Hydrogen plasma induced modification of photoluminescence from a-SiN{sub x}:H thin films

Journal Article · Fri Feb 07 04:00:00 EST 2014 · Journal of Applied Physics

DOI:https://doi.org/10.1063/1.4864255· OSTI ID:22278099

Bommali, R. K.; Ghosh, S.; Vijaya Prakash, G. ^[1]; Gao, K.; Zhou, S. ^[2]; Khan, S. A. ^[3]

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1. Nanophotonics Laboratory, Department of Physics, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110 016 (India)
2. Helmholtz-Zentrum Dresden-Rossendorf, Institute of Ion Beam Physics and Materials Research, P.O. Box-510119, 01314 Dresden (Germany)
3. Materials Science Division, Inter-University Accelerator Centre (IUAC), Aruna Asaf Ali Marg, New Delhi 110067 (India)

Low temperature (250–350 °C) hydrogen plasma annealing (HPA) treatments have been performed on amorphous hydrogenated silicon nitride (a-SiN{sub x}:H) thin films having a range of compositions and subsequent modification of photoluminescence (PL) is investigated. The PL spectral shape and peak positions for the as deposited films could be tuned with composition and excitation energies. HPA induced modification of PL of these films is found to depend on the N/Si ratio (x). Upon HPA, the PL spectra show an emergence of a red emission band for x ≤ 1, whereas an overall increase of intensity without change in the spectral shape is observed for x > 1. The emission observed in the Si rich films is attributed to nanoscale a-Si:H inclusions. The enhancement is maximum for off-stoichiometric films (x ∼ 1) and decreases as the compositions of a-Si (x = 0) and a-Si{sub 3}N{sub 4} (x = 1.33) are approached, implying high density of non-radiative defects around x = 1. The diffusion of hydrogen in these films is also analyzed by Elastic Recoil Detection Analysis technique.

• OSTI ID: 22278099
• Journal Information: Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 5 Vol. 115; ISSN JAPIAU; ISSN 0021-8979
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ANNEALING
EMISSION SPECTRA
EXCITATION
HYDROGEN
HYDROGENATION
MODIFICATIONS
NANOSTRUCTURES
PHOTOLUMINESCENCE
PLASMA
SILICON NITRIDES
TEMPERATURE DEPENDENCE
TEMPERATURE RANGE 0273-0400 K
TEMPERATURE RANGE 0400-1000 K
THIN FILMS