Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient 15 N NMR spectroscopy

Graham, Trent R.; Wei, Yihui; Walter, Eric D.; Nienhuis, Emily T.; Chun, Jaehun; Schenter, Gregory K.; Rosso, Kevin M.; Pearce, Carolyn I.; Clark, Aurora E.

doi:10.1039/D3CC04168A

Tracking nitrite's deviation from Stokes–Einstein predictions with pulsed field gradient ¹⁵ N NMR spectroscopy

Journal Article · Tue Dec 05 00:00:00 EST 2023 · ChemComm

DOI:https://doi.org/10.1039/D3CC04168A· OSTI ID:2216982

^[1]; Wei, Yihui ^[2]; ^[1]; ^[1]; ^[1]; ^[1]; ^[1]; ^[3]; ^[2]

Pacific Northwest National Laboratory, Richland, Washington 99354, USA
Department of Chemistry, University of Utah, Salt Lake City, Utah, 84112, USA
Pacific Northwest National Laboratory, Richland, Washington 99354, USA, Department of Crop and Soil Sciences, Washington State University, Pullman, Washington 99164, USA

The diffusivities of nitrite in concentrated sodium nitrite and simulant radioactive waste observed with ¹⁵ N PFGSTE-NMR spectroscopy exceeded predictions based on the Stokes–Einstein relationship.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Interfacial Dynamics in Radioactive Environments and Materials (IDREAM); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 2216982

Alternate ID(s):: OSTI ID: 2337910

Report Number(s):: PNNL-SA--189626

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 97 Vol. 59; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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