erol, Erdinç; Vahedigharehchopogh, Naji; Kıbrıslı, Orhan Journal of Physics: Condensed Matter, Vol. 33, Issue 48 https://doi.org/10.1088/1361-648X/ac22d9	journal	September 2021
Advances in Rare Earth Spectroscopy and Applications Dwivedi, Y.; Zilio, S. C. Journal of Nanoscience and Nanotechnology, Vol. 14, Issue 2 https://doi.org/10.1166/jnn.2014.9104	journal	February 2014
Photon Upconversion in Homogeneous Fluorescence-based Bioanalytical Assays Soukka, Tero; Rantanen, Terhi; Kuningas, Katri Annals of the New York Academy of Sciences, Vol. 1130, Issue 1 https://doi.org/10.1196/annals.1430.027	journal	May 2008
Room-temperature upconversion fiber laser tunable in the red, orange, green, and blue spectral regions Xie, Ping; Gosnell, T. R. Optics Letters, Vol. 20, Issue 9 https://doi.org/10.1364/OL.20.001014	journal	January 1995
Multi-NIR-Emissive Materials based on Heterolanthanide Molecular Assemblies Artizzu, Flavia; Quochi, Francesco; Marchiò, Luciano MRS Advances, Vol. 1, Issue 38 https://doi.org/10.1557/adv.2016.402	journal	May 2016

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