Nanopowders of YAl{sub 3}(BO{sub 3}){sub 4} doped by Nd, Yb and Cr obtained by sol-gel method: Synthesis, structure and luminescence properties
- Institute of Electronic Materials Technology, 133 Wolczynska Str., 01-919 Warsaw (Poland)
- Institute of Low Temp. and Struct. Research, Polish Ac. Sc., P.O. Box 1410, 50-950 Wroclaw (Poland)
Structure, morphology and luminescence properties of nanocrystalline samples of YAl{sub 3}(BO{sub 3}){sub 4} (YAB) undoped and doped with neodymium, ytterbium and chromium obtained by the sol-gel method are presented. The best results of synthesis are obtained for mannitol as polymerizing agent. Single phase of nanopowder is obtained for pure YAB. Dopants destroy the compound structure; two other compounds, namely Al{sub 18}B{sub 4}O{sub 33} and YBO{sub 3}, were revealed by X-ray investigation. Nanopowders show isometric and needles forms, the calculated size of crystallites is about 60 nm. Their optical properties are determined and results are compared to data obtained for single crystal counterparts. It is shown that the influence of rare earth ions incorporated into YBO{sub 3} phase on luminescent spectra and excited state relaxation dynamics of the nanopowders is negligibly small when the YBO{sub 3} content is of the order of several wt%. Residual impurity phases do not affect significantly spectroscopic properties of YAB nanopowders.
- OSTI ID:
- 22202520
- Journal Information:
- Materials Research Bulletin, Vol. 44, Issue 12; Other Information: Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0025-5408
- Country of Publication:
- United States
- Language:
- English
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