Composition-Orientation Induced Mechanical Synergy in Nanoparticle Brushes with Grafted Gradient Copolymers

Yin, Rongguan; Zhao, Yuqi; Jeong, Jaepil; Tarnsangpradit, Jirameth; Liu, Tong; An, So Young; Zhai, Yue; Hu, Xiaolei; Bockstaller, Michael R.; Matyjaszewski, Krzysztof

doi:10.1021/acs.macromol.3c01799

Composition-Orientation Induced Mechanical Synergy in Nanoparticle Brushes with Grafted Gradient Copolymers

Journal Article · Wed Nov 29 00:00:00 EST 2023 · Macromolecules

DOI:https://doi.org/10.1021/acs.macromol.3c01799· OSTI ID:2222967

^[1]; ^[2]; ^[1]; Tarnsangpradit, Jirameth ^[2]; ^[1]; An, So Young ^[1]; Zhai, Yue ^[2]; ^[1]; ^[2]; ^[1]

Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, United States
Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, Pennsylvania 15213, United States

Not Available

View Journal Article

Research Organization:: Carnegie Mellon University, Pittsburgh, PA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0018784

OSTI ID:: 2222967

Alternate ID(s):: OSTI ID: 2229854

Journal Information:: Macromolecules, Journal Name: Macromolecules Journal Issue: 23 Vol. 56; ISSN 0024-9297

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (73)

