Bandgap tuning in SrTi(N,O,F){sub 3} by anionic-lattice variation

Journal Article · Tue Oct 15 04:00:00 UTC 2013 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/J.JSSC.2013.08.001· OSTI ID:22278308

Yoon, Songhak; Maegli, Alexandra E.; Karvonen, Lassi; Matam, Santhosh K.; Shkabko, Andrey ^[1]; Riegg, Stefan ^[2]; Großmann, Thomas; Ebbinghaus, Stefan G. ^[3]; Pokrant, Simone ^[1]; Weidenkaff, Anke ^[1]

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1. Laboratory for Solid State Chemistry and Catalysis, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf (Switzerland)
2. Lehrstuhl für Experimentalphysik 5, EKM, Universität Augsburg, Universitätsstraße 1, 86135 Augsburg (Germany)
3. Institut für Chemie, Martin-Luther Universität Halle-Wittenberg, Kurt-Mothes-Straße 2, 06120 Halle/Saale (Germany)

Polycrystalline SrTiO{sub 3} and SrTi(O,F){sub 3} powders were synthesized by a solid-state reaction. A partial substitution of oxygen by nitrogen was subsequently carried out using thermal ammonolysis resulting in SrTi(N,O){sub 3} and SrTi(N,O,F){sub 3}. Powder X-ray diffraction (XRD) revealed a cubic perovskite structure with space group Pm-3m for all samples. The thermal ammonolysis slightly increased the lattice parameters, crystallite sizes and strain. As a result from the co-substitution of oxygen with nitrogen and fluorine for SrTi(N,O,F){sub 3}, highly distorted TiO{sub 6} octahedra were detected using X-ray absorption near edge structure (XANES) spectroscopy. The weakening of all active modes of the Raman spectra after thermal ammonolysis also indicated enhanced distortions in the local crystal structure. SrTi(N,O,F){sub 3} has the largest amount of nitrogen as well as fluorine among all four samples as determined by thermogravimetric analysis (TGA), elemental analysis and X-ray photoelectron spectroscopy (XPS). In the UV–vis spectra a distinctive shift of the absorption-edge energy was observed exclusively for the SrTi(N,O,F){sub 3} sample from 390 to 510 nm corresponding to a bandgap narrowing from 3.18 to 2.43 eV. - Graphical abstract: Figure shows the shift of the absorption-edge energy for the SrTi(N,O,F){sub 3} sample from 390 to 510 nm corresponding to a bandgap narrowing from 3.18 to 2.43 eV. Display Omitted - Highlights: • Synthesis of phase-pure SrTi(N,O,F){sub 3} via solid-state reaction. • The incorporated nitrogen contents increase by the presence of fluorine in SrTi(N,O,F){sub 3}. • Co-substitution with nitrogen and fluorine is beneficial for the bandgap narrowing compared to by only nitrogen or fluorine substitution.

• OSTI ID: 22278308
• Journal Information: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Vol. 206; ISSN 0022-4596; ISSN JSSCBI
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
ABSORPTION
ABSORPTION SPECTROSCOPY
AMMONOLYSIS
CRYSTAL STRUCTURE
FLUORINE
LATTICE PARAMETERS
PEROVSKITE
POLYCRYSTALS
RAMAN SPECTRA
RAMAN SPECTROSCOPY
SOLIDS
SPACE GROUPS
STRONTIUM
STRONTIUM TITANATES
THERMAL GRAVIMETRIC ANALYSIS
TITANIUM OXIDES
X RADIATION
X-RAY DIFFRACTION
X-RAY PHOTOELECTRON SPECTROSCOPY
X-RAY SPECTROSCOPY