Investigation on visible quantum cutting of Tb{sup 3+} in oxide hosts
Journal Article
·
· Journal of Applied Physics
- School of Physics and Electronic Electrical Engineering, Huaiyin Normal University, 111 West Chang Jiang Road, Huai'an 223001 (China)
- Department of Material Science, School of Physical Science and Technology, Lanzhou University, Lanzhou 730000 (China)
- Laboratory of Beijing Synchrotron Radiation, Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049 (China)
Visible quantum cutting (QC) through downconversion was observed upon 4f{sup 8}-4f{sup 7}5d{sup 1} excitation of Tb{sup 3+} in both BaGdB{sub 9}O{sub 16} and Ca{sub 8}MgGd(PO{sub 4}){sub 7} compounds. The QC involves a cross relaxation process between two neighboring Tb{sup 3+}. Modified and new QC models are proposed based on the QC mechanisms in Gd{sup 3+}-Tb{sup 3+} system. Two calculation equations for the cross relaxation efficiency are suggested according to the energy transfer theory and spectral results. By studying the spectral characteristics of Tb{sup 3+} in hosts from fluoride to oxide, it indicates that the visible QC in Gd{sup 3+}-Tb{sup 3+} system may occur mainly depending on the structural features of phosphors, rather than the phonon energies of matrixes. All of the above conclusions have meaning of guidance for investigating other phosphors with QC phenomenon.
- OSTI ID:
- 22277930
- Journal Information:
- Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 9 Vol. 115; ISSN JAPIAU; ISSN 0021-8979
- Country of Publication:
- United States
- Language:
- English
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