Gradient copolymers by atom transfer radical copolymerization Matyjaszewski, Krzysztof; Ziegler, Michael J.; Arehart, Stephen V. Journal of Physical Organic Chemistry, Vol. 13, Issue 12 https://doi.org/10.1002/1099-1395(200012)13:12<775::AID-POC314>3.0.CO;2-D	journal	January 2000
Surface and Particle Modification via RAFT Polymerization: An Update Pribyl, Julia; Benicewicz, Brian C. RAFT Polymerization https://doi.org/10.1002/9783527821358.ch22	book	October 2021
Advanced Materials by Atom Transfer Radical Polymerization Matyjaszewski, Krzysztof Advanced Materials, Vol. 30, Issue 23 https://doi.org/10.1002/adma.201706441	journal	March 2018
Polydopamine and Its Derivative Surface Chemistry in Material Science: A Focused Review for Studies at KAIST Lee, Haesung A.; Park, Eunsook; Lee, Haeshin Advanced Materials, Vol. 32, Issue 35 https://doi.org/10.1002/adma.201907505	journal	March 2020
Oil-Soluble Polymer Brush Grafted Nanoparticles as Effective Lubricant Additives for Friction and Wear Reduction Wright, Roger A. E.; Wang, Kewei; Qu, Jun Angewandte Chemie International Edition, Vol. 55, Issue 30 https://doi.org/10.1002/anie.201603663	journal	June 2016
Sono-RAFT Polymerization in Aqueous Medium McKenzie, Thomas G.; Colombo, Enrico; Fu, Qiang Angewandte Chemie International Edition, Vol. 56, Issue 40 https://doi.org/10.1002/anie.201706771	journal	September 2017
Surface Grafting “Band‐Aid” for “Everyone”: Filter Paper‐Assisted Surface‐Initiated Polymerization in the Presence of Air Li, Wei; Sheng, Wenbo; Li, Bin Angewandte Chemie International Edition, Vol. 60, Issue 24 https://doi.org/10.1002/anie.202103182	journal	May 2021
Why Do We Need More Active ATRP Catalysts? Lorandi, Francesca; Matyjaszewski, Krzysztof Israel Journal of Chemistry, Vol. 60, Issue 1-2 https://doi.org/10.1002/ijch.201900079	journal	October 2019
Silica-Polymethacrylate Hybrid Particles Synthesized Using High-Pressure Atom Transfer Radical Polymerization: Silica-Polymethacrylate Hybrid Particles Synthesized Using High-Pressure … Pietrasik, Joanna; Hui, Chin Ming; Chaladaj, Wojciech Macromolecular Rapid Communications, Vol. 32, Issue 3 https://doi.org/10.1002/marc.201000531	journal	November 2010
Reactivity Ratio Estimation from Cumulative Copolymer Composition Data Kazemi, Niousha; Duever, Thomas A.; Penlidis, Alexander Macromolecular Reaction Engineering, Vol. 5, Issue 9-10 https://doi.org/10.1002/mren.201100009	journal	August 2011
Preparation of gradient copolymers via ATRP using a simultaneous reverse and normal initiation process. I. Spontaneous gradient Min, Ke; Li, Mei; Matyjaszewski, Krzysztof Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 16 https://doi.org/10.1002/pola.20809	journal	January 2005
Gradient copolymers with broad glass transition temperature regions: Design of purely interphase compositions for damping applications Mok, Michelle M.; Kim, Jungki; Torkelson, John M. Journal of Polymer Science Part B: Polymer Physics, Vol. 46, Issue 1 https://doi.org/10.1002/polb.21341	journal	January 2007
Gradient copolymers Beginn, Uwe Colloid and Polymer Science, Vol. 286, Issue 13 https://doi.org/10.1007/s00396-008-1922-y	journal	September 2008
Fabrication of gradient multilayer polymer with improved damping performance based on poly(butyl acrylate)-grafted polysiloxane Sheng, Zeyuan; Wang, Jincheng; Song, Shiqiang Journal of Materials Science, Vol. 55, Issue 25 https://doi.org/10.1007/s10853-020-04818-w	journal	May 2020
A systematic approach to the study of multicomponent polymerization kinetics?the butyl acrylate/methyl methacrylate/vinyl acetate example: 1. Bulk copolymerization Dube, M. Polymer, Vol. 36, Issue 3 https://doi.org/10.1016/0032-3861(95)91568-R	journal	January 1995
