Tough and recyclable carbon-fiber composites with exceptional interfacial adhesion via a tailored vitrimer-fiber interface

Rahman, Md Anisur; Karunarathna, Menisha S.; Bowland, Christopher C.; Yang, Guang; Gainaru, Catalin; Li, Bingrui; Kim, Sungjin; Chawla, Vivek; Ghezawi, Natasha; Meyer, III, Harry M.; Naskar, Amit K.; Penumadu, Dayakar; Sokolov, Alexei P.; Saito, Tomonori

doi:10.1016/j.xcrp.2023.101695

Title: Tough and recyclable carbon-fiber composites with exceptional interfacial adhesion via a tailored vitrimer-fiber interface

Journal Article · Fri Dec 01 00:00:00 EST 2023 · Cell Reports Physical Science

DOI:https://doi.org/10.1016/j.xcrp.2023.101695· OSTI ID:2217255

; Karunarathna, Menisha S.; Bowland, Christopher C.; Yang, Guang; Gainaru, Catalin; Li, Bingrui; Kim, Sungjin; Chawla, Vivek; Ghezawi, Natasha; Meyer, III, Harry M.; Naskar, Amit K.; Penumadu, Dayakar; Sokolov, Alexei P.; Saito, Tomonori

Carbon-fiber-reinforced polymers (CFRPs) offer improved energy efficiency in aerospace and automobile applications due to lightweight and mechanical robustness but face challenges with limited recyclability and frequent fiber-polymer delamination caused by inadequate interfacial adhesion. Here, we report an effective design of tough and closed-loop recyclable carbon-fiber-reinforced vitrimers (CFRVs) with exceptional interfacial adhesion through the synergy of a boronic ester-modified commodity polymer, multidiol cross-linker, and diol-functionalized carbon fibers (CFs). The dynamic covalent bonding between the vitrimer and fiber interface results in 43% higher interfacial adhesion than that of CFRVs with pristine CFs. Moreover, CFRVs with diol-CFs exhibit ~731-MPa tensile strength, 26% higher than unmodified CFRVs and 49% higher than conventional epoxy CFRPs. Importantly, the dynamic boronic ester exchange enables CFRV closed-loop recyclability, repairability, fast thermoformability, self-adhesion, and multicycle processability without compromising mechanical performance. The designed dynamic fiber-matrix interaction will open up a new paradigm of multifunctional CFRPs while providing a path toward closed-loop structural materials.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); USDOE Office of Electricity (OE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2217255

Alternate ID(s):: OSTI ID: 2281146

Journal Information:: Cell Reports Physical Science, Journal Name: Cell Reports Physical Science Vol. 4 Journal Issue: 12; ISSN 2666-3864

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (36)

