Developing Water–Stable Pore–Partitioned Metal–Organic Frameworks with Multi–Level Symmetry for High–Performance Sorption Applications

Xiao, Yuchen; Hong, Anh N.; Chen, Yichong; Yang, Huajun; Wang, Yanxiang; Bu, Xianhui; Feng, Pingyun

doi:10.1002/smll.202205119

Developing Water–Stable Pore–Partitioned Metal–Organic Frameworks with Multi–Level Symmetry for High–Performance Sorption Applications

Journal Article · Mon Nov 28 00:00:00 UTC 2022 · Small

DOI:https://doi.org/10.1002/smll.202205119· OSTI ID:2205470

Xiao, Yuchen ^[1]; Hong, Anh N. ^[2]; Chen, Yichong ^[2]; Yang, Huajun ^[3]; Wang, Yanxiang ^[2]; Bu, Xianhui ^[3]; ^[2]

Univ. of California, Riverside, CA (United States); UC Riverside
Univ. of California, Riverside, CA (United States)
California State Univ. (CalState), Long Beach, CA (United States)

Here a new perspective is proposed in the design of pore-space-partitioned MOFs that is focused on ligand symmetry properties sub-divided here into three hierarchical levels: 1) overall ligand, 2) ligand substructure such as backbone or core, and 3) the substituent groups. Different combinations of the above symmetry properties exist. Given the close correlation between nature of chemical moiety and its symmetry, such a unique perspective into ligand symmetry and sub-symmetry in MOF design translates into the influences on MOF properties. Five new MOFs have been prepared that exhibit excellent hydrothermal stability and high-performance adsorption properties with potential applications such as C₃H₆/C₂H₄ and C₂H₂/CO₂ selective adsorption. The combination of high stability with high benzene/cyclohexane selectivity of ≈13.7 is also of particular interest.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Riverside, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE)

Grant/Contract Number:: SC0010596

OSTI ID:: 2205470

Alternate ID(s):: OSTI ID: 1900075

Journal Information:: Small, Journal Name: Small Journal Issue: 5 Vol. 19; ISSN 1613-6810

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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