Methods of making lithium ion conducting sulfide glass

Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.; Nimon, Vitaliy

Methods of making lithium ion conducting sulfide glass

Patent · Tue Sep 05 04:00:00 EDT 2023

OSTI ID:2222295

Visco, Steven J.; Nimon, Yevgeniy S.; Katz, Bruce D.; Nimon, Vitaliy

A lithium ion-conductive solid electrolyte including a freestanding inorganic vitreous sheet of sulfide-based lithium ion conducting glass is capable of high performance in a lithium metal battery. Such an electrolyte is also manufacturable, and readily adaptable for battery cell and cell component manufacture, in a cost-effective, scalable manner using an automated machine based system, apparatus and methods based on inline spectrophotometry to assess and inspect the quality of such vitreous solid electrolyte sheets and associated components. Suitable manufacturing methods can involve providing a sulfur precursor, providing a boron precursor material having lithium as a second constituent, combining the sulfur and boron precursor materials to form a precursor mixture, melting the mixture, and cooling the melt to form a solid lithium ion conducting glass. The glass may have a Li+ conductivity of at least 10⁻⁵ S/cm. The boron precursor material may be synthesized by reducing boron oxide to boron metal by heating the boron oxide in direct contact with lithium metal.

View Patent

Research Organization:: PolyPlus Battery Company, Berkeley, CA (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

DOE Contract Number:: AR0000772

Assignee:: PolyPlus Battery Company (Berkeley, CA)

Patent Number(s):: 11,749,834

Application Number:: 16/509,385

OSTI ID:: 2222295

Country of Publication:: United States

Language:: English

References (63)