Readily recyclable carbon fiber reinforced composites based on degradable thermosets: a review Wang, Binbo; Ma, Songqi; Yan, Shifeng Green Chemistry, Vol. 21, Issue 21 https://doi.org/10.1039/C9GC01760G	journal	January 2019
High mechanical properties of covalently functionalized carbon fiber and polypropylene composites by enhanced interfacial adhesion derived from rationally designed polymer compatibilizers Seo, Heun Young; Cho, Kie Yong; Im, Dohyun Composites Part B: Engineering, Vol. 228 https://doi.org/10.1016/j.compositesb.2021.109439	journal	January 2022
Dynamic Curing Agents for Amine-Hardened Epoxy Vitrimers with Short (Re)processing Times Spiesschaert, Yann; Guerre, Marc; De Baere, Ives Macromolecules, Vol. 53, Issue 7 https://doi.org/10.1021/acs.macromol.9b02526	journal	March 2020
Recent advances of interphases in carbon fiber-reinforced polymer composites: A review Zheng, Hao; Zhang, Wenjian; Li, Bowen Composites Part B: Engineering, Vol. 233 https://doi.org/10.1016/j.compositesb.2022.109639	journal	March 2022
Room-Temperature Self-Healable and Mechanically Robust Thermoset Polymers for Healing Delamination and Recycling Carbon Fibers Feng, Xiaming; Li, Guoqiang ACS Applied Materials & Interfaces, Vol. 13, Issue 44 https://doi.org/10.1021/acsami.1c16105	journal	October 2021
Enhanced Interfacial Adhesion and Properties of Polypropylene/Carbon Fiber Composites by Fiber Surface Oxidation in Presence of a Compatibilizer Tian, Huafeng; Yao, Yuanyuan; Liu, Di Polymer Composites, Vol. 40, Issue S1 https://doi.org/10.1002/pc.24938	journal	August 2018
Covalently Cross-Linked Elastomers with Self-Healing and Malleable Abilities Enabled by Boronic Ester Bonds Chen, Yi; Tang, Zhenghai; Zhang, Xuhui ACS Applied Materials & Interfaces, Vol. 10, Issue 28 https://doi.org/10.1021/acsami.8b09863	journal	June 2018
Comparing Life Cycle Energy and Global Warming Potential of Carbon Fiber Composite Recycling Technologies and Waste Management Options Meng, Fanran; Olivetti, Elsa A.; Zhao, Youyang ACS Sustainable Chemistry & Engineering, Vol. 6, Issue 8 https://doi.org/10.1021/acssuschemeng.8b01026	journal	June 2018
Reversing fatigue in carbon-fiber reinforced vitrimer composites Kamble, Mithil; Vashisth, Aniruddh; Yang, Hongkun Carbon, Vol. 187 https://doi.org/10.1016/j.carbon.2021.10.078	journal	February 2022
Unentangled Vitrimer Melts: Interplay between Chain Relaxation and Cross-link Exchange Controls Linear Rheology Ricarte, Ralm G.; Shanbhag, Sachin Macromolecules, Vol. 54, Issue 7 https://doi.org/10.1021/acs.macromol.0c02530	journal	March 2021
Design of tough adhesive from commodity thermoplastics through dynamic crosslinking Rahman, Md Anisur; Bowland, Christopher; Ge, Sirui Science Advances, Vol. 7, Issue 42 https://doi.org/10.1126/sciadv.abk2451	journal	October 2021
Biobased Carbon Fiber Composites with Enhanced Flame Retardancy: A Cradle-to-Cradle Approach Zamani, Parisa; Zabihi, Omid; Ahmadi, Mojtaba ACS Sustainable Chemistry & Engineering, Vol. 10, Issue 2 https://doi.org/10.1021/acssuschemeng.1c07859	journal	December 2021
Interlocked Covalent Adaptable Networks and Composites Relying on Parallel Connection of Aromatic Disulfide and Aromatic Imine Cross-Links in Epoxy Xiang, Shipeng; Zhou, Lin; Chen, Ruiqi Macromolecules, Vol. 55, Issue 23 https://doi.org/10.1021/acs.macromol.2c01912	journal	November 2022
Triblock Elastomeric Vitrimers: Preparation, Morphology, Rheology, and Applications Fang, Huagao; Gao, Xingchen; Zhang, Fan Macromolecules, Vol. 55, Issue 24 https://doi.org/10.1021/acs.macromol.2c01711	journal	December 2022
Dynamic Covalent Bond Exchange Enhances Penetrant Diffusion in Dense Vitrimers Huang, Junrou; Ramlawi, Nabil; Sheridan, Grant S. Macromolecules, Vol. 56, Issue 3 https://doi.org/10.1021/acs.macromol.2c02547	journal	January 2023
Graphene reinforced carbon fibers Gao, Zan; Zhu, Jiadeng; Rajabpour, Siavash Science Advances, Vol. 6, Issue 17 https://doi.org/10.1126/sciadv.aaz4191	journal	April 2020
Vitrimers: Permanently crosslinked polymers with dynamic network topology Van Zee, Nathan J.; Nicolaÿ, Renaud Progress in Polymer Science, Vol. 104 https://doi.org/10.1016/j.progpolymsci.2020.101233	journal	May 2020
Polymers with Dynamic Bonds: Adaptive Functional Materials for a Sustainable Future Samanta, Subarna; Kim, Sungjin; Saito, Tomonori The Journal of Physical Chemistry B, Vol. 125, Issue 33 https://doi.org/10.1021/acs.jpcb.1c03511	journal	July 2021
Malleable and Self-Healing Covalent Polymer Networks through Tunable Dynamic Boronic Ester Bonds Cromwell, Olivia R.; Chung, Jaeyoon; Guan, Zhibin Journal of the American Chemical Society, Vol. 137, Issue 20 https://doi.org/10.1021/jacs.5b03551	journal	May 2015