Gradient copolymers – Preparation, properties and practice Alam, Md. Mahbub; Jack, Kevin S.; Hill, David J. T. European Polymer Journal, Vol. 116 https://doi.org/10.1016/j.eurpolymj.2019.04.028	journal	July 2019
High-density polystyrene-grafted silver nanoparticles and their use in the preparation of nanocomposites with antibacterial properties Krystosiak, Piotr; Tomaszewski, Waldemar; Megiel, Elżbieta Journal of Colloid and Interface Science, Vol. 498 https://doi.org/10.1016/j.jcis.2017.03.041	journal	July 2017
Prediction of glass transition temperatures: Binary blends and copolymers Brostow, Witold; Chiu, Rachel; Kalogeras, Ioannis M. Materials Letters, Vol. 62, Issue 17-18 https://doi.org/10.1016/j.matlet.2008.02.008	journal	June 2008
Grafting polymer from oxygen-vacancy-rich nanoparticles to enable protective layers for stable lithium metal anode Li, Sipei; Liu, Tong; Yan, Jiajun Nano Energy, Vol. 76 https://doi.org/10.1016/j.nanoen.2020.105046	journal	October 2020
Small-angle neutron scattering study on block and gradient copolymer aqueous solutions Okabe, Satoshi; Seno, Ken-ichi; Kanaoka, Shokyoku Polymer, Vol. 47, Issue 21 https://doi.org/10.1016/j.polymer.2006.08.045	journal	October 2006
Surface-initiated controlled polymerization as a convenient method for designing functional polymer brushes: From self-assembled monolayers to patterned surfaces Olivier, Aurore; Meyer, Franck; Raquez, Jean-Marie Progress in Polymer Science, Vol. 37, Issue 1 https://doi.org/10.1016/j.progpolymsci.2011.06.002	journal	January 2012
Surface modification of inorganic nanoparticles for development of organic–inorganic nanocomposites—A review Kango, Sarita; Kalia, Susheel; Celli, Annamaria Progress in Polymer Science, Vol. 38, Issue 8 https://doi.org/10.1016/j.progpolymsci.2013.02.003	journal	August 2013
Brush-modified materials: Control of molecular architecture, assembly behavior, properties and applications Yan, Jiajun; Bockstaller, Michael R.; Matyjaszewski, Krzysztof Progress in Polymer Science, Vol. 100 https://doi.org/10.1016/j.progpolymsci.2019.101180	journal	January 2020
Complex polymer topologies and polymer—nanoparticle hybrid films prepared via surface-initiated controlled radical polymerization Mocny, Piotr; Klok, Harm-Anton Progress in Polymer Science, Vol. 100 https://doi.org/10.1016/j.progpolymsci.2019.101185	journal	January 2020
Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications Corrigan, Nathaniel; Jung, Kenward; Moad, Graeme Progress in Polymer Science, Vol. 111 https://doi.org/10.1016/j.progpolymsci.2020.101311	journal	December 2020
Organic–inorganic hybrid functional materials by nitroxide-mediated polymerization Beyou, Emmanuel; Bourgeat-Lami, Elodie Progress in Polymer Science, Vol. 121 https://doi.org/10.1016/j.progpolymsci.2021.101434	journal	October 2021
Copolymer Brush Particle Hybrid Materials with “Recall-and-Repair” Capability Zhao, Yuqi; Wu, Hanshu; Yin, Rongguan Chemistry of Materials, Vol. 35, Issue 17 https://doi.org/10.1021/acs.chemmater.3c01234	journal	August 2023
A Fatty Acid-Inspired Tetherable Initiator for Surface-Initiated Atom Transfer Radical Polymerization Yan, Jiajun; Pan, Xiangcheng; Wang, Zongyu Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b01338	journal	May 2017
Surface-Initiated Controlled Radical Polymerization: State-of-the-Art, Opportunities, and Challenges in Surface and Interface Engineering with Polymer Brushes Zoppe, Justin O.; Ataman, Nariye Cavusoglu; Mocny, Piotr Chemical Reviews, Vol. 117, Issue 3 https://doi.org/10.1021/acs.chemrev.6b00314	journal	January 2017
Surface-Initiated Photoinduced ATRP: Mechanism, Oxygen Tolerance, and Temporal Control during the Synthesis of Polymer Brushes Yan, Wenqing; Dadashi-Silab, Sajjad; Matyjaszewski, Krzysztof Macromolecules, Vol. 53, Issue 8 https://doi.org/10.1021/acs.macromol.0c00333	journal	April 2020
