Supported multimetallic catalysts for oxidative dehydrogenation of alkanes

Bunquin, Jeffrey C.; Ferrandon, Magali S.

Supported multimetallic catalysts for oxidative dehydrogenation of alkanes

Patent · Tue Aug 29 00:00:00 EDT 2023

OSTI ID:2222254

Bunquin, Jeffrey C.; Ferrandon, Magali S.

A catalyst for oxidative dehydrogenation of alkanes includes a substrate including an oxide; at least one promoter including a transition metal or a main group element of the periodic table; and an oxidation-active transition metal. The catalyst is multimetallic.

View Patent

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: UChicago Argonne, LLC (Chicago, IL)

Patent Number(s):: 11,738,331

Application Number:: 17/060,693

OSTI ID:: 2222254

Country of Publication:: United States

Language:: English

References (61)

Catalysis by Gold: Isolated Surface Au3+ Ions are Active Sites for Selective Hydrogenation of 1,3-Butadiene over Au/ZrO2 Catalysts Zhang, Xin; Shi, Hui; Xu, Bo-Qing Angewandte Chemie International Edition, Vol. 44, Issue 43 https://doi.org/10.1002/anie.200502101	journal	November 2005
Single Gold Atoms in Heterogeneous Catalysis: Selective 1,3-Butadiene Hydrogenation over Au/ZrO2 Liu, Zhi-Pan; Wang, Chuan-Ming; Fan, Kang-Nian Angewandte Chemie International Edition, Vol. 45, Issue 41 https://doi.org/10.1002/anie.200601853	journal	October 2006
Selective Alkane Oxidation by Manganese Oxide: Site Isolation of MnO _x Chains at the Surface of MnWO ₄ Nanorods Li, Xuan; Lunkenbein, Thomas; Pfeifer, Verena Angewandte Chemie International Edition, Vol. 55, Issue 12 https://doi.org/10.1002/anie.201510201	journal	February 2016
Pd Cluster Nanowires as Highly Efficient Catalysts for Selective Hydrogenation Reactions Zhang, Zhi-Cheng; Zhang, Xin; Yu, Qi-Yu Chemistry - A European Journal, Vol. 18, Issue 9 https://doi.org/10.1002/chem.201102903	journal	January 2012
Butane Dehydrogenation Reaction on Sulfur Poisoned Group 10 Metal/SiO ₂ Catalysts Chen, Hsiu-Wei; Chou, Chi-Hwei; Hong, Cheng Tsung Journal of the Chinese Chemical Society, Vol. 43, Issue 5 https://doi.org/10.1002/jccs.199600055	journal	October 1996
Propane Oxydehydrogenation over Molybdate-Based Catalysts Stern, David L.; Grasselli, Robert K. Journal of Catalysis, Vol. 167, Issue 2 https://doi.org/10.1006/jcat.1997.1568	journal	April 1997
Study of Mn-based Catalysts for Oxidative Dehydrogenation of Cyclohexane to Cyclohexene Zhu, Haiou; Ge, Qingjie; Li, Wenzhao Catalysis Letters, Vol. 105, Issue 1-2 https://doi.org/10.1007/s10562-005-8001-5	journal	November 2005
n-Butane Dehydrogenation on PtSn/Carbon Modified MgO Catalysts Shashikala, Veldurthi; Jung, Heon; Shin, Chae-Ho Catalysis Letters, Vol. 143, Issue 7 https://doi.org/10.1007/s10562-013-1009-3	journal	April 2013
Catalytic performance and stability of isomorphic molybdates used for the oxidative dehydrogenation of propane Palacio, Luz A.; Echavarría, Adriana; Lombardo, Eduardo A. Reaction Kinetics and Catalysis Letters, Vol. 85, Issue 1 https://doi.org/10.1007/s11144-005-0258-6	journal	May 2005
Pd–Sn/Al2O3 catalysts from colloidal oxide synthesis II. Surface characterization and catalytic properties for buta-1,3-diene selective hydrogenation Verdier, S. Journal of Catalysis, Vol. 218, Issue 2 https://doi.org/10.1016/S0021-9517(03)00064-2	journal	September 2003
