Structure of substituted 2-(phenoxy)benzimidazoles
Journal Article
·
· Crystallography Reports
- Ural State Forestry University (Russian Federation)
- Russian Academy of Sciences, Institute of Organic Synthesis, Ural Branch (Russian Federation)
The synthesis and X-ray diffraction study of 1-benzyl-2-[2-(5-ethyltetrazole-2-yl)-phenoxy]-1H-benzimidazole and 1-benzyl-2-[2-(5-ethyltetrazole-2-yl)-4-nitrophenoxy]-1H-benzimidazole single crystals have been performed. The oxidative splitting of an azo-hydrazone group of 1-(2-hydroxy-(5-nitro)phenyl)-3-ethyl-5-(benzylbenzimidazolyl)formazans, a break in the C2-N1 bond, the interaction of o-hydroxyl group of aryl fragment with oxygen, and the formation of new 2-(phenoxy)benzimidazoles are found to occur in the presence of perchlorate iron(III).
- OSTI ID:
- 22156322
- Journal Information:
- Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 2 Vol. 58; ISSN 1063-7745; ISSN CYSTE3
- Country of Publication:
- United States
- Language:
- English
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