Distribution of Alternating Sequences in Methyl Methacrylate/n-Butyl Acrylate Copolymers Prepared by Atom Transfer Radical Polymerization Sosnowski, Stanislaw; Szymanski, Ryszard; Lorandi, Francesca Macromolecules, Vol. 54, Issue 21 https://doi.org/10.1021/acs.macromol.1c01930	journal	October 2021
Self-Healable Acrylic-Based Covalently Adaptable Networks Wang, Siyang; Li, Lei; Liu, Qianhui Macromolecules, Vol. 55, Issue 11 https://doi.org/10.1021/acs.macromol.2c00739	journal	June 2022
Miniemulsion SI-ATRP by Interfacial and Ion-Pair Catalysis for the Synthesis of Nanoparticle Brushes Yin, Rongguan; Chmielarz, Paweł; Zaborniak, Izabela Macromolecules, Vol. 55, Issue 15 https://doi.org/10.1021/acs.macromol.2c01114	journal	July 2022
Topologically Induced Heterogeneity in Gradient Copolymer Brush Particle Materials Zhao, Yuqi; Wang, Zongyu; Yu, Chenxi Macromolecules, Vol. 55, Issue 19 https://doi.org/10.1021/acs.macromol.2c01131	journal	July 2022
A Molecular Weight Distribution Polydispersity Equation for the ATRP System: Quantifying the Effect of Radical Termination Mastan, Erlita; Zhu, Shiping Macromolecules, Vol. 48, Issue 18 https://doi.org/10.1021/acs.macromol.5b01525	journal	September 2015
50th Anniversary Perspective : Are Polymer Nanocomposites Practical for Applications? Kumar, Sanat K.; Benicewicz, Brian C.; Vaia, Richard A. Macromolecules, Vol. 50, Issue 3 https://doi.org/10.1021/acs.macromol.6b02330	journal	January 2017
Harnessing the Interaction between Surfactant and Hydrophilic Catalyst To Control e ATRP in Miniemulsion Fantin, Marco; Chmielarz, Paweł; Wang, Yi Macromolecules, Vol. 50, Issue 9 https://doi.org/10.1021/acs.macromol.7b00530	journal	April 2017
Miniemulsion ARGET ATRP via Interfacial and Ion-Pair Catalysis: From ppm to ppb of Residual Copper Wang, Yi; Lorandi, Francesca; Fantin, Marco Macromolecules, Vol. 50, Issue 21 https://doi.org/10.1021/acs.macromol.7b01730	journal	November 2017
Pushing the Limit: Synthesis of SiO ₂ - g -PMMA/PS Particle Brushes via ATRP with Very Low Concentration of Functionalized SiO ₂ –Br Nanoparticles Wang, Zongyu; Fantin, Marco; Sobieski, Julian Macromolecules, Vol. 52, Issue 22 https://doi.org/10.1021/acs.macromol.9b01973	journal	November 2019
Fabrication and Deformation of Mechanochromic Nanocomposite Elastomers Based on Rubbery and Glassy Block Copolymer-Grafted Silica Nanoparticles Cheng, Chao-Hung; Masuda, Shiori; Nozaki, Shuhei Macromolecules, Vol. 53, Issue 11 https://doi.org/10.1021/acs.macromol.9b02031	journal	May 2020
Synthesis of Gradient Copolymer Grafted Particle Brushes by ATRP Wang, Zongyu; Liu, Tong; Zhao, Yuqi Macromolecules, Vol. 52, Issue 24 https://doi.org/10.1021/acs.macromol.9b02157	journal	December 2019
Facile Entropy-Driven Segregation of Imprinted Polymer-Grafted Nanoparticle Brush Blends by Solvent Vapor Annealing Soft Lithography Wu, Wenjie; Singh, Maninderjeet; Zhai, Yue ACS Applied Materials & Interfaces, Vol. 14, Issue 40 https://doi.org/10.1021/acsami.2c11134	journal	September 2022
Nanosized Organo-Silica Particles with “Built-In” Surface-Initiated Atom Transfer Radical Polymerization Capability as a Platform for Brush Particle Synthesis Han, Jin; Zhai, Yue; Wang, Zongyu ACS Macro Letters, Vol. 9, Issue 9 https://doi.org/10.1021/acsmacrolett.0c00502	journal	August 2020
Alternating Methyl Methacrylate/n-Butyl Acrylate Copolymer Prepared by Atom Transfer Radical Polymerization Yin, Rongguan; Zhao, Yuqi; Gorczyński, Adam ACS Macro Letters, Vol. 11, Issue 10 https://doi.org/10.1021/acsmacrolett.2c00517	journal	October 2022
Sequence-Enhanced Self-Healing in “Lock-and-Key” Copolymers Zhao, Yuqi; Yin, Rongguan; Wu, Hanshu ACS Macro Letters, Vol. 12, Issue 4 https://doi.org/10.1021/acsmacrolett.3c00055	journal	March 2023
Ultrasonication-Induced Aqueous Atom Transfer Radical Polymerization Wang, Zhenhua; Wang, Zhanhua; Pan, Xiangcheng ACS Macro Letters, Vol. 7, Issue 3 https://doi.org/10.1021/acsmacrolett.8b00027	journal	February 2018
Tuning Selectivities in Gas Separation Membranes Based on Polymer-Grafted Nanoparticles Bilchak, Connor R.; Jhalaria, Mayank; Huang, Yucheng ACS Nano, Vol. 14, Issue 12 https://doi.org/10.1021/acsnano.0c07049	journal	November 2020
Fluoro-Polymer@BaTiO ₃ Hybrid Nanoparticles Prepared via RAFT Polymerization: Toward Ferroelectric Polymer Nanocomposites with High Dielectric Constant and Low Dielectric Loss for Energy Storage Application Yang, Ke; Huang, Xingyi; Huang, Yanhui Chemistry of Materials, Vol. 25, Issue 11 https://doi.org/10.1021/cm4010486	journal	May 2013
Surface-Initiated Polymerization as an Enabling Tool for Multifunctional (Nano-)Engineered Hybrid Materials Hui, Chin Ming; Pietrasik, Joanna; Schmitt, Michael Chemistry of Materials, Vol. 26, Issue 1 https://doi.org/10.1021/cm4023634	journal	August 2013
Copolymerization. I. A Basis for Comparing the Behavior of Monomers in Copolymerization; The Copolymerization of Styrene and Methyl Methacrylate Mayo, Frank R.; Lewis, Frederick M. Journal of the American Chemical Society, Vol. 66, Issue 9 https://doi.org/10.1021/ja01237a052	journal	September 1944
Thermally Cross-Linked Superparamagnetic Iron Oxide Nanoparticles: Synthesis and Application as a Dual Imaging Probe for Cancer in Vivo Lee, Haerim; Yu, Mi Kyung; Park, Sangjin Journal of the American Chemical Society, Vol. 129, Issue 42 https://doi.org/10.1021/ja072210i	journal	October 2007
Flexible Particle Array Structures by Controlling Polymer Graft Architecture Choi, Jihoon; Dong, Hongchen; Matyjaszewski, Krzysztof Journal of the American Chemical Society, Vol. 132, Issue 36 https://doi.org/10.1021/ja105189s	journal	September 2010
One-Pot Synthesis of Robust Core/Shell Gold Nanoparticles Dong, Hongchen; Zhu, Manzhou; Yoon, Jeong Ae Journal of the American Chemical Society, Vol. 130, Issue 39 https://doi.org/10.1021/ja8038097	journal	October 2008
Polymethylene Brushes via Surface-Initiated C1 Polyhomologation Li, Feng; Thiele, Sophia; Klok, Harm-Anton Journal of the American Chemical Society, Vol. 143, Issue 47 https://doi.org/10.1021/jacs.1c09187	journal	November 2021
Grafting from Surfaces for “Everyone”: ARGET ATRP in the Presence of Air Matyjaszewski, Krzysztof; Dong, Hongchen; Jakubowski, Wojciech Langmuir, Vol. 23, Issue 8 https://doi.org/10.1021/la063402e	journal	April 2007
Interfacial Activity of Gradient Copolymers Shull, Kenneth R. Macromolecules, Vol. 35, Issue 22 https://doi.org/10.1021/ma020698w	journal	October 2002
Synthesis and Characterization of Organic/Inorganic Hybrid Nanoparticles: Kinetics of Surface-Initiated Atom Transfer Radical Polymerization and Morphology of Hybrid Nanoparticle Ultrathin Films Pyun, Jeffrey; Jia, Shijun; Kowalewski, Tomasz Macromolecules, Vol. 36, Issue 14 https://doi.org/10.1021/ma034188t	journal	July 2003
Synthesis of Monodisperse Silica Particles Coated with Well-Defined, High-Density Polymer Brushes by Surface-Initiated Atom Transfer Radical Polymerization Ohno, Kohji; Morinaga, Takashi; Koh, Kyoungmoo Macromolecules, Vol. 38, Issue 6 https://doi.org/10.1021/ma048011q	journal	March 2005
Uniquely Broad Glass Transition Temperatures of Gradient Copolymers Relative to Random and Block Copolymers Containing Repulsive Comonomers Kim, Jungki; Mok, Michelle M.; Sandoval, Robert W. Macromolecules, Vol. 39, Issue 18 https://doi.org/10.1021/ma061241f	journal	September 2006
Preparation of Well-Defined Hybrid Materials by ATRP in Miniemulsion Bombalski, Lindsay; Min, Ke; Dong, Hongchen Macromolecules, Vol. 40, Issue 21 https://doi.org/10.1021/ma071408k	journal	October 2007
Suspensions of Silica Particles Grafted with Concentrated Polymer Brush: Effects of Graft Chain Length on Brush Layer Thickness and Colloidal Crystallization Ohno, Kohji; Morinaga, Takashi; Takeno, Satoshi Macromolecules, Vol. 40, Issue 25 https://doi.org/10.1021/ma071770z	journal	December 2007
Successful Miniemulsion ATRP Using an Anionic Surfactant: Minimization of Deactivator Loss by Addition of a Halide Salt Teo, Victoria L.; Davis, Brad J.; Tsarevsky, Nicolay V. Macromolecules, Vol. 47, Issue 18 https://doi.org/10.1021/ma501379q	journal	September 2014
Chain Dimensions in Poly(ethylene oxide)/Poly(methyl methacrylate) Blends Zeroni, Ilan; Lodge, Timothy P. Macromolecules, Vol. 41, Issue 3 https://doi.org/10.1021/ma702512q	journal	January 2008
Microphase Separation and Shear Alignment of Gradient Copolymers: Melt Rheology and Small-Angle X-Ray Scattering Analysis Mok, Michelle M.; Pujari, Saswati; Burghardt, Wesley R. Macromolecules, Vol. 41, Issue 15 https://doi.org/10.1021/ma8009454	journal	August 2008
Functionalization of Silica Nanoparticles via the Combination of Surface-Initiated RAFT Polymerization and Click Reactions Li, Yu; Benicewicz, Brian C. Macromolecules, Vol. 41, Issue 21 https://doi.org/10.1021/ma801551z	journal	October 2008
Conformational Transitions of Spherical Polymer Brushes: Synthesis, Characterization, and Theory Dukes, Douglas; Li, Yu; Lewis, Sarah Macromolecules, Vol. 43, Issue 3 https://doi.org/10.1021/ma901228t	journal	February 2010
Copolymerization of n -Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers: Comparison of Reactivity Ratios in Conventional and Atom Transfer Radical Copolymerization Roos, Sebastian G.; Müller, Axel H. E.; Matyjaszewski, Krzysztof Macromolecules, Vol. 32, Issue 25 https://doi.org/10.1021/ma9819337	journal	December 1999
Water accelerated self-healing of hydrophobic copolymers Davydovich, Dmitriy; Urban, Marek W. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19405-5	journal	November 2020
Tuning dispersity of linear polymers and polymeric brushes grown from nanoparticles by atom transfer radical polymerization Yin, Rongguan; Wang, Zongyu; Bockstaller, Michael R. Polymer Chemistry, Vol. 12, Issue 42 https://doi.org/10.1039/D1PY01178B	journal	January 2021
Toughening fragile matter: mechanical properties of particle solids assembled from polymer-grafted hybrid particles synthesized by ATRP Choi, Jihoon; Hui, Chin Ming; Pietrasik, Joanna Soft Matter, Vol. 8, Issue 15 https://doi.org/10.1039/c2sm06915f	journal	January 2012
Dynamics of a poly(ethylene oxide) tracer in a poly(methyl methacrylate) matrix: Remarkable decoupling of local and global motions Haley, Jeffrey C.; Lodge, Timothy P. The Journal of Chemical Physics, Vol. 122, Issue 23 https://doi.org/10.1063/1.1931656	journal	June 2005
Key-and-lock commodity self-healing copolymers Urban, Marek W.; Davydovich, Dmitriy; Yang, Ying Science, Vol. 362, Issue 6411 https://doi.org/10.1126/science.aat2975	journal	October 2018
Next-generation self-healing materials Sumerlin, Brent S. Science, Vol. 362, Issue 6411 https://doi.org/10.1126/science.aau6453	journal	October 2018

Similar Records

Synthesis of Gradient Copolymer Grafted Particle Brushes by ATRP

Journal Article · Wed Dec 04 23:00:00 EST 2019 · Macromolecules · OSTI ID:1799229

Copolymer Brush Particle Hybrid Materials with “Recall-and-Repair” Capability

Journal Article · Wed Aug 16 20:00:00 EDT 2023 · Chemistry of Materials · OSTI ID:1995555

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Copolymers
Materials
Nanoparticles
Organic compounds
Polymer particles

Composition-Orientation Induced Mechanical Synergy in Nanoparticle Brushes with Grafted Gradient Copolymers

Citation Formats

References (73)

Similar Records

Related Subjects