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Title: Facile fabrication of p-n heterojunctions for Cu{sub 2}O submicroparticles deposited on anatase TiO{sub 2} nanobelts

Journal Article · · Materials Research Bulletin
 [1];  [2];  [1]
  1. College of Science, Beijing Technology and Business University, 11 Fucheng Road, Beijing 100048 (China)
  2. Department of Materials Science and Engineering, Luoyang Institute of Science and Technology, Luoyang 471023 (China)

Graphical abstract: Cu{sub 2}O particle-deposited TiO{sub 2} nanobelts with p-n semiconductor heterojunction structure were successfully prepared via two-step preparation process, and their visible-light photodegradation activities of Rhodamine B were investigated in detail. Highlights: {yields} Cu{sub 2}O particle-deposited TiO{sub 2} nanobelts mainly with diameters in a range of 200-400 nm were successfully prepared. {yields} The amount of Cu{sub 2}O particles deposited on TiO{sub 2} nanobelts can be tuned. {yields} The composite structure with Cu{sub 2}O particles and TiO{sub 2} nanobelts exhibits p-n semiconductor heterojunction performance. {yields} Photocatalytic properties of such composites. -- Abstract: In this paper, Cu{sub 2}O particle-deposited TiO{sub 2} nanobelts with p-n semiconductor heterojunction structure were successfully prepared via a two-step preparation process to investigate electron-transfer performance between p-type Cu{sub 2}O and n-type TiO{sub 2}. Various measurement results confirm that the amount of pure Cu{sub 2}O submicroparticles, with diameters within the range of 200-400 nm and deposited on the surface of TiO{sub 2} nanobelts, can be controlled, and that the purity of Cu{sub 2}O is heavily affected by reaction time. Visible-light photodegradation activities of Rhodamine B show that photocatalysts have little or no photocatalytic activities mainly due to their p-n heterojunction structure, indicating that there hardly appears any electron-transfer from Cu{sub 2}O to TiO{sub 2}.

OSTI ID:
22210132
Journal Information:
Materials Research Bulletin, Vol. 46, Issue 11; Other Information: Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
Country of Publication:
United States
Language:
English