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Magnetocaloric alloys useful for magnetic refrigeration applications

Patent ·
OSTI ID:2222156
This invention relates to magnetocaloric materials comprising alloys useful for magnetic refrigeration applications. In some embodiments, the disclosed alloys may be Cerium, Neodymium, and/or Gadolinium based compositions that are fairly inexpensive, and in some cases exhibit only 2nd order magnetic phase transitions near their curie temperature, thus there are limited thermal and structural hysteresis losses. This makes these compositions attractive candidates for use in magnetic refrigeration applications. Surprisingly, the performance of the disclosed materials is similar or better to many of the known expensive rare-earth based magnetocaloric materials.
Research Organization:
General Engineering & Research, LLC, San Diego, CA (United States); Univ. of California, San Diego, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0015932
Assignee:
General Engineering & Research, L.L.C. (San Diego, CA); The Regents of the University of California (Oakland, CA)
Patent Number(s):
11,728,074
Application Number:
16/969,858
OSTI ID:
2222156
Country of Publication:
United States
Language:
English

References (9)

Thermodynamic aspects of the constitution, grain refining, and solidification enthalpies of Al-Ce-Si alloys journal November 2004
Magnetic anisotropy and magnetic properties of RTSi (R=Gd, Y; T=Mn, Fe) compounds journal October 1998
Recent Progress in Exploring Magnetocaloric Materials journal December 2009
Magnetocaloric effect: Overcoming the magnetic limit journal March 2009
Crystal structures of the compounds RAl0.5−Si0.5+ (R = La, Ce, Pr, Nd, Sm, Gd), R3Al4Si6 (R = La, Pr), and RAlSi2 (R = Pr, Nd) journal March 2004
Structure and magnetic properties of some bulk amorphous materials journal August 1999
Al-Ce-Si (Aluminum-Cerium-Silicon) journal August 2007
The Systems Ce–Al–(Si, Ge): Phase Equilibria and Physical Properties journal May 1998
Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron journal June 2004

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