Catalytic dehydrogenation of n-butane in a fluidized bed reactor with separate coking and regeneration zones Callejas, C.; Soler Herrero, Jaime; Herguido, Javier Studies in Surface Science and Catalysis, Vol. 130, p. 2717-2722 https://doi.org/10.1016/S0167-2991(00)80881-2	book	January 2000
Propane catalytic oxidation and oxy-dehydrogenation over manganese-based metal oxides Baldi, Marco; Sánchez-Escribano, Vicente; Gallardo-Amores, J. M. Studies in Surface Science and Catalysis, p. 635-640 https://doi.org/10.1016/S0167-2991(98)80503-X	book	January 1998
Oxidative dehydrogenation of propane over monoliths at short contact times Sadykov, V. A.; Pavlova, S. N.; Saputina, N. F. Catalysis Today, Vol. 61, Issue 1-4 https://doi.org/10.1016/S0920-5861(00)00362-X	journal	August 2000
Characterization of Mo-MnO catalyst for propane oxidative dehydrogenation Cadus, Luis E.; Ferretti, Osmar Applied Catalysis A: General, Vol. 233, Issue 1-2 https://doi.org/10.1016/S0926-860X(02)00193-X	journal	July 2002
Propane oxydehydrogenation over transition metal modified zeolite ZSM-5 Nowińska, K.; Wącław, A.; Izbińska, A. Applied Catalysis A: General, Vol. 243, Issue 2 https://doi.org/10.1016/S0926-860X(02)00504-5	journal	April 2003
Selective hydrogenation of 1,3-butadiene on TiO2-modified Pd/SiO2 catalysts Lee, Doh Chang; Kim, Jae Hyung; Kim, Woo Jae Applied Catalysis A: General, Vol. 244, Issue 1 https://doi.org/10.1016/S0926-860X(02)00597-5	journal	May 2003
Evaluation of the mechanism of the oxy-dehydrogenation of propane over manganese oxide Baldi, Marco; Finocchio, Elisabetta; Pistarino, Chiara Applied Catalysis A: General, Vol. 173, Issue 1 https://doi.org/10.1016/S0926-860X(98)00129-X	journal	October 1998
Propane oxydehydrogenation over alumina-supported vanadia doped with manganese and potassium Ermini, Valentina; Finocchio, Elisabetta; Sechi, Sara Applied Catalysis A: General, Vol. 198, Issue 1-2 https://doi.org/10.1016/S0926-860X(99)00499-8	journal	May 2000
Butane dehydrogenation on vanadium supported catalysts under oxygen free atmosphere Volpe, M.; Tonetto, G.; de Lasa, H. Applied Catalysis A: General, Vol. 272, Issue 1-2 https://doi.org/10.1016/j.apcata.2004.05.017	journal	September 2004
Preparation of nanostructured Pd particles using a seeding synthesis approach—Application to the selective hydrogenation of buta-1,3-diene Berhault, Gilles; Bisson, Laure; Thomazeau, Cécile Applied Catalysis A: General, Vol. 327, Issue 1 https://doi.org/10.1016/j.apcata.2007.04.028	journal	July 2007
Characterization and catalytic behavior in the n-butane dehydrogenation of trimetallic InPtSn/MgAl2O4 catalysts Bocanegra, Sonia A.; Castro, Alberto A.; Scelza, Osvaldo A. Applied Catalysis A: General, Vol. 333, Issue 1 https://doi.org/10.1016/j.apcata.2007.09.002	journal	December 2007
Selective and stable bimetallic PtSn/θ-Al2O3 catalyst for dehydrogenation of n-butane to n-butenes Nagaraja, Bhari Mallanna; Shin, Chae-Ho; Jung, Kwang-Deog Applied Catalysis A: General, Vol. 467 https://doi.org/10.1016/j.apcata.2013.07.022	journal	October 2013
Behavior of PtPb/MgAl2O4 catalysts with different Pb contents and trimetallic PtPbIn catalysts in n-butane dehydrogenation Bocanegra, Sonia A.; Scelza, Osvaldo A.; de Miguel, Sergio R. Applied Catalysis A: General, Vol. 468 https://doi.org/10.1016/j.apcata.2013.07.051	journal	November 2013