New, Highly Ion-Conductive Crystals Precipitated from Li₂S-P₂S₅ Glasses Mizuno, F.; Hayashi, A.; Tadanaga, K. Advanced Materials, Vol. 17, Issue 7, p. 918-921 https://doi.org/10.1002/adma.200401286	journal	April 2005
Über den Phosphorstickstoff Stock, Alfred; Grüneberg, Hans Berichte der deutschen chemischen Gesellschaft, Vol. 40, Issue 2 https://doi.org/10.1002/cber.190704002184	journal	March 1907
Li ⁺ Ion Conductors with Adamantane-Type Nitridophosphate Anions β-Li ₁₀ P ₄ N ₁₀ and Li ₁₃ P ₄ N ₁₀ X ₃ with X =Cl, Br Bertschler, Eva-Maria; Dietrich, Christian; Leichtweiß, Thomas Chemistry - A European Journal, Vol. 24, Issue 1 https://doi.org/10.1002/chem.201704305	journal	December 2017
ChemInform Abstract: Fast Li+ Ion Conduction in Li2O‐Al2O3‐TiO2‐SiO2‐P2O5 Glass‐Ceramics. Fu, J. ChemInform, Vol. 28, Issue 42 https://doi.org/10.1002/chin.199742009	journal	October 1997
Cyclic voltammetry studies of the lithiumthioborate glass—indium interface Rudolph, B.; Burckhardt, W.; Staikov, G. Electrochimica Acta, Vol. 34, Issue 11 https://doi.org/10.1016/0013-4686(89)87035-5	journal	November 1989
Ionically conductive sulfide-based lithium glasses Kennedy, John H.; Zhang, Zhengming; Eckert, Hellmut Journal of Non-Crystalline Solids, Vol. 123, Issue 1-3 https://doi.org/10.1016/0022-3093(90)90804-U	journal	August 1990
Preparation and ionic conductivity of new B2S3-Li2S-LiI glasses Wada, H.; Menetrier, M.; Levasseur, A. Materials Research Bulletin, Vol. 18, Issue 2 https://doi.org/10.1016/0025-5408(83)90080-6	journal	February 1983
Fast Li+ ion transport in iodine-thioborate glasses Burckhardt, W.; Makyta, M.; Levasseur, A. Materials Research Bulletin, Vol. 19, Issue 8 https://doi.org/10.1016/0025-5408(84)90224-1	journal	August 1984
Energy barrier height measurements of chemically vapour deposited P3N5 films by internal photoinjection Hirota, Yukihiro; Mikami, Osamu Thin Solid Films, Vol. 162 https://doi.org/10.1016/0040-6090(88)90191-5	journal	August 1988
Preparation and electrical properties of the 0,37Li2S-0,18P2S5-0,45LiI glass Malugani, J.; Robert, G. Solid State Ionics, Vol. 1, Issue 5-6 https://doi.org/10.1016/0167-2738(80)90048-X	journal	December 1980
Superionic conduction in Li 2 S - P 2 S 5 - LiI - glasses Mercier, René; Malugani, Jean-Pierre; Fahys, Bernard Solid State Ionics, Vol. 5 https://doi.org/10.1016/0167-2738(81)90341-6	journal	October 1981
Electrical properties of lithium conductive silicon sulfide glasses prepared by twin roller quenching Pradel, A.; Ribes, M. Solid State Ionics, Vol. 18-19 https://doi.org/10.1016/0167-2738(86)90139-6	journal	January 1986
Preparation and conductivity measurements of SiS2Li2S glasses doped with LiBr and LiCl Kennedy, J.; Sahami, S.; Shea, S. Solid State Ionics, Vol. 18-19 https://doi.org/10.1016/0167-2738(86)90142-6	journal	January 1986
Solid state batteries using vitreous solid electrolytes Akridge, J.; Vourlis, H. Solid State Ionics, Vol. 18-19 https://doi.org/10.1016/0167-2738(86)90313-9	journal	January 1986
New lithium ion conductors based on Li2S-SiS2 system Kondo, S.; Takada, K.; Yamamura, Y. Solid State Ionics, Vol. 53-56 https://doi.org/10.1016/0167-2738(92)90310-L	journal	July 1992
Electrical properties of amorphous lithium electrolyte thin films Bates, J. B.; Dudney, N. J.; Gruzalski, G. R. Solid State Ionics, Vol. 53-56, Issue Part 1, p. 647-654 https://doi.org/10.1016/0167-2738(92)90442-R	journal	July 1992
Preparation of phosphorus targets using the compound phosphorus nitride Maier-Komor, P. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 257, Issue 1 https://doi.org/10.1016/0168-9002(87)91164-8	journal	June 1987
