Characterization, properties and catalytic application of TiO{sub 2} nanotubes prepared by ultrasonic-assisted sol-hydrothermal method
- College of Biological and Environmental Engineering, Zhejiang University of Technology, No. 18 ChaoWang Rd., Hangzhou (China)
- State Key Lab of Silicon Materials, Zhejiang University, Hangzhou 310027 (China)
Graphical abstract: A novel class of titania nanotubes (TNTs) have been prepared by ultrasonic assisted sol-hydrothermal method using tetrabutyl titanate and ethanol as the precursors. The physicochemical characteristics of the catalysts were investigated by transmission electron microscopy, X-ray diffraction, Brunauer–Emmett–Teller method, Differential Scanning Calorimeters-Thermogravimetric Analysis (DSC–TG) and UV–vis absorption spectra. The photocatalytic activity of the products was evaluated in terms of reactive brilliant red X-3B in an aqueous solution under UV irradiation for 1 h. The results showed that the catalyst revealed an excellent photocatalytic activity. The degradation rate of reactive brilliant X-3B could be up to 96%. Display Omitted Highlights: ► TiO{sub 2} nanotubes were prepared by ultrasonic-assisted sol-hydrothermal method. ► TEM, HRTEM, XRD, and BET were used to study morphology and crystalline structure. ► FTIR, DSC-TG was used to investigate pyrolytic process and phase structure. ► UV–vis absorption spectra were used to evaluate the photocatalysis of catalysts. ► Dye degradation result showed that the catalyst had excellent photocatalytic activity. -- Abstract: A novel class of titania nanotubes (TNTs) have been prepared by ultrasonic assisted sol-hydrothermal method using tetrabutyl titanate and ethanol as the precursors. The physicochemical characteristics of the catalysts were investigated by transmission electron microscopy (TEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) method, Differential Scanning Calorimeters-Thermogravimetric Analysis (DSC-TG) and UV–vis absorption spectra. The photocatalytic activity of the products was evaluated in terms of reactive brilliant red X-3B in an aqueous solution under UV irradiation for 1 h. The results showed that the anatase nanotubes prepared by ultrasonic assisted sol-hydrothermal method exhibited excellent photocatalytic activity. The degradation rate of reactive brilliant X-3B could be up to 96%. The high degradation rate was attributed to the good crystalline pure-phase structure of nanotubes caused by ultrasound. Furthermore, the large surface areas also played an important role in the high degradation rate.
- OSTI ID:
- 22215617
- Journal Information:
- Materials Research Bulletin, Journal Name: Materials Research Bulletin Journal Issue: 11 Vol. 47; ISSN MRBUAC; ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
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