n-Butane dehydrogenation over Pt/Mg(In)(Al)O Wu, Jason; Peng, Zhenmeng; Sun, Pingping Applied Catalysis A: General, Vol. 470 https://doi.org/10.1016/j.apcata.2013.10.058	journal	January 2014
Effect of oxide supports on Pd–Ni bimetallic catalysts for 1,3-butadiene hydrogenation Hou, Ruijun; Porosoff, Marc D.; Chen, Jingguang G. Applied Catalysis A: General, Vol. 490 https://doi.org/10.1016/j.apcata.2014.11.001	journal	January 2015
A theoretical view of 1,3-butadiene selective hydrogenation toward cis-2-butene on PdNi layered catalyst Gómez, Guillermina; Belelli, Patricia G.; Cabeza, Gabriela F. Applied Surface Science, Vol. 353 https://doi.org/10.1016/j.apsusc.2015.06.127	journal	October 2015
Effect of mixed Al2O3 structure between θ- and α-Al2O3 on the properties of Pd/Al2O3 in the selective hydrogenation of 1,3-butadiene Pattamakomsan, Kanda; Suriye, Kongkiate; Dokjampa, Siraprapa Catalysis Communications, Vol. 11, Issue 5 https://doi.org/10.1016/j.catcom.2009.10.019	journal	January 2010
Direct dehydrogenation of n-butane over Pt/Sn/M/γ-Al2O3 catalysts: Effect of third metal (M) addition Seo, Hyun; Lee, Jong Kwon; Hong, Ung Gi Catalysis Communications, Vol. 47 https://doi.org/10.1016/j.catcom.2014.01.007	journal	March 2014
Hydrogenation of 1,3-butadiene over Au and Pt/SiO2-N catalysts at low temperature Liu, Chenguang; Yang, Kang; Zhao, Jinchong Catalysis Communications, Vol. 67 https://doi.org/10.1016/j.catcom.2015.04.007	journal	July 2015
Cu, Mn and Co molybdates derived from novel precursors catalyze the oxidative dehydrogenation of propane Palacio, Luz Amparo; Echavarría, Adriana; Sierra, Ligia Catalysis Today, Vol. 107-108 https://doi.org/10.1016/j.cattod.2005.07.031	journal	October 2005
Comparative study of Au/ZrO2 catalysts in CO oxidation and 1,3-butadiene hydrogenation Zhang, Xin; Shi, Hui; Xu, Bo-Qing Catalysis Today, Vol. 122, Issue 3-4 https://doi.org/10.1016/j.cattod.2007.02.016	journal	April 2007
Use of Al2O3–SnO2 as a support of Pt for selective dehydrogenation of light paraffins Ballarini, Adriana D.; Ricci, Claudia G.; de Miguel, Sergio R. Catalysis Today, Vol. 133-135 https://doi.org/10.1016/j.cattod.2007.11.055	journal	April 2008
Selective hydrogenation of 1,3-butadiene over Pd and Pd–Sn catalysts supported on different phases of alumina Pattamakomsan, Kanda; Ehret, Eric; Morfin, Franck Catalysis Today, Vol. 164, Issue 1 https://doi.org/10.1016/j.cattod.2010.10.013	journal	April 2011
n-Butane dehydrogenation over mono and bimetallic MCM-41 catalysts under oxygen free atmosphere Ajayi, B. P.; Jermy, B. Rabindran; Ogunronbi, K. E. Catalysis Today, Vol. 204 https://doi.org/10.1016/j.cattod.2012.07.013	journal	April 2013
Improved performance of carbon nanofiber-supported palladium particles in the selective 1,3-butadiene hydrogenation: Influence of carbon nanostructure, support functionalization treatment and metal precursor Bachiller-Baeza, B.; Peña-Bahamonde, J.; Castillejos-López, E. Catalysis Today, Vol. 249 https://doi.org/10.1016/j.cattod.2014.12.044	journal	July 2015
Selective hydrogenation of mixed C4 containing high vinyl acetylene by Mn-Pd, Ni-Pd and Ag-Pd on Al2O3 catalysts Insorn, Paisan; Kitiyanan, Boonyarach Catalysis Today, Vol. 256 https://doi.org/10.1016/j.cattod.2015.01.042	journal	November 2015
Selective hydrogenation of 1,3-butadiene in mixture with isobutene on a Pd/α-alumina catalyst in a semi-batch reactor Seth, Deepyaman; Sarkar, Amitava; Ng, Flora T. T. Chemical Engineering Science, Vol. 62, Issue 17 https://doi.org/10.1016/j.ces.2007.05.029	journal	September 2007
Influence of toluene on the catalytic activity of NiPdCe catalyst for selective hydrogenation of 1,3-butadiene Lozano, Luís; Brito, Joaquín L.; Olivera, Claudio Fuel, Vol. 110 https://doi.org/10.1016/j.fuel.2012.11.024	journal	August 2013
Selective hydrogenation of 1,3-butadiene on Pt3Sn(111) alloys: comparison to Pt(111) Jugnet, Y.; Sedrati, R.; Bertolini, J. Journal of Catalysis, Vol. 229, Issue 1 https://doi.org/10.1016/j.jcat.2004.09.028	journal	January 2005
UV Raman spectroscopic studies of V/θ-Al2O3 catalysts in butane dehydrogenation Wu, Z.; Stair, P. Journal of Catalysis, Vol. 237, Issue 2 https://doi.org/10.1016/j.jcat.2005.11.005	journal	January 2006
Atmospheric pressure studies of selective 1,3-butadiene hydrogenation on well-defined Pd/Al2O3/NiAl(110) model catalysts: Effect of Pd particle size Silvestrealbero, J.; Rupprechter, G.; Freund, H. Journal of Catalysis, Vol. 240, Issue 1 https://doi.org/10.1016/j.jcat.2006.02.024	journal	May 2006
Strained Pd overlayers on Ni nanoparticles supported on alumina and catalytic activity for buta-1,3-diene selective hydrogenation Massard, R.; Uzio, D.; Thomazeau, C. Journal of Catalysis, Vol. 245, Issue 1 https://doi.org/10.1016/j.jcat.2006.09.014	journal	January 2007
Bimetallic Au–Pd catalysts for selective hydrogenation of butadiene: Influence of the preparation method on catalytic properties Kolli, Nadia El; Delannoy, Laurent; Louis, Catherine Journal of Catalysis, Vol. 297 https://doi.org/10.1016/j.jcat.2012.09.022	journal	January 2013
Tuning catalytic reactivity on metal surfaces: Insights from DFT Loffreda, David; Michel, Carine; Delbecq, Francoise Journal of Catalysis, Vol. 308 https://doi.org/10.1016/j.jcat.2013.08.011	journal	December 2013
Selective hydrogenation of 1,3-butadiene on PdNi bimetallic catalyst: From model surfaces to supported catalysts Hou, Ruijun; Yu, Weiting; Porosoff, Marc D. Journal of Catalysis, Vol. 316 https://doi.org/10.1016/j.jcat.2014.04.015	journal	July 2014
Pd–Au single-crystal surfaces: Segregation properties and catalytic activity in the selective hydrogenation of 1,3-butadiene Piccolo, Laurent; Piednoir, Agnès; Bertolini, Jean-Claude Surface Science, Vol. 592, Issue 1-3 https://doi.org/10.1016/j.susc.2005.07.005	journal	November 2005
Precisely Controlled Porous Alumina Overcoating on Pd Catalyst by Atomic Layer Deposition: Enhanced Selectivity and Durability in Hydrogenation of 1,3-Butadiene Yi, Hong; Du, Hongyi; Hu, Yingli ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/acscatal.5b00129	journal	March 2015
Effects of Feed Compositions on Oxidative Dehydrogenation of Propane over Mn−P−O Catalyst Jibril, Baba Y. Industrial & Engineering Chemistry Research, Vol. 44, Issue 4 https://doi.org/10.1021/ie040087n	journal	January 2005
Effect of the Synthesis Method of MgAl ₂ O ₄ and of Sn and Pb Addition to Platinum Catalysts on the Behavior in n -Butane Dehydrogenation Bocanegra, Sonia; Yañez, María Julia; Scelza, Osvaldo Industrial & Engineering Chemistry Research, Vol. 49, Issue 9 https://doi.org/10.1021/ie9009205	journal	March 2010
Single-Atom Pd ₁ /Graphene Catalyst Achieved by Atomic Layer Deposition: Remarkable Performance in Selective Hydrogenation of 1,3-Butadiene Yan, Huan; Cheng, Hao; Yi, Hong Journal of the American Chemical Society, Vol. 137, Issue 33 https://doi.org/10.1021/jacs.5b06485	journal	August 2015
