Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes

Tan, Xinghua; Chen, Zhefeng; Liu, Tongchao; Zhang, Yongxin; Zhang, Mingjian; Li, Shunning; Chu, Weiguo; Liu, Kang; Yang, Peihua; Pan, Feng

doi:10.1002/adma.202301096

Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes

Journal Article · Fri Jun 30 00:00:00 EDT 2023 · Advanced Materials

DOI:https://doi.org/10.1002/adma.202301096· OSTI ID:2217540

Tan, Xinghua ^[1]; Chen, Zhefeng ^[2]; Liu, Tongchao ^[3]; Zhang, Yongxin ^[4]; Zhang, Mingjian ^[2]; Li, Shunning ^[2]; Chu, Weiguo ^[4]; ^[5]; ^[5]; ^[2]

Peking Univ., Beijing (China); National Center for Nanoscience and Technology, Beijing (China). CAS Key Laboratory for Nanophotonic Materials and Devices
Peking Univ., Beijing (China)
Argonne National Laboratory (ANL), Argonne, IL (United States)
National Center for Nanoscience and Technology, Beijing (China). CAS Key Laboratory for Nanophotonic Materials and Devices
Wuhan Univ. (China)

Ni-rich layered oxides are the most promising cathodes for Li-ion batteries, but chemo-mechanical failures during cycling and large first-cycle capacity loss hinder their applications in high-energy batteries. Herein, by introducing spinel-like mortise-tenon structures into the layered phase of LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811), the adverse volume variations in cathode materials can be significantly suppressed. Meanwhile, these mortise-tenon structures play the role of the expressway for fast lithium-ion transport, which is substantiated by experiments and calculations. Moreover, the particles with mortise-tenon structures usually terminate with the most stable (003) facet. The new cathode exhibits a discharge capacity of 215 mAh g^–1 at 0.1 C with an initial Coulombic efficiency of 97.5%, and capacity retention of 82.2% after 1200 cycles at 1 C. Importantly, this work offers a viable lattice engineering to address the stability and low initial Coulombic efficiency of the Ni-rich layered oxides, and facilitates the implementation of Li-ion batteries with high-energy density and long durability.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 2217540

Alternate ID(s):: OSTI ID: 1994587

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 32 Vol. 35; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
Ni-rich layered cathode
fast lithiumion transport
initial Coulombic efficiency
mortise-tenon structure
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Imitating Architectural Mortise‐Tenon Structure for Stable Ni‐Rich Layered Cathodes

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