Current status of carbon fibre and carbon fibre composites recycling Zhang, Jin; Chevali, Venkata S.; Wang, Hao Composites Part B: Engineering, Vol. 193 https://doi.org/10.1016/j.compositesb.2020.108053	journal	July 2020
Polydopamine As an Efficient and Robust Platform to Functionalize Carbon Fiber for High-Performance Polymer Composites Chen, Shusheng; Cao, Yewen; Feng, Jiachun ACS Applied Materials & Interfaces, Vol. 6, Issue 1 https://doi.org/10.1021/am404394g	journal	November 2013
Effect of surface modification on carbon fiber and its reinforced phenolic matrix composite Yuan, Hua; Wang, Chengguo; Zhang, Shan Applied Surface Science, Vol. 259 https://doi.org/10.1016/j.apsusc.2012.07.034	journal	October 2012
Epoxy resin with exchangeable disulfide crosslinks to obtain reprocessable, repairable and recyclable fiber-reinforced thermoset composites Ruiz de Luzuriaga, Alaitz; Martin, Roberto; Markaide, Nerea Materials Horizons, Vol. 3, Issue 3 https://doi.org/10.1039/C6MH00029K	journal	January 2016
Room-temperature fully recyclable carbon fibre reinforced phenolic composites through dynamic covalent boronic ester bonds Wang, Shujuan; Xing, Xiaolong; Zhang, Xiaoting Journal of Materials Chemistry A, Vol. 6, Issue 23 https://doi.org/10.1039/C8TA01801D	journal	January 2018
Adaptable Crosslinks in Polymeric Materials: Resolving the Intersection of Thermoplastics and Thermosets Scheutz, Georg M.; Lessard, Jacob J.; Sims, Michael B. Journal of the American Chemical Society, Vol. 141, Issue 41 https://doi.org/10.1021/jacs.9b07922	journal	September 2019
Carboxyl functionalization of carbon fibers through a grafting reaction that preserves fiber tensile strength Ehlert, Gregory J.; Lin, Yirong; Sodano, Henry A. Carbon, Vol. 49, Issue 13 https://doi.org/10.1016/j.carbon.2011.05.057	journal	November 2011
Rapid Fabrication of Malleable Fiber Reinforced Composites with Vitrimer Powder Yu, Luxia; Zhu, Chengpu; Sun, XiaoHao ACS Applied Polymer Materials, Vol. 1, Issue 9 https://doi.org/10.1021/acsapm.9b00641	journal	July 2019
Properties of thermo-chemically surface treated carbon fibers and of their epoxy and vinyl ester composites Vautard, F.; Ozcan, S.; Meyer, H. Composites Part A: Applied Science and Manufacturing, Vol. 43, Issue 7 https://doi.org/10.1016/j.compositesa.2012.02.018	journal	July 2012
Reprocessable, Self-Adhesive, and Recyclable Carbon Fiber-Reinforced Composites Using a Catalyst-Free Self-Healing Bio-Based Vitrimer Matrix Xu, Yazhou; Dai, Songlin; Zhang, Haibo ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 48 https://doi.org/10.1021/acssuschemeng.1c05586	journal	November 2021
Dynamic urea bond for the design of reversible and self-healing polymers Ying, Hanze; Zhang, Yanfeng; Cheng, Jianjun Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4218	journal	February 2014
Closed-Loop Recycling of Both Resin and Fiber from High-Performance Thermoset Epoxy/Carbon Fiber Composites Ma, Xu; Xu, Haifeng; Xu, Zejun ACS Macro Letters, Vol. 10, Issue 9 https://doi.org/10.1021/acsmacrolett.1c00437	journal	August 2021
Surface modification of carbon fiber/epoxy composites with randomly oriented aramid fiber felt for adhesion strength enhancement Choi, Ilbeom; Lee, Dai Gil Composites Part A: Applied Science and Manufacturing, Vol. 48 https://doi.org/10.1016/j.compositesa.2013.01.003	journal	May 2013
Closed-Loop Recycling of Carbon Fiber-Reinforced Composites Enabled by a Dual-Dynamic Cross-linked Epoxy Network Liu, Yingying; Lu, Fei; Yang, Lei ACS Sustainable Chemistry & Engineering, Vol. 11, Issue 4 https://doi.org/10.1021/acssuschemeng.2c06322	journal	January 2023
Repairable Woven Carbon Fiber Composites with Full Recyclability Enabled by Malleable Polyimine Networks Taynton, Philip; Ni, Huagang; Zhu, Chengpu Advanced Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adma.201505245	journal	February 2016
Intrinsically Self-Healing Polymers: From Mechanistic Insight to Current Challenges Li, Bingrui; Cao, Peng-Fei; Saito, Tomonori Chemical Reviews, Vol. 123, Issue 2 https://doi.org/10.1021/acs.chemrev.2c00575	journal	December 2022
Polybutadiene Vitrimers Based on Dioxaborolane Chemistry and Dual Networks with Static and Dynamic Cross-links Breuillac, Antoine; Kassalias, Alexis; Nicolaÿ, Renaud Macromolecules, Vol. 52, Issue 18 https://doi.org/10.1021/acs.macromol.9b01288	journal	August 2019

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36 MATERIALS SCIENCE
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Title: Tough and recyclable carbon-fiber composites with exceptional interfacial adhesion via a tailored vitrimer-fiber interface

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