Alumina- and Zirconia−Alumina-Loaded Tin−Platinum. Surface Features and Performance for Butane Dehydrogenation Larese, C.; Campos-Martin, J. M.; Fierro, J. L. G. Langmuir, Vol. 16, Issue 26 https://doi.org/10.1021/la0009644	journal	December 2000
Highly effective molybdena–manganese catalyst for propane oxidative dehydrogenation Cadus, Luis E.; Ferretti, Osmar Catalysis Letters, Vol. 69, Issue 3, p. 199-202 https://doi.org/10.1023/A:1019030225144	journal	November 2000
n-Butane Dehydrogenation on PtSn Supported on MAl ₂ O ₄ (M: Mg or Zn) Catalysts Bocanegra, Sonia A.; de Miguel, Sergio R.; Castro, Alberto A. Catalysis Letters, Vol. 96, Issue 3/4 https://doi.org/10.1023/B:CATL.0000030110.62160.f2	journal	July 2004
Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limit Lucci, Felicia R.; Liu, Jilei; Marcinkowski, Matthew D. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9550	journal	October 2015
Tuning the shape of nanoparticles to control their catalytic properties: selective hydrogenation of 1,3-butadiene on Pd/Al2O3 Piccolo, Laurent; Valcarcel, Ana; Bausach, Marta Physical Chemistry Chemical Physics, Vol. 10, Issue 36 https://doi.org/10.1039/b809651a	journal	January 2008
Kinetics and mechanism of the oxidative dehydrogenation of isobutane on cobalt, nickel, and manganese molybdates Agafonov, Yu. A.; Nekrasov, N. V.; Gaidai, N. A. Kinetics and Catalysis, Vol. 48, Issue 2 https://doi.org/10.1134/S0023158407020097	journal	March 2007
Platinum-Tin Nano-Catalysts Supported on Alumina for Direct Dehydrogenation of n -Butane Lee, Jong Kwon; Seo, Hyun; Hong, Ung Gi Journal of Nanoscience and Nanotechnology, Vol. 15, Issue 10 https://doi.org/10.1166/jnn.2015.11241	journal	October 2015
Direct Dehydrogenation of n -Butane Over Pt/Sn/Zn/ γ -Al ₂ O ₃ Nano-Catalyst: Effect of Zn Content Seo, Hyun; Lee, Jong Kwon; Hong, Ung Gi Journal of Nanoscience and Nanotechnology, Vol. 15, Issue 10 https://doi.org/10.1166/jnn.2015.11243	journal	October 2015
Dehydrogenation and Isomerization of Butane over Cr Catalysts Supported on H-SSZ-35 Type Zeolites Inaba, Megumu; Murata, Kazuhisa; Saito, Masahiro Bulletin of the Chemical Society of Japan, Vol. 77, Issue 2 https://doi.org/10.1246/bcsj.77.381	journal	February 2004
Effect of Sn Addition on n-Butane Dehydrogenation over Alumina-supported Pt Catalysts Prepared by Co-impregnation and Sol-gel Methods Kikuchi, Iori; Ohshima, Masa-aki; Kurokawa, Hideki Journal of the Japan Petroleum Institute, Vol. 55, Issue 3 https://doi.org/10.1627/jpi.55.206	journal	January 2012
Dehydrogenation of n-Butane to Butadiene over Pt–Sn/MgO–Al₂O₃ Kikuchi, Iori; Haibara, Yoichi; Ohshima, Masa-aki Journal of the Japan Petroleum Institute, Vol. 55, Issue 1 https://doi.org/10.1627/jpi.55.33	journal	January 2012

Similar Records

Supported multimetallic catalysts for oxidative dehydrogenation of alkanes

Patent · Mon Nov 09 23:00:00 EST 2020 · OSTI ID:1771598

Multimetallic catalysts for selective hydrogenation of dienes and acetylenes, and purification of olefin feedstocks

Patent · Tue Jun 25 00:00:00 EDT 2019 · OSTI ID:1568507

Multimetallic catalysts

Patent · Tue Aug 27 00:00:00 EDT 2019 · OSTI ID:1576364

Supported multimetallic catalysts for oxidative dehydrogenation of alkanes

Citation Formats

References (61)

Similar Records

Related Subjects