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A facile approach for shape selective synthesis of rhodium nanostructures and conductivity studies

Journal Article · · AIP Advances
DOI:https://doi.org/10.1063/1.4764867· OSTI ID:22107640
 [1]
  1. Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University Aurangabad-431 004 (India)

Shape selective synthesis of Rh nanostructures has been demonstrated with the help of a single step chemical vapor deposition, where different shapes like cubes at 500 Degree-Sign C, pyramids and hexagons at 500 Degree-Sign C, 700 Degree-Sign C and 900 Degree-Sign C respectively have been obtained as a function of temperature. Scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS) and four probe conductivity measurements were used to study the morphology, crystallinity and phase purity of the structures. The conductivity values for as synthesised nanostructures have been obtained in the range of 2-7 kS/cm{sup 2}. On the basis of the experimental results, from TGA and XPS studies possible mechanistic pathway for the evolution of Rh nanostructures was discussed.

OSTI ID:
22107640
Journal Information:
AIP Advances, Journal Name: AIP Advances Journal Issue: 4 Vol. 2; ISSN AAIDBI; ISSN 2158-3226
Country of Publication:
United States
Language:
English