Crystal structure of octapotassium octasulfatodiceriate pentahydrate

Journal Article · Mon Mar 15 04:00:00 EDT 2010 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774510020069· OSTI ID:22051229

Alekseeva, O A; Bocharov, S N; Kryuchkova, L Yu ^[1]

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1. St. Petersburg State University (Russian Federation)

Single crystals without Co and Ni have been crystallized by the substitution method in the K{sub 2}Ni(SO{sub 4}){sub 2}-Ce(SO{sub 4}){sub 2}-H{sub 2}SO{sub 4}-H{sub 2}O system using K{sub 2}Co(SO{sub 4}){sub 2} . 6H{sub 2}O, K{sub 2} (Co,Ni)(SO{sub 4}){sub 2} . 6H{sub 2}O, or K{sub 2}Ni(SO{sub 4}){sub 2} . 6H{sub 2}O as protocrystals. The structure of the single crystals obtained has been established by X-ray diffraction analysis. The crystal structure contains dimer complex anions [Ce{sub 2}({mu}-SO{sub 4}){sub 2}(SO{sub 4}){sub 6}]{sup 8-}, K{sup +} cations, and crystallization water molecules.

• OSTI ID: 22051229
• Journal Information: Crystallography Reports, Journal Name: Crystallography Reports Journal Issue: 2 Vol. 55; ISSN CYSTE3; ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
ANIONS
CATIONS
CERIUM SULFATES
CRYSTAL STRUCTURE
CRYSTALLIZATION
DIMERS
MONOCRYSTALS
POTASSIUM COMPLEXES
POTASSIUM IONS
SULFURIC ACID
X-RAY DIFFRACTION