Ionically conductive glasses based on SiS2 Kennedy, J. H. Materials Chemistry and Physics, Vol. 23, Issue 1-2 https://doi.org/10.1016/0254-0584(89)90015-1	journal	August 1989
A thin-film solid-state microbattery Jones, Steven D.; Akridge, James R. Journal of Power Sources, Vol. 44, Issue 1-3 https://doi.org/10.1016/0378-7753(93)80196-V	journal	April 1993
Thin-film rechargeable lithium batteries Bates, J. B.; Dudney, N. J.; Lubben, D. C. Journal of Power Sources, Vol. 54, Issue 1, p. 58-62 https://doi.org/10.1016/0378-7753(94)02040-A	journal	March 1995
Electrical properties of new glasses based on the Li₂S–SiS₂ system Bartholomew, Roger F.; Young, Dianna M.; Ellison, Adam J. G. Journal of Non-Crystalline Solids, Vol. 256-257, p. 242-247 https://doi.org/10.1016/S0022-3093(99)00486-X	journal	October 1999
Preparation and characterization of lithium ion-conducting oxysulfide glasses Minami, T. Solid State Ionics, Vol. 136-137, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00555-5	journal	November 2000
Improved stability for the SiS2-P2S5-Li2S-LiI glass system Kennedy, John H.; Zhang, Zhengming Solid State Ionics, Vol. 28-30 https://doi.org/10.1016/S0167-2738(88)80133-4	journal	September 1988
Superionic conductivity of glass-ceramics in the system Li 2 O- Al 2 O 3 -TiO 2 -P 2 O 5 Fu, Jie Solid State Ionics, Vol. 96, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00018-0	journal	April 1997
Fast Li+ ion conducting glass-ceramics in the system Li2O–Al2O3–GeO2–P2O5 Fu, J. Solid State Ionics, Vol. 104, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00434-7	journal	December 1997
Formation of superionic crystals from mechanically milled Li2S–P2S5 glasses Hayashi, Akitoshi; Hama, Shigenori; Minami, Tsutomu Electrochemistry Communications, Vol. 5, Issue 2 https://doi.org/10.1016/S1388-2481(02)00555-6	journal	February 2003
Chemistry and applications of metal nitrides Hector, A. L.; Levason, W. Coordination Chemistry Reviews, Vol. 257, Issue 13-14 https://doi.org/10.1016/j.ccr.2013.02.001	journal	July 2013
Glass–ceramic Li2S–P2S5 electrolytes prepared by a single step ball billing process and their application for all-solid-state lithium–ion batteries Trevey, James; Jang, Jum Suk; Jung, Yoon Seok Electrochemistry Communications, Vol. 11, Issue 9 https://doi.org/10.1016/j.elecom.2009.07.028	journal	September 2009
Recent development of sulfide solid electrolytes and interfacial modification for all-solid-state rechargeable lithium batteries Tatsumisago, Masahiro; Nagao, Motohiro; Hayashi, Akitoshi Journal of Asian Ceramic Societies, Vol. 1, Issue 1 https://doi.org/10.1016/j.jascer.2013.03.005	journal	March 2013
Preparation and ionic conductivity of Li₇P₃S_11−z glass-ceramic electrolytes Hayashi, Akitoshi; Minami, Keiichi; Ujiie, Satoshi Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49, p. 2670-2673 https://doi.org/10.1016/j.jnoncrysol.2010.04.048	journal	October 2010
Preparation and characterization of lithium ion conducting Li2S–P2S5–GeS2 glasses and glass-ceramics Minami, Keiichi; Hayashi, Akitoshi; Tatsumisago, Masahiro Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49 https://doi.org/10.1016/j.jnoncrysol.2010.05.016	journal	October 2010
Electrical and electrochemical properties of Li₂S–P₂S₅–P₂O₅ glass–ceramic electrolytes Ohtomo, Takamasa; Mizuno, Fuminori; Hayashi, Akitoshi Journal of Power Sources, Vol. 146, Issue 1-2, p. 715-718 https://doi.org/10.1016/j.jpowsour.2005.03.063	journal	August 2005
All-solid-state lithium secondary batteries using the 75Li2S·25P2S5 glass and the 70Li2S·30P2S5 glass–ceramic as solid electrolytes Ohtomo, Takamasa; Hayashi, Akitoshi; Tatsumisago, Masahiro Journal of Power Sources, Vol. 233 https://doi.org/10.1016/j.jpowsour.2013.01.090	journal	July 2013
A brief review of atomic layer deposition: from fundamentals to applications Johnson, Richard W.; Hultqvist, Adam; Bent, Stacey F. Materials Today, Vol. 17, Issue 5 https://doi.org/10.1016/j.mattod.2014.04.026	journal	June 2014
VULNÉRABILITÉ ET PROTECTION DES MAJEURS (Février et mars 2022) No authors listed Santé mentale et Droit, Vol. 22, Issue 3, p. 470-478 https://doi.org/10.1016/j.smed.2022.04.013	journal	June 2022
Mechanochemical synthesis of amorphous solid electrolytes using SiS2 and various lithium compounds Hayashi, A. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2003.12.040	journal	November 2004
Material design of new lithium ionic conductor, thio-LISICON, in the Li2S–P2S5 system Murayama, M.; Sonoyama, N.; Yamada, A. Solid State Ionics, Vol. 170, Issue 3-4 https://doi.org/10.1016/j.ssi.2004.02.025	journal	May 2004
Characterization of Li2S?P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries Hayashi, A. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.08.036	journal	November 2004
Glassy materials based on Li2S for all-solid-state lithium secondary batteries Tatsumisago, M. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.09.012	journal	November 2004
Mechanochemical synthesis of lithium ion conducting glasses and glass–ceramics in the system Li2S–P–S Ohtomo, Takamasa; Mizuno, Fuminori; Hayashi, Akitoshi Solid State Ionics, Vol. 176, Issue 31-34 https://doi.org/10.1016/j.ssi.2005.03.025	journal	October 2005
High lithium ion conducting glass-ceramics in the system Li2S–P2S5 Mizuno, F.; Hayashi, A.; Tadanaga, K. Solid State Ionics, Vol. 177, Issue 26-32 https://doi.org/10.1016/j.ssi.2006.04.017	journal	October 2006
Lithium ion conducting solid electrolytes prepared from Li2S, elemental P and S Mizuno, F.; Ohtomo, T.; Hayashi, A. Solid State Ionics, Vol. 177, Issue 26-32 https://doi.org/10.1016/j.ssi.2006.04.024	journal	October 2006
Electrical and electrochemical properties of glass–ceramic electrolytes in the systems Li2S–P2S5–P2S3 and Li2S–P2S5–P2O5 Minami, Keiichi; Hayashi, Akitoshi; Ujiie, Satoshi Solid State Ionics, Vol. 192, Issue 1 https://doi.org/10.1016/j.ssi.2010.06.018	journal	June 2011
Mechanochemical synthesis of Li2S–P2S5 glass electrolytes with lithium salts Minami, Keiichi; Hayashi, Akitoshi; Tatsumisago, Masahiro Solid State Ionics, Vol. 181, Issue 33-34 https://doi.org/10.1016/j.ssi.2010.08.021	journal	October 2010
A new crystalline LiPON electrolyte: Synthesis, properties, and electronic structure Senevirathne, Keerthi; Day, Cynthia S.; Gross, Michael D. Solid State Ionics, Vol. 233 https://doi.org/10.1016/j.ssi.2012.12.013	journal	February 2013
Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte Wenzel, Sebastian; Weber, Dominik A.; Leichtweiss, Thomas Solid State Ionics, Vol. 286 https://doi.org/10.1016/j.ssi.2015.11.034	journal	March 2016
Facile Synthesis of Lithium Sulfide Nanocrystals for Use in Advanced Rechargeable Batteries Li, Xuemin; Wolden, Colin A.; Ban, Chunmei ACS Applied Materials & Interfaces, Vol. 7, Issue 51 https://doi.org/10.1021/acsami.5b09367	journal	December 2015
Synthesis, Structure, and Bonding in Polyiodide and Metal Iodide−Iodine Systems Svensson, Per H.; Kloo, Lars Chemical Reviews, Vol. 103, Issue 5 https://doi.org/10.1021/cr0204101	journal	May 2003
Atomic Layer Deposition: An Overview George, Steven M. Chemical Reviews, Vol. 110, Issue 1, p. 111-131 https://doi.org/10.1021/cr900056b	journal	January 2010
Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02261	journal	July 2013
Fabrication of electrode–electrolyte interfaces in all-solid-state rechargeable lithium batteries by using a supercooled liquid state of the glassy electrolytes Kitaura, Hirokazu; Hayashi, Akitoshi; Ohtomo, Takamasa J. Mater. Chem., Vol. 21, Issue 1 https://doi.org/10.1039/C0JM01090A	journal	January 2011
Preparation and Structure of Lithium-Ion-Conducting Mixed-Anion Glasses in the System LiBO2-LiBS2 Tatsumisago, Masahiro; Yoneda, Kazuya; Minami, Tsutomu Journal of the American Ceramic Society, Vol. 71, Issue 9 https://doi.org/10.1111/j.1151-2916.1988.tb06411.x	journal	September 1988
Preparation of Li2S-P2S5 Amorphous Solid Electrolytes by Mechanical Milling Hayashi, Akitoshi; Hama, Shigenori; Morimoto, Hideyuki Journal of the American Ceramic Society, Vol. 84, Issue 2 https://doi.org/10.1111/j.1151-2916.2001.tb00685.x	journal	February 2001
Novel Fast Lithium Ion Conduction in Garnet-Type Li ₅ La ₃ M ₂ O ₁₂ (M = Nb, Ta) Thangadurai, Venkataraman; Kaack, Heiko; Weppner, Werner J. F. Journal of the American Ceramic Society, Vol. 86, Issue 3 https://doi.org/10.1111/j.1151-2916.2003.tb03318.x	journal	March 2003
Lithium Ionic Conductor Thio-LISICON: The Li₂S-GeS₂-P₂S₅ System Kanno, Ryoji; Murayama, Masahiro Journal of The Electrochemical Society, Vol. 148, Issue 7, p. A742-A746 https://doi.org/10.1149/1.1379028	journal	January 2001
Complex Plane and 7Li NMR Studies of Highly Conductive Sulfide-Based Lithium Glasses Visco, Steven J. Journal of The Electrochemical Society, Vol. 132, Issue 4 https://doi.org/10.1149/1.2113952	journal	January 1985
Preparation and Conductivity Measurements of SiS[sub 2]-Li[sub 2]S-LiBr Lithium Ion Conductive Glasses Sahami, Saeed Journal of The Electrochemical Society, Vol. 132, Issue 4 https://doi.org/10.1149/1.2114001	journal	January 1985
Complex Plane and 7Li NMR Studies of Arsenic Sulfide-Based Lithium Glasses Visco, Steven J. Journal of The Electrochemical Society, Vol. 132, Issue 7 https://doi.org/10.1149/1.2114208	journal	January 1985
All Solid-state Lithium Secondary Batteries Using High Lithium Ion Conducting Li ₂ S–P ₂ S ₅ Glass-Ceramics Mizuno, Fuminori; Hama, Shigenori; Hayashi, Akitoshi Chemistry Letters, Vol. 31, Issue 12 https://doi.org/10.1246/cl.2002.1244	journal	December 2002
Solubility of Nitrogen and Oxygen in Lithium and Methods of Lithium Purification Hoffman, E. E. Symposium on Newer Metals https://doi.org/10.1520/STP46339S	book	January 1960
Superionic Conduction in Rapidly Quenched Li₂S-SiS₂-Li₃PO₄ Glasses Tatsumisago, Masahiro; Hirai, Kouichi; Minami, Tsutomu Journal of the Ceramic Society of Japan, Vol. 101, Issue 1179 https://doi.org/10.2109/jcersj.101.1315	journal	January 1993
Recent Advances in Inorganic Solid Electrolytes for Lithium Batteries Cao, Can; Li, Zhuo-Bin; Wang, Xiao-Liang Frontiers in Energy Research, Vol. 2 https://doi.org/10.3389/fenrg.2014.00025	journal	June 2014
Membranes in Lithium Ion Batteries Yang, Min; Hou, Junbo Membranes, Vol. 2, Issue 3, p. 367-383 https://doi.org/10.3390/membranes2030367	journal	July 2012

Similar Records

Methods of making and inspecting a web of vitreous lithium sulfide separator sheet and lithium electrode assemblies

Patent · Tue Mar 24 00:00:00 EDT 2020 · OSTI ID:1637814

Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods

Patent · Mon Dec 03 23:00:00 EST 2018 · OSTI ID:1496211

Standalone sulfide based lithium ion-conducting glass solid electrolyte and associated structures, cells and methods

Patent · Mon Nov 09 23:00:00 EST 2020 · OSTI ID:1771620

Methods of making lithium ion conducting sulfide glass

Citation Formats

References (63)

Similar Records

Related Subjects