Liquid crystalline phase synthesis of nanoporous MnO{sub 2} thin film arrays as an electrode material for electrochemical capacitors

Journal Article · Thu Nov 15 04:00:00 EST 2012 · Materials Research Bulletin

DOI:https://doi.org/10.1016/J.MATERRESBULL.2012.08.023· OSTI ID:22215545

Yang, Guangwu ^[1]; Wang, Baoli ^[2]; Guo, Wenyue ^[1]; Bu, Zhongheng; Miao, Chengcheng ^[1]; Xue, Tong; Li, Hulin ^[3]

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1. College of Science, China University of Petroleum, Qingdao, Shandong 266555 (China)
2. School of Geosciences, China University of Petroleum, Qingdao, Shandong 266555 (China)
3. College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China)

Graphical abstract: Three-dimensional (3D) MnO{sub 2} thin film arrays with nanoporous structure is electrodeposited on Ti foil from hexagonal lyotropic liquid crystalline phase. Low-angle X-ray diffraction (XRD), wide-angle XRD, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) are employed to study the morphology and the structure of the as-synthesized MnO{sub 2} materials. Galvanostatic charge/discharge measurements show the nanoporous, 3D electrode material exhibits excellent capacitive performance between the potential range of −0.1 to 0.9 V, and a maximum specific capacitance as high as 462 F g{sup −1} are achieved in 0.5 M Na{sub 2}SO{sub 4} solution at a charge/discharge current density of 4 A g{sup −1}. Highlights: ► 3D MnO{sub 2} thin film arrays with nanoporous structure is fabricated for the first time. ► A maximum specific capacitance as high as 462 F g{sup −1} is obtained. ► The 3D and nanoporous superarchitecture facilitate electrolyte penetration. -- Abstract: Three-dimensional (3D) MnO{sub 2} thin film arrays with nanoporous structure is electrodeposited on Ti foil from hexagonal lyotropic liquid crystalline phase. Low-angle X-ray diffraction (XRD), wide-angle XRD, field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) are employed to study the morphology and the structure of the as-synthesized MnO{sub 2} materials. Galvanostatic charge/discharge measurements show the nanoporous, 3D electrode material exhibits excellent capacitive performance between the potential range of −0.1 to 0.9 V, and a maximum specific capacitance as high as 462 F g{sup −1} are achieved in 0.5 M Na{sub 2}SO{sub 4} solution at a charge/discharge current density of 4 A g{sup −1}.

• OSTI ID: 22215545
• Journal Information: Materials Research Bulletin, Journal Name: Materials Research Bulletin Journal Issue: 11 Vol. 47; ISSN MRBUAC; ISSN 0025-5408
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CURRENT DENSITY
ELECTRODEPOSITION
ELECTRODES
FIELD EMISSION
MANGANESE OXIDES
SCANNING ELECTRON MICROSCOPY
SODIUM SULFATES
SYNTHESIS
THIN FILMS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION