Infrared spectroscopy of large scale single layer graphene on self assembled organic monolayer
- Department of Chemistry, Seoul National University, Seoul 151-742 (Korea, Republic of)
We study the effect of self-assembled monolayer (SAM) organic molecule substrate on large scale single layer graphene using infrared transmission measurement on Graphene/SAM/SiO{sub 2}/Si composite samples. From the Drude weight of the chemically inert CH{sub 3}-SAM, the electron-donating NH{sub 2}-SAM, and the SAM-less graphene, we determine the carrier density doped into graphene by the three sources—the SiO{sub 2} substrate, the gas-adsorption, and the functional group of the SAM's—separately. The SAM-treatment leads to the low carrier density N ∼ 4 × 10{sup 11} cm{sup −2} by blocking the dominant SiO{sub 2}- driven doping. The carrier scattering increases by the SAM-treatment rather than decreases. However, the transport mobility is nevertheless improved due to the reduced carrier doping.
- OSTI ID:
- 22280556
- Journal Information:
- Applied Physics Letters, Vol. 104, Issue 4; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
- Country of Publication:
- United States
- Language:
- English
Similar Records
Self-Assembled Monolayers as Templates for Heme Crystallization
Self-Assembled Monolayers as Templates for Heme Crystallization.