Shape-controlled synthesis and properties of dandelion-like manganese sulfide hollow spheres

Journal Article · Sat Sep 15 00:00:00 EDT 2012 · Materials Research Bulletin

DOI:https://doi.org/10.1016/J.MATERRESBULL.2012.06.005· OSTI ID:22215708

Ma, Wei ^[1]; Chen, Gen; Zhang, Dan; Zhu, Jianyu; Qiu, Guanzhou ^[1]; Liu, Xiaohe ^[1]

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1. Department of Inorganic Materials, Central South University, Changsha, Hunan 410083 (China)

Graphical abstract: Dandelion-like MnS hollow spheres assembled with nanorods could be successfully synthesized in large quantities through a simple and convenient hydrothermal synthetic method under mild conditions using soluble hydrated manganese chloride as Mn source, L-cysteine as both a precipitator and complexing reagent. The dandelion-like MnS hollow spheres might have potential applications in microdevices and magnetic cells. Highlights: ► MnS hollow spheres assembled with nanorods could be synthesized. ► The morphologies and sizes of final products could be controlled. ► Possible formation mechanism of MnS hollow spheres is proposed. -- Abstract: Dandelion-like gamma-manganese (II) sulfide (MnS) hollow spheres assembled with nanorods have been prepared via a hydrothermal process in the presence of L-cysteine and polyvinylpyrrolidone (PVP). L-cysteine was employed as not only sulfur source, but also coordinating reagent for the synthesis of dandelion-like MnS hollow spheres. The morphology, structure and properties of as-prepared products have been investigated in detail by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), selected area electron diffraction (SAED), high-resolution transmission electron microscopy (HRTEM) and photoluminescence spectra (PL). The probable formation mechanism of as-prepared MnS hollow spheres was discussed on the basis of the experimental results. This strategy may provide an effective method for the fabrication of other metal sulfides hollow spheres.

• OSTI ID: 22215708
• Journal Information: Materials Research Bulletin, Journal Name: Materials Research Bulletin Journal Issue: 9 Vol. 47; ISSN MRBUAC; ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
77 NANOSCIENCE AND NANOTECHNOLOGY
CRYSTAL GROWTH
CYSTEINE
ELECTRON DIFFRACTION
MANGANESE
MANGANESE CHLORIDES
MANGANESE SULFIDES
NANOSTRUCTURES
OPTICAL PROPERTIES
PHOTOLUMINESCENCE
PVP
SCANNING ELECTRON MICROSCOPY
SPHERES
SYNTHESIS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
X-RAY SPECTROSCOPY