Synthesis and characterization of nanocrystalline Ni-YSZ cermet anode for SOFC
- Department of Metallurgical and Materials Engineering, Indian Institute of Technology Madras, Chennai 600 036 (India)
Ni-YSZ cermet anode has been synthesized in one step using a simple and cost effective combustion synthesis process. The processed powder of NiO-YSZ is found to be nanocrystalline with crystallite sizes of 29 and 22 nm for NiO and YSZ respectively by X-ray diffraction and transmission electron microscopy analysis. X-ray diffraction analysis also shows that the precursor salts are converted to highly crystalline phases of NiO and YSZ (8 mol% Y{sub 2}O{sub 3}) without any intermediate calcination step and no undesirable phases are present. Comparison with the X-ray diffraction pattern of a commercial YSZ sample shows that the process is also effective in maintaining a close compositional control. The microstructure of the sintered and reduced sample shows a well defined network of pores which is necessary for the effective functioning of the anode. The electrical conductivity as a function of temperature shows metallic behavior.
- OSTI ID:
- 22066170
- Journal Information:
- Materials Characterization, Vol. 61, Issue 1; Other Information: Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1044-5803
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
77 NANOSCIENCE AND NANOTECHNOLOGY
ANODES
CALCINATION
CERMETS
COMPARATIVE EVALUATIONS
CRYSTALS
ELECTRIC CONDUCTIVITY
MICROSTRUCTURE
NANOSTRUCTURES
NICKEL OXIDES
POWDERS
SOLID OXIDE FUEL CELLS
SYNTHESIS
TEMPERATURE DEPENDENCE
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
YTTRIUM OXIDES
ZIRCONIUM OXIDES