Synthesis and crystal structure of 3-ammonium-4-hydroxyphenyl sulfonate hemihydrate
- University of Sfax, Solid State Laboratory, Sfax Faculty of Science (Tunisia)
The crystal structure of 3-ammonium-4-hydroxyphenyl sulfonate hemihydrate C{sub 6}H{sub 3}(NH{sub 3})(OH)SO{sub 3} {center_dot} 0.5H{sub 2}O is determined by single-crystal X-ray diffraction. The unit cell parameters are as follows: a = 11.2395(3), b = 10.3814(3), c = 13.7509(4) A, {beta} = 100.326(1) Degree-Sign , V = 1578.49(8) A{sup 3}, space group P2{sub 1}/n, Z = 4. The crystal structure can be described us a succession of infinite corrugated layers parallel to ab plane. These layers consist of rings formed by four sulfonate molecules located around a center of symmetry. The rings are connected to each other and to water molecules via O-H...O hydrogen bonds. The structure is further stabilized by {pi}-{pi} interactions between phenyl rings of organic entities of successive layers.
- OSTI ID:
- 22156464
- Journal Information:
- Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 1 Vol. 58; ISSN 1063-7745; ISSN CYSTE3
- Country of Publication:
- United States
- Language:
- English
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